Isothermal Vapor-Liquid Equilibrium of Methanol + Glycerol and 1-Propanol + Glycerol

https://doi.org/10.22146/ijc.21186

Annas Wiguno(1*), Asalil Mustain(2), Wahyu Fazar Eka Irwansyah(3), Gede Wibawa(4)

(1) Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Kampus ITS Sukolilo Surabaya 60111
(2) Department of Chemical Engineering, State Polytechnic of Malang, Jl. Soekarno Hatta No. 9, Malang 65141
(3) Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Kampus ITS Sukolilo Surabaya 60111
(4) Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Kampus ITS Sukolilo Surabaya 60111
(*) Corresponding Author

Abstract


Isothermal vapor-liquid equilibrium (VLE) data for two binary mixtures of methanol + glycerol and 1-propanol + glycerol were determined at the temperature range from (313.15 to 363.15) K using a simple quasi-static ebulliometer. All systems showed that the vapor pressures increased with increasing alcohols (methanol or 1-propanol) concentrations at corresponding system. The Wilson, Non-Random Two-Liquid (NRTL) and Universal Quasi-Chemical (UNIQUAC) activity coefficient models were used to correlate the experimental data. Both systems showed slightly deviations from the ideal liquid phase behavior.

Keywords


vapor-liquid equilibrium; binary mixtures; methanol; 1-propanol; glycerol

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References

[1] Veljković, V.B., Banković-Ilić, I.B., and Stamenković, O.S., 2015, Renewable Sustainable Energy Rev., 49, 500–516.

[2] Atadashi, I.M., Aroua, M.K., and Aziz, A.A., 2011, Renewable Energy, 36 (2), 437–443.

[3] Kuss, V.V., Kuss, A.V., da Rosa, R.G., Aranda, D.A.G., and Cruz, Y.R., 2015, Renewable Sustainable Energy Rev., 50, 1013–1020.

[4] Alptekin, E., Canakci, M., and Sanli, H., 2014, Waste Manage., 34 (11), 2146–2154.

[5] Bhatti, H.N., Hanif, M.A., Qasim, M., and Ata-ur-Rehman, 2008, Fuel, 87 (13-14), 2961–2966.

[6] López, B.C., Cerdán, L.E., Medina, A.R., López, E.N., Valverde, L.M., Peña, E.H., Moreno, P.A.G., Grima, E.M., 2015, J. Biosci. Bioeng., 119 (6), 706–711.

[7] Saleh, J., Tremblay, A.Y., and Dubé, M.A., 2010, Fuel, 89 (9), 2260–2266.

[8] Qadariyah, L., Mahfud, Sumarno, Machmudah, S., Wahyudiono, Sasaki, M., and Goto, M., 2011, Bioresour. Technol., 102 (19), 9267–9271.

[9] Oliveira, M.B., Teles, A.R.R., Queimada, A.J., and Coutinho, J.A.P., 2009, Fluid Phase Equilib., 280 (1-2), 22–29.

[10] Soujanya, J., Satyavathi, B., and Prasad, T.E.V., 2010, J. Chem. Thermodyn., 42 (5), 621–624.

[11] Veneral, J.G., Benazzi, T., Mazutti, M.A., Voll, F.A.P., Cardozo-Filho, L., Corazza, M.L., Guirardello, R., and Oliveira, J.V., 2013, J. Chem. Thermodyn., 58, 398–404.

[12] Shimoyama, Y., Abeta, T., Zhao, L., and Iwai, Y., 2009, Fluid Phase Equilib., 284 (1), 64–69.

[13] Wibawa, G., Mustain, A., Akbarina, M.F., and Ruslim, R.M., 2015, J. Chem. Eng. Data, 60 (3), 955–959.

[14] Chen, R., Ding, H., Liu, M., Qi, J., Zhou, H., and Chen, N., 2014, Fluid Phase Equilib., 382, 133–138.

[15] Yang, Z., Xia, S., Shang, Q., Yan, F., and Ma, P., 2014, J. Chem. Eng. Data, 59 (3), 825–831.

[16] Yang, C., Sun, Y., Qin, Z., Feng, Y., Zhang, P., and Feng, X., 2014, J. Chem. Eng. Data, 59 (4), 1273–1280.

[17] Zhang, L., Wu, W., Sun, Y., Li, L., Jiang, B., Li, X., Yang, N., and Ding, H., 2013, J. Chem. Eng. Data, 58 (5), 1308–1315.

[18] Wilson, G.M., 1964, J. Am. Chem. Soc., 86 (2), 127–130.

[19] Renon, H., and Prausnitz, J.M., 1968, AlChE J., 14 (1), 135–144.

[20] Abrams, D.S., and Prausnitz, J.M., 1975, AlChE J., 21, 1, 116-128.

[21] Oktavian, R., Amidelsi, V., Rasmito, A., and Wibawa, G., 2013, Fuel, 107, 47–51.

[22] Zharov, V.T., and Pervukhin, O.K., 1972, Zh. Fiz. Khim., 46, 1970–1973.

[23] Barker, J.A., 1953, Aust. J. Chem., 6 (3), 207–210.

[24] Poling, B.E., Prausnitz, J.M., and O’Connell, J.P., 2001, The Properties of Gases and Liquids, 5th Ed., McGraw-Hill, New York.

[25] Gómez, E., Calvar, N., Macedo, E.A., and Domínguez, Á., 2012, J. Chem. Thermodyn., 45 (1), 9–15.

[26] Segade, L., de Llano, J.J., Domínguez-Pérez, M., Cabeza, Ó., Cabanas, M., and Jiménez, E., 2003, J. Chem. Eng. Data, 48 (5), 1251–1255.

[27] Reid, R.C., Prausnitz, J.M., and Poling, B.E., 1987, The Properties of Gases and Liquids, 4th Ed., McGraw-Hill, New York.

[28] Ge, M-L., Ma, J-L., and Chu, B., 2010, J. Chem. Eng. Data, 55 (7), 2649–2651.

[29] Hansen, H.K., Rasmussen, P., Fredenslund, A., Schiller, M., and Gmehling, J., 1991, Ind. Eng. Chem. Res., 30 (10), 2352–2355.



DOI: https://doi.org/10.22146/ijc.21186

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