Chalcone Based Colorimetric Sensor for Anions: Experimental and TD-DFT Study

https://doi.org/10.22146/ijc.21181

Adita Silvia Fitriana(1), Harno Dwi Pranowo(2), Bambang Purwono(3*)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(*) Corresponding Author

Abstract


The interactions between sensor chalcone of 3-(4-hydroxy-3-methoxyphenyl)-1-phenyl-2-propen-1-one (1) and anions (F–, Cl–, Br–, CN–, CO32–, and SO42–) have been experimentally and TD-DFT theoretically investigated. Sensor (1) showed a naked-eye detectable color change from yellow to red upon addition of F–, CO32–, CN–, and SO42– anions in DMSO, whereas no significant color change was observed upon addition of Cl– and Br– anions. The interaction models were predicted by optimizing (1)-anion complex using DFT/B3LYP method. Optimized (1)-anion complexes showed that sensor (1) was deprotonated by CO32–, CN–, F–, and SO42–. The formation of deprotonated sensor (1)– was responsible for the colorimetric signaling. Absorption spectra of neutral and deprotonated sensor were calculated using TD-DFT method. The calculated spectra were in good agreement with experimental results.

Keywords


chalcone; anion sensor; DFT; colorimetric

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References

[1] Reena, V., Suganya, S., and Velmathi, S., 2013, J. Fluorine Chem., 153, 89–95.

[2] Chen, H., Sun, Y., Zhou, C., Cao, D., Liu, Z., and Ma, L., 2013, Spectrochim. Acta, Part A, 116, 389–393.

[3] Liu, X-M., Zhao, Q., Li, Y., Song, W-C., Li, Y-P., Chang, Z., and Bu, X-H., 2013, Chinese Chem. Lett., 24 (11), 962–966.

[4] Yadav, U.N., Pant, P., Sharma, D., Sahoo, S.K., and Shankarling, G.S., 2014, Sens. Actuators, B, 197, 73–80.

[5] Marini, V.G., Zimmermann, L.M., and Marchado, V.G., 2010, Spectrochim. Acta, Part A, 75 (2), 799–806.

[6] Jin, R., 2012, Theor. Chem. Acc., 131, 1260–1270.

[7] Kumari, N., Jha, S., and Bhattacharya, S., 2011, J. Org. Chem., 76 (20), 8215–8222.

[8] Thiagarajan, V., Ramamurthy, P., Thirumalai, D., and Ramakrishnan, V.T., 2005, Org. Lett., 7 (4), 657–660.

[9] Peng, X., Wu, Y., Fan, J., Tian, M., and Han, K., 2005, J. Org. Chem., 70 (25), 10524–10531.

[10] Vadavi, R.S., Kim, H., Lee, K.M., Kim, T., Lee, J., Lee, Y.S., and Lee, M.H., 2012, Organometallics, 31 (1), 31–34.

[11] Sun, Y., Chen, H., Cao, D., Liu, Z., Chen, H., Deng, Y., and Fang, Q., 2012, J. Photochem. Photobiol., A, 244, 65–70.

[12] Shan, Y., Liu, Z., Cao, D., Sun, Y., Wang, K., and Chen, H., 2014, Sens. Actuators, B, 198, 15–19.

[13] Anggraini, S., 2012, Bachelor Thesis, Department of Chemistry, Universitas Gadjah Mada, Yogyakarta, Indonesia.

[14] Steiner, T., 2002, Angew. Chem. Int. Ed., 41 (1), 48–76.

[15] Wong, M.W., Xie, H., and Kwa, S.T., 2013, J. Mol. Model, 19 (1), 205–213.

[16] Jin, R., Sun, W., and Tang, S., 2012, Int. J. Mol. Sci., 13 (9), 10986–10999.

[17] Jin, R., and Irfan, A., 2012, Comput. Theor. Chem., 986, 93–98.

[18] Hadisaputra, S., Canaval, L.R., Pranowo, H.D., and Armunanto, R., 2014, Indones. J. Chem., 14 (2), 199–208.



DOI: https://doi.org/10.22146/ijc.21181

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