Fabrikasi dan Karakterisasi Sensor Elektrokimia untuk Mendeteksi Kadmium Berbasis Teknologi Film Tebal

https://doi.org/10.22146/ijeis.53468

Riska Sri Wahyuni(1*), Robert V. M.(2), Arifin Arifin(3)

(1) Departemen Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin
(2) Pusat Penelitian Elektronika dan Telekomunikasi Lembaga Ilmu Pengetahuan Indonesia
(3) Departemen Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin
(*) Corresponding Author

Abstract


Electrochemical sensor has been fabrication and characterization electrode to detect heavy metals of cadmium with thick film technology. Fabrication electrodes electrochemical sensors start with the design stage of electrodes, screen maker, screen printing, and substrate cutting. The fabrication process produces a ten-pieces of sensors to be used to sensors characterization of SEM, XRD, and Cyclic Voltammetry (CV). The process of characterization produces morphology and the structure of the composites N/IL/G, and linieritas 0,9623, precision ranges between 4,11 and 10,35%, sensitivity of 0,04112 µA.L-1/mg.mm2, limit detection 0,18 mg/L, and accuracy between 79,5 and 126,8%.

Keywords


SEM; XRD; Cyclic Voltammetry

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References

[1] Z. Xu, X. Fan, Q. Ma, B. Tang, Z. Lu, J. Zhang, G. Mo, J. Ye, dan J. Ye. “A Sensitive Electrochemical Sensor for Simultaneous Voltammetric Sensing of Cadmium and Lead based on Fe3O4/Multiwalled Carbon Nanotube/Laser Scribed Graphene Composites Functionalized with Chitosan Modified Electrode”, Materials Chemistry and Physics, vol. 584, no. 19, 2019.

[2] J. Prasek dan M. Adamek. “Development of New Thick Film Sensor for Heavy Metals Detection”, IEEE, pp. 749-752, 2004.

[3] A. Shaha, S. Sultan, A. Zahid, S. Aftab, J. Nisar, S. Nayab, R. Qureshi, G. S. Khan, H. Hussain, S. A. Ozkan. “Highly Sensitive and Selective Electrochemical Sensor for The Trace Level Detection of Mercury and Cadmium”, Electrochimica Acta, pp. 1-7, 2017.

[4] Y. Bow. “Penentuan Logam Berat secara Anodic Stripping Voltammetry menggunakan Elektroda Grafit Pensil”. Seminar Nasional Forum In Research, Science, and Technology (FIRST), pp. 61-65, 2015.

[5] S. Senthilkumar dan R. Saraswathi. “Electrochemical Sensing of Cadmium and Lead Ions at Zeolite-Modified Electrodes: Optimization and Field Measurements”. Sensors and Actuators B: Chemical, vol. 141, pp. 65–75, 2009.

[6] M. M. Radhi, N. K. Al-Damlooji, M. R. Jobayr, dan D. S. Dawood. “Electrochemical Sensors of Cyclic Voltammetry to Detect Cd(II) in Blood Medium”. Sensors & Transducers, vol. 155, no. 8, pp. 150-154, 2013.

[7] Bais R., Sharma P., Rathore P., dan Dubey S.. “Electrochemical Complexation Studies of Cadmium (II) for its Ultra Trace Determination”, Research Journal of Chemical Sciences, vol. 3, no. 6, pp. 38-42, 2013.

[8] S. Chaiyo, E. Mehmeti, K. Zagar, W. Siangproh, O. Chailapakul, dan K. Kalcher. “Electrochemical Sensors for The Simultaneous Determination of Zinc, Cadmium and Lead Using a Nafion/Ionic Liquid/Graphene Composite Modified Screen-Printed Carbon Electrode”, Analytica Chimica Acta, vol. 2670, no. 16, 2016.

[9] K. T. Rotko, K. Domanska, K. Vytras, R. Metelka, A. N. Wiercinska, dan M. Sys. “Application of Screen-Printed Carbon Electrode Modified with Lead in Stripping Analysis of Cd(II)”, Open Chem, vol. 15, no. 10, pp. 28-33, 2017.

[10] J. H. Luo, X. X. Jiao, N. B. Li, dan H. Q. Luo. “Sensitive Determination of Cd(II) by Square Wave Anodic Stripping Voltammetry with in-situ Bismuth-Modified Multiwalled Carbon Nanotubes Doped Carbon Paste Electrodes”, Electroanalytical Chemistry 689, pp. 130-134, 2013.

[11] S. Agus, R. Hardian, dan A. Muzakir. Karakterisasi Material: Prinsip dan Aplikasinya dalam Penelitian Kimia. UPI Press, Bandung, 2012.

[12] A. Ngqalakwezi, D. Nkazi, G. Seifert, dan T. Ntho. “Effects of Reduction of Graphene Oxide on The Hydrogen Storage Capacities of Metal Graphene Nanocomposite”. Catalysis Today, 2019.

[13] E. N. Hidayati, M. Alauhdin, dan A. T. Prasetya. “Perbandingan Metode Destruksi pada Analisis Pb dalam Rambut dengan AAS”. Indo. J. Chem. Sci, vol. 3, no.1, 2014.

[14] A. Kumalasari, A. S. Panggabean, dan E. Akkas. “Pengembangan Metode Rapid Test dalam Penentuan Ash Content dan Calorific Value Batubara di Laboratorium PT Jasa Mutu Mineral Indonesia”. Jurnal Atomik, vol. 2, no. 1, pp. 121-127, 2017.



DOI: https://doi.org/10.22146/ijeis.53468

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