Packed Bed Biosorption of Lead and Copper Ions Using Sugarcane Bagasse
Keywords:
biosorption, heavy metal, continuous system, packed bed column, sugarcane
Abstract
Bagasse, a waste material from sugarcane has been studied as a biosorbent for removing heavy metals, Pb2+ and Cu2+, in a continuous system using a packed bed column. This study was undertaken to determine the influence of varying the bed height and flow rate on the breakthrough and saturation time. Thomas, Adams-Bohart and Yoon-Nelson models were used to assess the effects of varying parameters and both Thomas and Yoon-Nelson models were found to be satisfactory to describe the column data obtained in the experiment. Moreover, lead ions are adsorbed more efficiently with an adsorption capacity of 4.54 mg/g compared to copper ions with 3.98 mg/g at the most feasible parameters having a flow rate of 100 mL/min and a bed height of 30 cm
References
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29. Khormaei M., Nasernejad B., Edrisi M., Eslamzadeh T. (2007). Copper biosorption from aqueous solutions by sour orange residue. Journal of Hazardous Materials, 149, 269–274.
30. Kim, Y., Kim, C., Choi, I., Rengraj, S., Yi, J. (2004). Arsenic removal using mesoporous alumina prepared via a templating method, Environ. Sci. Technol. 38, 924–931.
31. Lawal O.S., Sanni A.R., Ajayi I.A., Rabiu O.O. (2010). Equilibrium, thermodynamic and kinetic studies for the biosorption of aqueous lead(II) ions onto the seed husk of Calophyllum inophyllum. Journal of Hazardous Materials, 177, 829–835.
32. Liu C., Ngo H.H., Guo W., Tung K. (2012). Optimal conditions for preparation of banana peels, sugarcane bagasse and watermelon rind in removing copper from water. Bioresource Technology, 119, 349–354.
33. Momcilovic, M., Purenovic, M., Bojic, A., Zarubica, A., Randelovic, M. (2011). Removal of lead(II) ions from aqueous solutions by adsorption onto pine cone activated carbon, Desalination 276, 53–9.
34. Mosier, N., Wyman, C., Dale, B., Elander, R., Lee, Y. Y., Holtzapple, M. and M.; Ladisch, M. (2005), Features of promising technologies for pretreatment of lignocellulosic biomass, Bioresource Technology, 96, 673–686.
35. Mudipalli, A. (2007). Lead hepatotoxicity & potential health effects. Indian J. Med. Res. 126, 518- 527.
36. Munaf E., Zein R. (1997). The Use of Rice Husk for Removal of Toxic Metals from Wastewater. Environmental Technology, 18, 359-362.
37. Ofomaja, A.E., Naidoo, E.B. (2011). Biosorption of copper from aqueous solution by chemically activated pine cone: A kinetic study. Chemical Engineering Journal, 175, 260–270.
38. Ozer, A., Ozer, D., Ozer, A. (2004). The adsorption of copper(II) ions onto dehydrated wheat bran (DWB): determination of equilibrium and thermodynamic parameters. Process Biochem. 39, 2183–2191.
39. Parvathi K., Nagendran R., Nareshkumar R. (2007). Lead biosorption onto waste beer yeast by- product, a means to decontaminate effluent generated from battery manufacturing industry. Electronic Journal of Biotechnology, Vol 10 No. 1
40. Pagnanelli F., Esposito L., Veglio F. (2003). Metal speciation and pH effect on Pb, Cu, Zn and Cd biosorption onto Sphaerotilus natans: Langmuir type empirical model. Water Res., 37, 627– 633.
41. Ronda A., Martín-Lara1 M.A., Dionisiol E., Blazquez G., Calerol M. (2013). Effect of lead in biosorption of copper by almond shell. Journal of the Taiwan Institute of Chemical Engineers, 44, 466-473.
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43. Srinivasan K., Balasubramaniam N., Ramakrishna T.V. (1998). Studies on Chromium Removal by Rice Husk Carbon. Indian Journal Environmental Health, 30 (4), 376-387.
44. Tasar, S., Kaya, F., Ozer, A. (2014). Biosorption of lead (II) ions from aqueous solution by peanut shells: Equilibrium, thermodynamic and kinetic studies. Journal of Environmental Chemical Engineering, 2, 1018–1026.
45. Tayeb, E.S., Abdelhafez, A.A., Ali, S.H., Ramadan, E.M. (2012). Effect of acid hydrolysis and fungal biotreatment on agro-industrial wastes for obtainment of free sugars for bioethanol production. Brazilian Journal of Microbiology, 1523-1535.
46. Tempkin, M.I., Pyzhev, V. (1940). Kinetics of ammonia synthesis on promoted iron catalyst. Acta Phys. Chim. 12, 327–356.
47. Volesky, B., Davis, T.A., Vieira, R.H.S.F. (2000). Sargassum seaweed as biosorbent for heavy metals, Water Research, 34 (17), 4270–4278.
48. Volesky B., Holan Z.R. (1995). Accumulation of cadmium, lead, and nickel by fungal and wood biosorbents. Appl Biochem Biotechnology, 5, 133–146.
49. Wongjunda J.and Saueprasearsit P. (2010). Biosorption of Chromium (VI) using rice husk ash and modified rice husk ash. Environmental Research Journal, vol. 4, no. 3, pp. 244–250.
50. Wood, G.O., Stampfer, J.F. (1993). Adsorption rate coefficients for gases and vapors on activated carbons, Carbon, 31, 195–200.
51. Yan C., Li G., Xue P., Wei Q., Li Q. (2010). Competitive effect of Cu(II) and Zn(II) on the biosorption of lead(II) by Myriophyllum spicatum. Journal of Hazardous Materials, 179, 721–728.
52. Yan G., Viraraghavan T. (2001). Heavy metal removal in a biosorption column by immobilized M. rouxii biomass, Bioresour. Technol. 78 (2001) 243–249.
53. Yang, J., Volesky, B. (1999). Modeling uranium – proton ion exchange in biosorption. Environ. Sci. Technol. 33, 4079–4085.
54. Yargıç A.Ş., Yarbay Şahin R.Z., Özbay N., Önal E. (2013). Assessment of toxic copper(II) biosorption from aqueous solution by chemically-treated tomato waste (Solanum lycopersicum). Journal of Cleaner Production, 1-8.
55. Yoon, Y.H. and J.H. Nelson (1984). Application of gas adsorption kinetics. I. A theoretical model for respirator CARTRIDGE service life. Am. Ind. Hyg. Assoc. J., 45: 509-516.
56. Yu, J. X., Wang, L.Y., Chi, R.A., Zhang, Y.F., Xu, Z.G., Guo, J. (2013). Competitive adsorption of Pb2+ and Cd2+ on magnetic modified sugarcane bagasse prepared by two simple steps. Applied Surface Science, 268, 163–17.
2. Ajmal, M., Rao, R.A.K., Anwar, S., Ahmad, J., Ahmad, R. (2003). Adsorption Studies on Rice Husk: Removal and Recovery of Cd (II) from Wastewater. Bioresource Tech., 86: 147- 149.
3. Aksu, Z. and F. Gonen (2004). Biosorption of phenol by immobilized activated sludge in a continuous packed bed: Prediction of breakthrough curves. Process Biochem., 39: 599-613.
4. Aksu Z. abd Isoglu A.I. (2005). Removal of copper(II) ions from aqueous solution by biosorption onto agricultural waste sugar beet pulp. J. Process Biochem, 3031–3044.
5. Annadurai, G., Juang, R.S., Lee, D.J. (2002). Adsorption of heavy metals from water using banana and orange peels. Water Science and Technology, 47(1), 185-190.
6. Ayoob, S., A.K. Gupta and P.B. Bhakat (2007). Analysis of breakthrough developments and modeling of fixed bed adsorption system for As(V) removal from water by Modified Calcined Bauxite (MCB). Sep. Purif. Technol., 52: 430-438.
7. Bahadur, K. D., Paramatma, M. (2014). Adsorptive Removal of Cr(VI) from Aqueous Solution by Sugarcane Biomass. Research Journal of Chemical Sciences., 4(5), 32-40.
8. Barka N., Abdennouri M., El Makhfouk M., Qourzal S. (2013). Biosorption characteristics of cadmium and lead onto eco-friendly dried cactus (Opuntia ficus indica) cladodes. Journal of Environmental Chemical Engineering,1, 144–149.
9. Blázquez G., Calero1 M., Hernáinz F., Tenorio G., Martín-Lara M.A. (2010). Equilibrium biosorption of lead(II) from aqueous solutions by solid waste from olive-oil production. Chemical Engineering Journal, 160, 615–622
10. Blázquez G., Martín-Lara M.A., Dionisio-Ruiz E., Tenorio G., Calero M. (2011). Evaluation and comparison of the biosorption process of copper ions onto olive stone and pine bark. Journal of Industrial and Engineering Chemistry, 17, 824–833.
11. Brown, P.A., Gill, S.A., Allen, S.J. (2000). Metal removal from wastewater using peat. Water Research, 34, 3907–3916.
12. Chuah, T.G., Jumasiah, A., Katayon, S., Thomas Choong, S.Y. (2005). Rice husk as a potentially low-cost biosorbent for heavy metal and dye removal: an overview. Desalination, 175, 305–316.
13. Dermibas, E., Kobya, M., Senturk, E., Ozkan, T. (2004). Adsorption kinetics for the removal of Cr (VI) from aqueous solutions on the activated carbon prepared from agricultural wastes. Journal of water. 30 (4), 533- 539.
14. Dwivedi C.P., Sahu, J.N., Mohanty, C.R., Mohan B., Meikap, B.C. (2008). Column performance of granular activated carbon packed bed for Pb(II) removal. Journal of Hazardous Materials. 156. 596–603
15. Esfandiar, N., Nasernejad, B., Ebadi, T. (2014). Removal of Mn (II) from groundwater by sugarcane bagasse and activated carbon (a comparative study): Application of response surface methodology (RSM). Journal of Industrial and Engineering Chemistry. 20, 3726–3736.
16. Gaballah, I., Goy, D., Allain, E., Kilbertus, G., Thauront, J. (1997). Recovery of copper through decontamination of synthetic solutions using modified barks. Met. Metall. Trans. B., 28, 13–23.
17. Goksungur, Y., Uren, S., Guvenc, U. (2005). Biosorption of cadmium and lead ions by ethanol treated waste baker’s yeast biomass. Bioresource Technology. 96, 103–109.
18. G.L. Guo, W.H. Chen, W.S. Hwang. Journal Bioresource Technology, 99 (2008), p. 6046.
19. Gurisik, E., Arica, M.Y., Bektas, S., Genc ̧ O. (2004). Comparison of the heavy metal biosorption capacity of active, heat-inactivated and NaOH-treated phanerochaete chrysosporium biosorbents. Eng. Life Sci. 4 (1), 86–89.
20. Hamza I., Martincigh B., Ngila J., Nyamori V. (2013). Adsorption studies of aqueous Pb(II) onto a sugarcane bagasse/multi-walled carbon nanotube composite. Physics and Chemistry of the Earth, 66, 157–166.
21. Han, R., Li H., Li, Y., Zhang J., Xiao H., Shi J. (2006). Biosorption of copper and lead ions by waste beer yeast. Journal of Hazardous Materials, 137, 1569– 1576.
22. Hanafiah, M.A.K.M., Ngah, W.S.W., Ibrahim, S.C., Zakaria, H., Ilias, W.A.H.W. (2006). Kinetics and thermodynamic study of lead adsorption onto rubber (Hevea brasiliensis) leaf powder. J. Appl. Sci. 6, 2762–2767.
23. Hassani, A., Vafaei, F., Karaca, S., Khataee, A.R. (2013). Adsorption of a cationic dye from aqueous solution using Turkish lignite: Kinetic, isotherm, thermodynamic studies and neural network modeling. Journal of Industrial and Engineering Chemistry. 20, 2615– 2624.
24. Homagai, P.L., Ghimire, K.N., Inoue, K. (2010). Adsorption behavior of heavy metals onto chemically modified sugarcane bagasse. Bioresour. Technol. 101, 2067–2069.
25. Kalavathy, M.H., Karthikeyan, T., Rajgopal, S., Miranda, L.R. (2005). Kinetic and isotherm studies of Cu(II) adsorption onto H3PO4-activated rubber wood sawdust, J. Colloid Interface Sci. 292 354–362.
26. Karnitz, O., Jr., Gurgel, L. V. A., Perin de Melo, J. C., Botaro, V. R., Melo, T. M. S., Gil, R.P. F., & Gil, L. F. (2007). Adsorption of heavy metal ion from aqueous solution single metal solution by chemically modified sugarcane bagasse. Bioresource Technology, 98(6), 1291–1297.
27. Karthikeyan, G., Ilango, S.S. (2007). Fluoride sorption using morringa indica-based activated carbon. Iranian Journal of Environmental Health, science and Engineering 4, 21-28.
28. Khoramzadeh, E., Nasernejad, B., Halladj, R. (2013). Mercury biosorption from aqueous solutions by Sugarcane Bagasse. Journal of the Taiwan Institute of Chemical Engineers 44 266–269.
29. Khormaei M., Nasernejad B., Edrisi M., Eslamzadeh T. (2007). Copper biosorption from aqueous solutions by sour orange residue. Journal of Hazardous Materials, 149, 269–274.
30. Kim, Y., Kim, C., Choi, I., Rengraj, S., Yi, J. (2004). Arsenic removal using mesoporous alumina prepared via a templating method, Environ. Sci. Technol. 38, 924–931.
31. Lawal O.S., Sanni A.R., Ajayi I.A., Rabiu O.O. (2010). Equilibrium, thermodynamic and kinetic studies for the biosorption of aqueous lead(II) ions onto the seed husk of Calophyllum inophyllum. Journal of Hazardous Materials, 177, 829–835.
32. Liu C., Ngo H.H., Guo W., Tung K. (2012). Optimal conditions for preparation of banana peels, sugarcane bagasse and watermelon rind in removing copper from water. Bioresource Technology, 119, 349–354.
33. Momcilovic, M., Purenovic, M., Bojic, A., Zarubica, A., Randelovic, M. (2011). Removal of lead(II) ions from aqueous solutions by adsorption onto pine cone activated carbon, Desalination 276, 53–9.
34. Mosier, N., Wyman, C., Dale, B., Elander, R., Lee, Y. Y., Holtzapple, M. and M.; Ladisch, M. (2005), Features of promising technologies for pretreatment of lignocellulosic biomass, Bioresource Technology, 96, 673–686.
35. Mudipalli, A. (2007). Lead hepatotoxicity & potential health effects. Indian J. Med. Res. 126, 518- 527.
36. Munaf E., Zein R. (1997). The Use of Rice Husk for Removal of Toxic Metals from Wastewater. Environmental Technology, 18, 359-362.
37. Ofomaja, A.E., Naidoo, E.B. (2011). Biosorption of copper from aqueous solution by chemically activated pine cone: A kinetic study. Chemical Engineering Journal, 175, 260–270.
38. Ozer, A., Ozer, D., Ozer, A. (2004). The adsorption of copper(II) ions onto dehydrated wheat bran (DWB): determination of equilibrium and thermodynamic parameters. Process Biochem. 39, 2183–2191.
39. Parvathi K., Nagendran R., Nareshkumar R. (2007). Lead biosorption onto waste beer yeast by- product, a means to decontaminate effluent generated from battery manufacturing industry. Electronic Journal of Biotechnology, Vol 10 No. 1
40. Pagnanelli F., Esposito L., Veglio F. (2003). Metal speciation and pH effect on Pb, Cu, Zn and Cd biosorption onto Sphaerotilus natans: Langmuir type empirical model. Water Res., 37, 627– 633.
41. Ronda A., Martín-Lara1 M.A., Dionisiol E., Blazquez G., Calerol M. (2013). Effect of lead in biosorption of copper by almond shell. Journal of the Taiwan Institute of Chemical Engineers, 44, 466-473.
42. Sciban, M., Kukic, D., Prodanovic, J. (2013). Potential of agro-based waste materials as adsorbents of heavy metal ions from water. Report. Sustain., 325- 329.
43. Srinivasan K., Balasubramaniam N., Ramakrishna T.V. (1998). Studies on Chromium Removal by Rice Husk Carbon. Indian Journal Environmental Health, 30 (4), 376-387.
44. Tasar, S., Kaya, F., Ozer, A. (2014). Biosorption of lead (II) ions from aqueous solution by peanut shells: Equilibrium, thermodynamic and kinetic studies. Journal of Environmental Chemical Engineering, 2, 1018–1026.
45. Tayeb, E.S., Abdelhafez, A.A., Ali, S.H., Ramadan, E.M. (2012). Effect of acid hydrolysis and fungal biotreatment on agro-industrial wastes for obtainment of free sugars for bioethanol production. Brazilian Journal of Microbiology, 1523-1535.
46. Tempkin, M.I., Pyzhev, V. (1940). Kinetics of ammonia synthesis on promoted iron catalyst. Acta Phys. Chim. 12, 327–356.
47. Volesky, B., Davis, T.A., Vieira, R.H.S.F. (2000). Sargassum seaweed as biosorbent for heavy metals, Water Research, 34 (17), 4270–4278.
48. Volesky B., Holan Z.R. (1995). Accumulation of cadmium, lead, and nickel by fungal and wood biosorbents. Appl Biochem Biotechnology, 5, 133–146.
49. Wongjunda J.and Saueprasearsit P. (2010). Biosorption of Chromium (VI) using rice husk ash and modified rice husk ash. Environmental Research Journal, vol. 4, no. 3, pp. 244–250.
50. Wood, G.O., Stampfer, J.F. (1993). Adsorption rate coefficients for gases and vapors on activated carbons, Carbon, 31, 195–200.
51. Yan C., Li G., Xue P., Wei Q., Li Q. (2010). Competitive effect of Cu(II) and Zn(II) on the biosorption of lead(II) by Myriophyllum spicatum. Journal of Hazardous Materials, 179, 721–728.
52. Yan G., Viraraghavan T. (2001). Heavy metal removal in a biosorption column by immobilized M. rouxii biomass, Bioresour. Technol. 78 (2001) 243–249.
53. Yang, J., Volesky, B. (1999). Modeling uranium – proton ion exchange in biosorption. Environ. Sci. Technol. 33, 4079–4085.
54. Yargıç A.Ş., Yarbay Şahin R.Z., Özbay N., Önal E. (2013). Assessment of toxic copper(II) biosorption from aqueous solution by chemically-treated tomato waste (Solanum lycopersicum). Journal of Cleaner Production, 1-8.
55. Yoon, Y.H. and J.H. Nelson (1984). Application of gas adsorption kinetics. I. A theoretical model for respirator CARTRIDGE service life. Am. Ind. Hyg. Assoc. J., 45: 509-516.
56. Yu, J. X., Wang, L.Y., Chi, R.A., Zhang, Y.F., Xu, Z.G., Guo, J. (2013). Competitive adsorption of Pb2+ and Cd2+ on magnetic modified sugarcane bagasse prepared by two simple steps. Applied Surface Science, 268, 163–17.
Published
2016-06-30
How to Cite
Duga, N. D. F., Imperial, P. E. A., Soriano, A. N., & Nieva, A. D. (2016). Packed Bed Biosorption of Lead and Copper Ions Using Sugarcane Bagasse. ASEAN Journal of Chemical Engineering, 16(1), 23-37. Retrieved from https://journal.ugm.ac.id/v3/AJChE/article/view/8905
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