Detection of Hg2+ Metal Ions Using Silver Nanoparticles Stabilized by Gelatin and Tween-20

https://doi.org/10.22146/ijc.21216

Lilis Sulistiawaty(1), Sri Sugiarti(2*), Noviyan Darmawan(3)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Kampus IPB Darmaga, Jl. Agatis Wing 2 Level 4, Bogor 16144
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Kampus IPB Darmaga, Jl. Agatis Wing 2 Level 4, Bogor 16144
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Kampus IPB Darmaga, Jl. Agatis Wing 2 Level 4, Bogor 16144
(*) Corresponding Author

Abstract


Silver nanoparticles were synthesized by reduction method using glucose as reducing agent for precursor AgNO3. This research was aimed at comparing the stability and performance of silver nanoparticles with stabilizer gelatin (Gelatin-AgNPs) and tween-20 (Tween-AgNPs) produced from the synthesis to the silver nanoparticles without stabilizer, and applying the Gelatin-AgNPs and Tween-AgNPs to detect heavy metal in water sample. The silver nanoparticles produced were characterized using UV-Vis spectrophotometer and Transmission Electron Microscopy (TEM). From measurement of UV-Vis spectrophotometer, the absorbance wavelength of silver nanoparticles (AgNPs) appeared in range 411 nm, Gelatin-AgNPs in 417 nm, and Tween-AgNPs in 420 nm. The identification using TEM showed the average size for each AgNPs, Gelatin-AgNPs, and Tween-AgNPs was 11.73, 9.68, and 17.54 nm, respectively. The result showed that Gelatin-AgNPs has better stability compared to Tween-AgNPs. The reaction of Gelatin-AgNPs and Tween-AgNPs with several ions showed color changes of Gelatin-AgNPs and Tween-AgNPs occurred only on addition to Hg2+ metal ions solution. Based on the experiment of Hg2+ metal ions determination this method has limit of detection of 0.45 mg/L for Gelatin-AgNPs and 0.13 mg/L for Tween-AgNPs.

Keywords


silver nanoparticles; glucose; gelatin; tween-20

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References

[1] Tolaymat, T.M., El-Badawy, A.M., Genaidy, A., Sheckel, K.G., Luxton, T.P., and Suidan, M., 2010, Sci. Total Environ., 408(5), 999–1006

[2] Anna Zielińska, A., Skwarek, E., Zaleska, A., Gazda, M., and Hupka, J., 2009, Procedia Chem., 1(2), 1560–1566.

[3] Li, H., and Bian, Y., 2009, Nanotechnology, 20(14), 145502–145507.

[4] Khanna, P.K., Singh, N., Charan, S., and Viswanath, A.K., 2005, Mater. Chem. Phys., 92(1), 214–219.

[5] Zhang, J.P., Sheng, L.Q., and Chen, P, 2003, Chin. Chem. Lett., 14(6), 645–648.

[6] Zhang, Y., Yang, D., Kong, Y., Way, X., Randoli, O., and Gao, G, 2010, Nano Biomed. Eng., 2(4), 252–257.

[7] Cai, J., Kimura, S., Wada, M., and Kuga, S, 2009, Biomacromolecules, 10(1), 87–94.

[8] Raveendran, P., Fu. J., and Wallen, S.L., 2003, J. Am. Chem. Soc., 125(46), 13940–13941.

[9] Singh, C., Baboota, R.K., Naik, P.K., and Singh, H, 2012, Adv. Mater. Lett., 3(4), 279–285.

[10] Roh, J., Shim, J., Kim, Y., 2011, Colorimetric detection of metal ions with tween coated gold nanoparticle, Proceeding on the 18th International Conference on Composite Materials, 21-26 August, South Korea.

[11] Darroudi, M., Ahmad, M., Abdullah, A.H., Ibrahim, N.A., and Shameli, K, 2010, Int. J. Mol. Sci., 11(10), 3898–3905.

[12] Darroudi, M., Ahmad, M., Abdullah, A.H., and Ibrahim, N.A, 2011, Int. J. Nanomed., 6, 569–574.

[13] Timberlake, K.C, 2010, General, Organic, and Biological Chemistry: Structure of Life, 3rd ed., Prentice Hall, New York.

[14] Shankar, S.S., Rai, A., Ahmad, A., and Sastry, M., 2004, J. Colloid Interface Sci., 275(2), 496–502.

[15] Samberg, M.E., Oldenbrg, S.J, and Monteiro-Riviere, N.A., 2010, Environ. Health Perspect., 118(3), 407-413.

[16] Solomon, S.D., Bahadory, M., Jeyarajasingam, A.V., Rutkowsky, S.A., Boritz, C., and Mulfinger, L., 2007, J. Chem. Educ., 84(2), 322–325.

[17] Jiang, H., Moon, K., Zhang, Z., Pothukuchi, S., and Wong, C.P., 2006, J. Nanopart. Res., 8(1), 117–124.

[18] Jiang, Z.L., Feng, Z.W., and Shen, X.C, 2001, Chin. Chem. Lett., 12(6), 551–554.

[19] Alexandridis, P., 2011, Chem. Eng. Technol., 34(1), 15–28.

[20] Oluwafemi, O.S., Lucwaba, Y., Gura, A., Masabeya, M., Ncapayi, V., Olujimi, O.O., and Songca, S.P, 2013, Colloids Surf., B, 102, 718–723.

[21] Xiong, D., and Li, H, 2008, Nanotechnology, 19(46), 465502-465507.

[22] Eurachem, 1998, The Fitness for purpose of analytical method: A Laboratory guide to method validation and related topics, Eurachem Guide, http://www.eurachem.org.



DOI: https://doi.org/10.22146/ijc.21216

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