Fabrication of Cellulose Sponge: Effects of Drying Process and Cellulose Nanofiber Deposition on the Physical Strength

  • Abdul Halim Department Department of Pulp and Paper Technology, Institute of Technology and Science Bandung
  • Yinchao Xu Department of Light Chemistry Industry, School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou, Zhejiang Province, 310023, P.R. China
  • Toshiharu Enomae Faculty of Life and Environmental Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8572, Japan
Keywords: Cellulose nanofiber, Cellulose sponge, Drying, Physical strength, Regenerated cellulose

Abstract

Cellulose sponge was fabricated by regenerating cellulose from a xanthate solution. The solution, which contained sodium phosphate particles as a template to create sponge porosity, was dried at 55, 65, 75 and 85 °C for 2, 4, 6, and 8 h. Mass transfer during the initial and last stages of drying was controlled in terms of temperature and concentration differences, respectively. The activation energy and pre-exponential factor of the mass transfer coefficient were -51,841.947 kJ mol-1 and 7.26×109 m-2 h-1, respectively. Regenerated cellulose contained a crystalline type of cellulose II, and the crystallinity was independent of drying conditions. At a low drying temperature (T≤55 °C) and short drying period (t≤2h), the cellulose was unregenerated. At higher temperatures and longer drying periods, no relationship between temperature and physical strength was observed. Cellulose nanofiber (CNF) was added to the xanthate solution at a ratio of 1:100 of CNF to linter cellulose for xanthation; however, this did not affect the physical strength of the cellulose sponge for both mechanically and chemically fabricated CNF.

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Published
2020-06-30
How to Cite
Halim, A., Xu, Y., & Enomae, T. (2020). Fabrication of Cellulose Sponge: Effects of Drying Process and Cellulose Nanofiber Deposition on the Physical Strength. ASEAN Journal of Chemical Engineering, 20(1), 1-10. Retrieved from https://journal.ugm.ac.id/v3/AJChE/article/view/9092
Section
Articles