Effect of Graphene Oxide Sealing on the Corrosion Resistance of Anodized Aluminum Oxide

  • Siska Prifiharni Research Center for Metallurgy, National Research and Innovation Agency, Management Building 720 KST. BJ. Habibie, Banten, Indonesia
  • Yung Yung Senaputri Departement Metallurgy Engineering, Sumbawa University of Technology, Jl. Raya Olat Maras, Sumbawa Regency, NTB, Indonesia
  • Gadang Priyotomo Research Center for Metallurgy, National Research and Innovation Agency, Management Building 720 KST. BJ. Habibie, Banten, Indonesia
  • Arini Nikitasari Research Center for Metallurgy, National Research and Innovation Agency, Management Building 720 KST. BJ. Habibie, Banten, Indonesia
  • Rahayu Kusumastuti Research Center for Metallurgy, National Research and Innovation Agency, Management Building 720 KST. BJ. Habibie, Banten, Indonesia
  • Siti Musabikha Research Center for Metallurgy, National Research and Innovation Agency, Management Building 720 KST. BJ. Habibie, Banten, Indonesia
  • Syamsul Bahtiar Departement Metallurgy Engineering, Sumbawa University of Technology, Jl. Raya Olat Maras, Sumbawa Regency, NTB, Indonesia
  • Emsal Yanuar Departement Metallurgy Engineering, Sumbawa University of Technology, Jl. Raya Olat Maras, Sumbawa Regency, NTB, Indonesia
  • Lalu Suahimi Departement Metallurgy Engineering, Sumbawa University of Technology, Jl. Raya Olat Maras, Sumbawa Regency, NTB, Indonesia
  • Rita Desiasni Departement Metallurgy Engineering, Sumbawa University of Technology, Jl. Raya Olat Maras, Sumbawa Regency, NTB, Indonesia
  • Fauzi Widyawati Departement Metallurgy Engineering, Sumbawa University of Technology, Jl. Raya Olat Maras, Sumbawa Regency, NTB, Indonesia
  • Murni Handayani Research Center for Advanced Materials, National Research and Innovation Agency (BRIN), Building 440, KST. BJ. Habibie, Banten, Indonesia
Keywords: Aluminium Anode Oxide (AAO), Corrosion Resistance, Graphene Oxide, Sealing Process

Abstract

Aluminum alloy materials are widely used in aerospace, construction industry, automotive, and other fields due to their low cost and typical properties, including high strength-to-weight ratio and good corrosion resistance. The role of the anodization process that forms anodic aluminum oxide (AAO) can improve corrosion resistance, but the aluminum surface is pivoted after the anodization process. This study was conducted to determine the effect of GO-sealed on the corrosion resistance of AAO. The results show that anodized aluminum with GO-sealed performs better corrosion resistance as indicated by higher Rporous and Rsolid values when compared to unsealed anodized aluminum. Furthermore, anodized aluminum with GO-sealed has a smoother surface and harder than unsealed aluminum. It is indicated by surface characterization and hardness test.

References

Adyono, N., and Lestari, W.D., 2020. “Hard Anodize of 6061-T0 Aluminium Alloy in Sulfuric Acid Bath at Near Zero Temperature and Its Mechanical Properties,” in: 1st International Conference Eco-Innovation in Science, Engineering, and Technology. Galaxy Science, Surabaya, Indonesia.

Affi, J., Handayani, M., Anggoro, M.A., Esmawan, A., Sabarman, H., Satriawan, A., Shalannanda, W., Siburian, R., and Anshori, I., 2023. “Electrochemical and capacitive behavior of reduced graphene oxide from green reduction of graphene oxide by urea for supercapacitor electrodes.” J. Mater. Sci.: Mater. Electron. 34, 1–11.

Badr, A., Sadighi, M., Asgharzadeh, H., and Rabizadeh, T., 2019. “Enhancing the corrosion resistance of aluminum by graphene oxide and reduced graphene oxide films.” Mater. Res. Express 6, 075606.

Caporali, S., Fossati, A., and Bardi, U., 2010. “Oxidative post-treatments for enhanced corrosion resistance of aluminium electrodeposited from ionic liquids.” Corros. Sci. 52, 235–241.

Handayani, M., Kepakisan, K.A.A., Anshori, I., Darsono, N., and Nugraha T., Y., 2021. “Graphene oxide based nanocomposite modified screen printed carbon electrode for qualitative cefixime detection.” AIP Conf Proc 2382.

Handayani, M., Suwaji, B.I., Ihsantia Ning Asih, G., Kusumaningsih, T., Kusumastuti, Y., Rochmadi, and Anshori, I., 2022. “In-situ synthesis of reduced graphene oxide/silver nanoparticles (rGO/AgNPs) nanocomposites for high loading capacity of acetylsalicylic acid.” Nanocomposites 8, 74–80.

Hu, N., Dong, X., He, X., Browning, J.F., and Schaefer, D.W., 2015a. “Effect of sealing on the morphology of anodized aluminum oxide.” Corros. Sci. 97, 17–24.

Kang, D., Kwon, J.Y., Cho, H., Sim, J.H., Hwang, H.S., Kim, C.S., Kim, Y.J., Ruoff, R.S., and Shin, H.S., 2012. “Oxidation resistance of iron and copper foils coated with reduced graphene oxide multilayers.” ACS Nano 6, 7763–7769.

Li, Q., Liang, J., Liu, B., Peng, Z., and Wang, Q., 2014. “Effects of cathodic voltages on structure and wear resistance of plasma electrolytic oxidation coatings formed on aluminium alloy.” Appl. Surf. Sci. 297, 176–181.

Sherif, E.S.M., 2013. “Electrochemical investigations on the corrosion inhibition of aluminum by 3-amino-1,2,4-triazole-5-thiol in naturally aerated stagnant seawater.” J. Ind. Eng. Chem.19, 1884–1889.

Wisnujati, A., Wijayanto, H., Widodo, A.M., Mudjijana, and Rahaman, M., 2023. “Characterization of anodizing process on aluminum series 6 with variable voltage,” in: Proceedings of the First Mandalika International Multi-Conference on Science and Engineering 2022, MIMSE 2022 (Mechanical and Electrical). Atlantis Press International BV, pp. 46–56.

Xue, B., Yu, M., Liu, J., Li, S., Xiong, L., and Kong, X., 2016. “Corrosion protective properties of silane functionalized graphene oxide film on AA2024-T3 aluminum alloy.” J. Electrochem. Soc. 163, C798–C806.

Yu, M., Dong, H., Shi, H., Xiong, L., He, C., Liu, J., and Li, S., 2019. “Effects of graphene oxide-filled sol-gel sealing on the corrosion resistance and paint adhesion of anodized aluminum.” Appl. Surf. Sci., 479, 105–113.

Yu, X., Zhang, G., Zhang, Z., and Wang, Y., 2023. “Research on corrosion resistance of anodized and sealed 6061 aluminum alloy in 3.5 % sodium chloride solution.” Int. J. Electrochem. Sci., 18, 100092.

Zhang, J. sheng, Zhao, X. hui, Zuo, Y., and Xiong, J. ping, 2008. “The bonding strength and corrosion resistance of aluminum alloy by anodizing treatment in a phosphoric acid modified boric acid/sulfuric acid bath.” Surf. Coat. Technol. 202, 3149–3156.

Zuo, Y., Zhao, P.H., and Mao, J.M., 2003. “The influences of sealing methods on corrosion behavior of anodized aluminum alloys in NaCl solutions.” Surf. Coat. Technol. 166, 237–242.

Published
2024-08-30
How to Cite
Prifiharni, S., Senaputri, Y. Y., Priyotomo, G., Nikitasari, A., Kusumastuti, R., Musabikha, S., Bahtiar, S., Yanuar, E., Suahimi, L., Desiasni, R., Widyawati, F., & Handayani, M. (2024). Effect of Graphene Oxide Sealing on the Corrosion Resistance of Anodized Aluminum Oxide. ASEAN Journal of Chemical Engineering, 24(2), 156-163. https://doi.org/10.22146/ajche.12084
Section
Articles