Synthesis of Ni/CaO-γ-Al2O3@Ru Core Shell via Micro-Emulsion Method for Bio-oil Steam Reforming of Empty Fruit Bunch

Desi Riana Saputri(1*), Widodo Wahyu Purwanto(2)

(1) Chemical Engineering Department, Faculty of Engineering, Universitas Indonesia, Depok, 16424, Indonesia
(2) Chemical Engineering Department, Faculty of Engineering, Universitas Indonesia, Depok, 16424, Indonesia
(*) Corresponding Author


Hydrogen production from bio-oil steam reforming plays an important role in the development of renewable hydrogen from biomass to produce the cleanest fuel. However, the existence of coke and low carbon conversion are problems that have been found in some studies. The purpose of this study was to reduce coke formation and to enhance carbon conversion by using core shell nanoparticle catalysts that could increase of surface area, support interaction and its catalytic activity for hydrogen production from bio-oil steam reforming of empty fruit bunch (EFB). Ni/CaO-γ-Al2O3@Ru core shells were prepared by CTAB/n-hexanol/n-hexane/water micro-emulsion system. The catalysts were characterized by means XRD, BET, FESEM-EDS and TEM. Bio-oil aqueous fraction was analyzed by using GC-MS. Carbon conversion and hydrogen yield by using Ni/CaO-γ-Al2O3@Ru core shell are resulted more 68.4 % and 18.6% than using Ni/CaO-γ-Al2O3 catalyst, respectively. The highest hydrogen yield by using Ni/CaO-γ-Al2O3@Ru core shell for steam reforming bio-oil is 5.6% in minute 10 with 0.07 g of coke deposit. The study concludes that the effect of Ni/CaO-γ-Al2O3@Ru core shell is more efficient in hydrogen production, carbon conversion and coke deposit compared to Ni/CaO-γ-Al2O3 catalyst


bio-oil, core shell, hydrogen, micro-emulsion, Ni/CaO-γ-Al2O3@Ru, steam reforming

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  1. Abdullah, N., & H. Gerhauser. (2008). Bio-oil derived from empty fruit bunches, Fuel,87: 2606 –2613.
  2. Fu, P., et al. (2014). Investigation on hydrogen production by catalytic steam reforming of maize stalk fast pyrolysis bio-oil, Int. J. Hydrog.Energy.,39: 13962-13971.
  3. Gyger, F., et al. (2014). Pd@SnO2 and SnO2@Pd core@shell nanocomposite sensors, Part. Sys. Char.,31: 591-596.
  4. Hamelinck, C.N., G.V. Hooijdonk., & A.P. Faaij (2005). Ethanol from lignocellulosic biomass: techno-economic performance in short, middle, and longterm., Biomass Bioenergy., 28:384-410.
  5. Hames, B.R., S.R. Thomas, A.D. Sluiter, C.J. Roth., & D.W. Templeton (2003). Rapid biomass analysis, new tools for compositional analysis of corn stover feedstocks and process intermediates ethanol production, Appl. Biochem. Biotech., 16:105-8.
  6. Ishihara, A., E.W. Qian, I. N. Finahari, I. P Sutrina., & T. Kabe. (2005). Addition effect of ruthenium on nickel steam reforming catalysts, Fuel, 84: 1462-1468.
  7. Koo, K.Y., S. Lee., U. H. Jung., H. Roh & W.L. Yoon. (2013). Syngas production via combined steam and carbon dioxide feforming of methane over Ni-Ce/MgAl2O4catalysts with enhanced coke resistance, Fuel Process. Technol., 119: 151 –157
  8. Majewski, A. J., J. Wood., & W. Bujalski. (2013). Nickel-silica core@shell catalyst for methane reforming, Int. J. Hydrog.Energy,38: 14531-14541.
  9. Meibod, M. P. (2013). Bio-oil wheat straw and hydrogen from aqueous phase of bio-oil,Thesis Chemical and Petroleum Engineering Department University of Calgary, Alberta.
  10. Mohanti, M. K., N. Panigrahi, & A. K. Pradhan.(2012).Non-edible karanja biodiesel-asustainable fuel for Cl engine, International Journal of Engineering Research and Application, 2, 853-860.
  11. Pefia, M.A., Gomez, J.P & Fierro, J.L.G. (1996). New catalytic routes for syngas and hydrogen production, App. Catal., A,General 144: 7–57.
  12. Takanabe, K., & K.I. Aika (2004). Sustainable hydrogen from biooil-steam reforming of acetic acid as a model oxygenate, J.Catal.227, 101–108.
  13. Salehi, E., F. S. Azad., T. Harding & J. Abedi. (2011). Production of hydrogen bysteam reforming of bio-oil over Ni/Al2O3catalysts: effect of addition of promoter and preparation procedure,Fuel Process.Technol,92: 2203-2210.
  14. Vagia, E. C., & A. A. Lemonidou. (2008). Hydrogen production via steam reforming of bio-oil components over calcium aluminate supported nickel and noble metal catalysts, App. Catal., A,351, 111-121.
  15. Valle, B., A. Remiro., A.T. Aguayo., J. Bilbao., & A. G. Gayubo. (2013). Catalysts of Ni/α-Al2O3and Ni/La2O3-αAl2O3for hydrogen production by steam reforming of bio-oil aqueous fraction with pyrolytic lignin retention. Int. J. Hydrog.Energy,38: 1307-1318.
  16. Xiu, S., & A. Shahbazi. (2012). Bio-oil production and upgrading research: A review. J. Renew.Sustain.Energy Review,16, 4406-4414.
  17. Zhang, F., M. Wang., L. Zhu., S. Wang., J. Zhou., & Z. Luo. (2016). A comparative research on the catalytic activity of La2O3and γ-Al2O3supported catalysts for acetic acid steam reforming, Int. J. Hydrog.Energy,42: 3667-3675


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ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.