Comparison of Furfural Production from Corn Waste and Empty Fruit Bunch (EFB): Effect of Time, Temperature, and Solvent

Muryanto; M Fadil MK Rongan; Tasrikin  Agustianto; Eka  Triwahyuni; Muhammad Arifuddin  Fitriady; Teuku Beuna  Bardant; Sri Sugiwati; Roni Maryana; Yanni Sudiyani; Misri Gozan

doi:10.22146/ajche.18177

Muryanto Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
M Fadil MK Rongan Chemical Department, Faculty of Mathematics and Natural Sciences, Universitas Jenderal Soedirman, Purwokerto, West Java, Indonesia
Tasrikin Agustianto Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Eka Triwahyuni Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Muhammad Arifuddin Fitriady Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Teuku Beuna Bardant Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Sri Sugiwati Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Roni Maryana Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Yanni Sudiyani Research Centre for Chemistry, National Research and Innovation Agency, Kawasan Puspiptek Serpong, 15314, Indonesia
Misri Gozan Chemical Engineering Department, Faculty of Engineering, University of Indonesia, Depok 16424, Indonesia

DOI: https://doi.org/10.22146/ajche.18177

Abstrak

Furfural is a compound derived from xylose, a building block material. Sources of furfural can come from various corn industry wastes such as corn cobs and corn husks, and palm oil industry wastes like Empty Fruit Bunch (EFB). This study aims to compare the potential of furfural production from corn industry waste and palm oil industry waste. The research method involves the hydrolysis and dehydration of hemicellulose using two types of solvents, sulfuric acid (SA) and Deep Eutectic Solvents (DES), at varying temperatures (160 °C, 170 °C, and 180 °C) and reaction times (60, 120, and 180 minutes). The highest furfural yield from corn cobs, 7.69 g/L, was obtained using 1 M sulfuric acid solvent at 160 °C for 60 minutes. The optimal condition for producing a high concentration of furfural from corn cobs was achieved using DES at 170°C for 60 minutes, yielding approximately 13.18 g/L. In contrast, furfural production from EFB resulted in a concentration of 4.70 g/L.

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