Artikel penelitian
Vol 11 No 1 (2017): Volume 11, Number 1, 2017
Pengaruh organic loading rate pada produksi biohidrogen dari sampah buah melon (Cucumis melo L.) menggunakan reaktor alir pipa
Departemen Teknik Kimia, Fakultas Teknik Universitas Gadjah Mada Jl. Grafika No. 2, Yogyakarta, 55281
Departemen Teknik Kimia, Fakultas Teknik Universitas Gadjah Mada Jl. Grafika No. 2, Yogyakarta, 55281
Departemen Teknik Kimia, Fakultas Teknik Universitas Gadjah Mada Jl. Grafika No. 2, Yogyakarta, 55281
Abstrak
Krisis energi dan dampak buruk dari penggunaan bahan bakar fosil menuntut pengembangan sumber energi yang bersifat non-polutif dan terbarukan, misalnya bio-H2. Bio-H2 dapat di produksi dari biomassa organik seperti sampah buah melon, karena terdapat dalam jumlah banyak dan memiliki kandungan fraksi organik yang memadai. Pada penelitian ini produksi bio-H2 dari sampah buah melon dilakukan secara fermentasi gelap pada reaktor alir pipa yang terdiri dari tahap aklimatisasi mikroorganisme dan tahap pengumpanan substrat secara kontinu. Variasi organic loading rate (OLR) yang digunakan adalah 6.04 kg VS/(m3.hari) (OLR-1), 7.62 kg VS/(m3.hari) (OLR-2) dan 26.32 kg VS/(m3.hari) (OLR-3). Sampel gas dan cairan diambil dari dalam reaktor untuk di analisis kadar H2, kadar volatile solid (VS) dan volatile fatty acid (VFA). Hasil penelitian menunjukkan bahwa produksi bio-H2 yang optimal sebesar 90.89 mL/g VS pada variasi OLR-3 yaitu 26.32 kg VS/(m3.hari) dengan efisiensi degradasi substrat mencapai 45.39%. Konsentrasi asam-asam organik yang dihasilkan berkisar antara 400-800 mg/L dan asam asetat adalah sebagai produk yang dominan dengan konsentrasi rata-rata sebesar 442.93 mg/L.
Referensi
Arimi, M. M., Knodel, J., Kiprop, A., Namango, S. S., Zhang, Y. and Geiβen, Sven-Uwe, 2015, "Strategies for Improvement of Biohydrogen Production from Organic-Rich Wastewater: A Review," Biomass and Bioenergy, 75, 101-118.
Baghchehsaraee, B., 2009, "Batch and Continuous Biohydrogen Production Using Mixed Microbial Culture," Dissertation, The University of Western Ontario, Canada.
Beltran, F. J., Garcia-Araya, J. F., and Alvarez, P. M., 1999, "Wine Distillery Wastewater Degradation: Improvement of Aerobic Biodegradation by Means of an Integrated Chemical (Ozone)-biological Treatment," Journal of Agricultural and Food Chemistry, 47 (9), 3919-24.
Chen, C. C., Lin, C. Y., and Lin, M. C., 2002, "Acid-base Enrichment Enhances Anaerobic Hydrogen Production Process," Appl Microbiol Biotechnol, 58(2), 224-8.
Fan, K. S., 2006, "Effect of Hydraulic Retention Time on Anaerobic Hydrogenesis in CSTR," Bioresource Technology, 97, 84-9.
Hu, C. C., Giannis, A., Chen, Chia-Lung, Qi, W., and Wang, Jing-Yuan, 2013, "Comparative Study of Biohydrogen Production by Four Dark Fermentative Bacteria," Int. J. Hydrogen Energy, 38, 15686-15692.
Hussy, I., Hawkes, F. R., Dinsdale, R., and Hawkes, D. L., 2003, "Continuous Fermentative Hydrogen Production from a Wheat Starch Co-Product by Mixed Microflora," Biotech Bioeng, 84(6), 619-26.
Hwang, M. H., Jang, N. J., Hyun, S. H., and Kim, I. S., 2004, "Anaerobic Biohydrogen Production from Ethanol Fermentation: The Role of pH," J. Biotechnol, 111(3), 297-309.
Kinyua, M. N., 2013, "Effect of Solids Retention Time on the Denitrification Potential of Anaerobically Digested Swine Waste," Theses and Dissertations, University of South Florida, USA.
Logan, B. E., 2004, "Extracting Hydrogen and Electricity from Renewable Resources," Enviromental Sci. Tech., 38(9), 160-7.
Mariakakis, I., Bischoff, P., Krampe, J., Meyer, C. and Steinmetz, H., 2011, "Effect of Organic Loading Rate and Solids Retention Time on Microbial Population During Biohydrogen Production by Dark Fermentation in Large Lab-scale," Int. J. Hydrogen Energy, 36(17), 10690-700.
Ozmihci, S., and Kargi, F., 2011, "Dark Fermentative Biohydrogen Production from Wheat Starch Using Co-Culture with Periodic Feeding: Effects of Substrate Loading Rate," Int. J. of Hydrogen Energy, 36, pp. 7089-7093.
Prabhudessai, V., 2013, "Anaerobic Digestion of Food Waste in a Horizontal Plug Flow Reactor," Thesis, Institute of Technology and Science Pilani (Rajasthan), India.
Vijayaraghavan, K., Ahmad, D., and Bin Ibrahim, M. K., 2006, "Biohydrogen Generation from Jackfruit Peel Using Anaerobic Contact Filter," Int. J. Hydrogen, 31, 569-579.