Reductive leaching of low-grade manganese ores from Way Kanan using corncob as reductant
Yolanda Dwika Putri(1), Widi Astuti(2*), Donny Lesmana(3), Simparmin Br Ginting(4), Vincent Sutresno Hadi Sujoto(5)
(1) Chemical Engineering of Lampung University, Bandar Lampung, Indonesia
(2) Indonesian Institute of Sciences
(3) Chemical Engineering of Lampung University, Bandar Lampung, Indonesia
(4) Chemical Engineering of Lampung University, Bandar Lampung, Indonesia
(5) Chemical Engineering Department, Gadjah Mada University, Jl. Grafika 2, Yogyakarta 55281, Indonesia
(*) Corresponding Author
Abstract
The processing of mining products in indonesia has not been utilized optimally. One of them is manganese ore. Way kanan is one of indonesia's potential manganese ore sites. The manganese leaching study used a -200 mesh way kanan manganese ore that was reacted with sulfuric acid at concentrations of 0.1 M, 0.5 M, and 1 M, as well as corncob as a reductant. To separate the dissolved iron in the leaching process, the manganese sulfate solution was purified with sodium hydroxide and then filtered to have a manganese sulfate solution free of iron. Manganese was precipitated using oxalic acid. The manganese oxalate precipitation was calcined at a temperature of 350 °c for two hours. The best manganese extraction obtained at 92.3% was at a sulfuric acid concentration of 1 M, a temperature of 80 °c, and a solution volume of 400 ml. Calcination of manganese oxalate converted the material into hausmannite (Mn3O4).
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Astuti W, Mufakhir FR, Prasetyo E, Sumardi S, Yuda APT, Nur- jaman F, Supriyatna YI, Handoko AS. 2019a. Reductive- atmospheric leaching of manganese from pyrolusite ore using various reducing agents. p. 030117. doi:10.1063/1. 5098292.
Astuti W, Mufakhir FR, Prasetyo E, Yuda APT, Sumardi S, Nur- jaman F, Supriyatna YI, Handoko AS, Suharto. 2019b. Ef- fect of ore mineralogy on the reductive-leaching of man- ganese ores. IOP Conference Series: Materials Science and Engineering. 478:012014. doi:10.1088/1757-899X/47 8/1/012014.
Badan Pusat Statistik Lampung. 2019. Luas Panen, Produksi, dan Produktivitas Tanaman Jagung. https://lampung.bp s.go.id/linkTableDinamis/view/id/191.
Ismail AA, Ali EA, Ibrahim IA, Ahmed MS. 2004. A compara- tive study on acid leaching of low grade manganese ore using some industrial wastes as reductants. Canadian Journal of Chemical Engineering. 82(6):1296–1300. doi: 10.1002/cjce.5450820618.
Jing-sheng Z. 2007. Current Challenge and Chance in China’s Mn-Industry. https://www.semanticscholar.org/paper/ Current-Challenge-and-Chance-in-China’s-Mn-Indus try-Jing-sheng/aa455629560c1d190ff081ef44b93b1e6 d19e7dd.
Kisman BP, Edya P. 2016. Prospeksi Mangan Di Kecamatan Timpeh, Kabupaten Dharmasraya, Provinsi Sumatera Barat. Prosiding Kelompok Penyelidikan Mineral …. http:
//203.189.89.148/kolokium/2015_2/min/08.ProsedingD harmasraya_Kisman.pdf.
Levenspiel O. 1999. Chemical Reaction Engineering. In- dustrial & Engineering Chemistry Research. 38(11):4140– 4143. doi:10.1021/ie990488g.
Liu Y, Lin Q, Li L, Fu J, Zhu Z, Wang C, Qian D. 2014. Study on hydrometallurgical process and kinetics of manganese extraction from low-grade manganese carbonate ores. International Journal of Mining Science and Technology. 24(4):567–571. doi:10.1016/j.ijmst.2014.05.022.
Mufakhir FR, Sumardi S. 2013. Karakterisasi Bijih Mangan Daerah Kabupaten Tanggamus dan Way Kanan Provinsi Lampung dan Prosfektif Pengolahannya. Unit Pelak- sanaan Teknis Balai Pengolahan Mineral Lampung LIPI. Lampung. https://nanopdf.com/download/karakterisasi
-bijih-mangan-daerah-kabupaten_pdf.
Putra AA, Suharno B, Ferdian D, Nurjaman F. 2015. Pengaruh campuran reduktor coal-coke dalam proses reduksi biji mangan lokal pada submerged arc furnace = Effect of mix reductant coal-coke in process reductin local man- ganese ore in the submerged arc furnace. https://lib.ui.a c.id/detail?id=20421581&lokasi=lokal.
Sahoo P, Rao K. 1989. Sulphation-roasting of low-grade man- ganese ores — Optimisation by factorial design. Interna- tional Journal of Mineral Processing. 25(1-2):147–152. doi: 10.1016/0301-7516(89)90061-6.
Sujoto VSH, Sutijan, Astuti W, Sumardi S, Louis ISY, Petrus HTBM. 2022. Effect of Operating Conditions on Lithium Recovery from Synthetic Geothermal Brine Using Elec- trodialysis Method. Journal of Sustainable Metallurgy. doi:10.1007/s40831-021-00488-3.
Sumardi S. 2014. Leaching of manganese ores from east nusa tenggara using oxalic acid and molasses as reduc- ing agents and synthesis of manganese dioxide powder by hydrothermal method. Publikasi LIPI. http://lipi.go.id/publikasi/leaching-of-manganese-ores-from-east-n usa-tenggara-using-oxalic-acid-and-molasses-as-r educing-agents-and-synthesis-of-manganese-dioxi de-powder-by-hydrothermal-method/18684.
Sun Y, Fu G, Jiang L. 2017. Kinetic Study of the Leaching of Low- Grade Manganese Ores by Using Pretreated Sawdust as Reductant. Minerals. 7(5):83. doi:10.3390/min7050083.
Unal S, Mahmut B. 1988. Bench-Scale Manganese Sulfate Pro- duction from Low-grade Pyrolusite. Chimica Acta Tur- cica. 16(1):9–20.
Zhang W, Cheng CY. 2007. Manganese metallurgy review. Part I: Leaching of ores/secondary materials and recov- ery of electrolytic/chemical manganese dioxide. Hy- drometallurgy. 89(3-4):137–159. doi:10.1016/j.hydromet.2007.08.010.
DOI: https://doi.org/10.22146/jrekpros.70372
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