Effect of Surfactant on Single Drop Mass Transfer in Liquid-Liquid Extraction

https://doi.org/10.22146/ajche.50122

Panut Mulyono(1*), Setia Muliati(2)

(1) Department of Chemical Engineering, Faculty of Engineering, Gadjah Mada University Jl. Grafika No. 2, Kampus UGM, Yogyakarta 55281, INDONESIA
(2) Department of Chemical Engineering, Faculty of Engineering, Gadjah Mada University Jl. Grafika No. 2, Kampus UGM, Yogyakarta 55281, INDONESIA
(*) Corresponding Author

Abstract


Liquid-liquid mass transfer coefficients for single freely rising drops in the presence of surfactant in an extraction column have been investigated using the system of kerosene-acetic acid-water. The surfactant used in this study was alkyl benzene sulfonate (ABS). The experiments were carried out by bubbling kerosene-acetic acid solution as a series of single drops from the bottom of a column containing water-ABS solution. The column used in this experiment was made from glass of 36 mm inside diameter and constructed of 60, 120, and 180 cm height. The effects of surfactant concentration, column height, and drop diameter on the overall mass transfer coefficient have been studied. The data can all be correlated by Shd = 2.08 x10−5 Red 4.01 We −1.97 (dd / H ) 0.68 with an average deviation of 17.72%. This equation is valid for the ranges of Red from 186.68 to 402.19, We from 0.80 to 3.33, and dd/H from 0.0028 to 0.0105.

Keywords


Liquid-liquid extraction, mass transfer coefficient, single drop, and surfactant.

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References

  1. Brodkey, R.S., and Hershey, H.C. (1988). Transport Phenomena: A Unified Approach, McGraw-Hill Book Company, New York.
  2. Garner, F.H., and Hale, A.R. (1953). “The effects of surface active agents in liquid extraction processes,” Chem. Eng. Sci., 2, 157-163.
  3. Garner, F.H., and Skelland, A.H.P. (1956). “Effects of surface active agents on extraction from droplets,” Ind. Eng. Chem., 48, 51-58.
  4. Handlos, A.E., and Baron, T. (1957). “Mass and heat tansfer from drops in liquid-liquid Extraction,” A.I.Ch.E. Journal, 3, 127-136.
  5. Horng, J.S., and Maa, J.R. (1986). “The effect of a surfactant on mixer-settler operation,” J. Chem. Tech. Biotechnol., 36, 15-26.
  6. Huang, W.S., and Kintner, R.C. (1969). “Effects of surfactants on mass transfer inside drops,” A.I.Ch.E. Journal, 15, 735-744.
  7. Lee, Y.L., Maa, J.R., and Yang, Y.M. (1998), “The effect of surfactant on mass transfer in extraction column,” J. Chem. Eng. Japan, 31, 340-346.
  8. McCabe, W.L., Smith, J.C., and Harriott, P. (1993). Unit operation of chemical Engineering, 5th ed., McGraw-Hill Book Co., Singapore.
  9. West, F.B., Herrman, A.J., Chong, A.T., and Thomas, L.E.K. (1952). “Addition agents and interfacial barriers in liquid-liquid extraction,” Ind. Eng. Chem., 44, 625- 631.



DOI: https://doi.org/10.22146/ajche.50122

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ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.