The Development of Lithium Ion Recovery Method by Activated Carbon and Natural Zeolite-based Adsorbent

https://doi.org/10.22146/ajche.49569

Chandra Wahyu Purnomo(1*), Endhy Kesuma(2), Sang Kompiang Wirawan(3), Hirofumi Hinode(4)

(1) Chemical Engineering Department, Engineering Faculty, Gadjah Mada University, Indonesia
(2) Chemical Engineering Department, Engineering Faculty, Gadjah Mada University, Indonesia
(3) Chemical Engineering Department, Engineering Faculty, Gadjah Mada University, Indonesia
(4) Transdiciplinary Science and Engineering Department, Tokyo Institute of Technology, Japan
(*) Corresponding Author

Abstract


Coconut shell char and natural zeolite been activated and then tested to separate between lithium and cobalt ions in solutions. The capacity of adsorption and selectivity between the ions were investigated. The longer adsorption time, the capacity was getting better but the selectivity decreased. It was observed that the optimum selectivity was obtained by 3 hours adsorption using activated carbon. The chemical activated sample has superior performance and selectivity compared with physical activation carbons of the same activation temperature. After the adsorption, pure lithium solution can be obtained while the other metal is adsorbed inside the adsorbent

Keywords


selective adsorption, activated carbon, natural zeolite, lithium recovery

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References

  1. A. Tuncuk, V. Stazi, A. Akcil, E.Y. Yazici, H. Deveci. "Aqueous metal recovery techniques from e-scrap: Hydrometalurgy in recycling." Minerals Engineering 25, 2012: 28-37.
  2. Gulnaziya Issabayeva, Mohamed Kheireddine Aroua, Nik Meriam Sulaiman. "Continuous adsorption of lead ions in a column packed." Journal of Hazardous Materials 155 , 2008: 109-113.
  3. Jia-Li Xiao, Shu-Ying Sun, Xingfu Song, Ping Li, Jian-Guo Yu. "Lithium ion recovery from brine using granulated polyacrylamide–MnO2." Chemical Engineering Journal, 279,, 2015: 659- 666.
  4. Ji-Moon Jeong, Kyong Yop Rhee, Soo- Jin Park. "Effect of chemical treatments on lithium recovery process of activated." Journal of Industrial and Engineering Chemistry, 27,, 2015: 329- 333.
  5. Ji-Moon Jeong, Kyong Yop Rhee, Soo- Jin Park. "Effect of chemical treatments on lithium recovery process of activated." Journal of Industrial and Engineering Chemistry 27 , 2015: 329- 333.
  6. Julien Lemaire a, Lenka Svecova, Fanny Lagallarde, Richard Laucournet, Pierre- Xavier Thivel. "Lithium recovery from aqueous solution by sorption/desorption." Minerals Engineering, 25,, 2012: 28-37.
  7. K. Anoop Krishnan, T.S. Anirudhan. "Kinetic and equilibrium modelling of cobalt(II) adsorption." Chemical Engineering Journal, 137, 2008: 257- 264.
  8. Zaira Zaman Chowdhury, Sharifuddin Mohd. Zain, Rashid Atta Khan, Rahman Faizur Farique. "Batch and fixed bed adsorption studies of lead (II) cations from aqueous solutions onto granular activated carbon derived from mangostana garcinia shell." Bioresources, 7, 3,, 2012: 2895-2915.
  9. Wirawan, S.K., Warmada, I.W., Wahyuni, E.T., 2013, ‘ Effect of ion exchanged to the CO2 adsorption on MFI zeolites’, ASEAN Journal of Chemical Engineering, 13(2), 73-82
  10. Wirawan, S.K., Sudibyo, H., Setiaji, M.F., Warmada, I.W., Wahyuni, E.T. , 2015 Development of natural zeolites adsorbent: Chemical analysis and preliminary TPD adsorption study, Journal of Engineering Science and Technology, 10 (spec. issued 4, 87-95



DOI: https://doi.org/10.22146/ajche.49569

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ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.