Synthesis of Pb(II) Imprinted Carboxymethyl Chitosan and the Application as Sorbent for Pb(II) Ion

https://doi.org/10.22146/ijc.21252

Abu Masykur(1*), Sri Juari Santosa(2), Dwi Siswanta(3), Jumina Jumina(4)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami 36A Surakarta 57126
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara Kotak Pos BLS 21, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara Kotak Pos BLS 21, Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara Kotak Pos BLS 21, Yogyakarta 55281
(*) Corresponding Author

Abstract


The aims of this research is to synthesize Pb(II) imprinted polymers with carboxymethyl chitosan (CMC) as polymers and bisphenol A diglycidyl ether (BADGE) as cross-linker (Pb-IIP). Chitosan (CTS), non imprinted polymer (NIP) and Pb-IIP were characterized using infrared (IR) spectroscopy, X-ray diffraction (XRD), surface area analyzer (SAA), scanning electron microscopy (SEM), and energy dispersive X-ray (EDX) spectroscopy. The result showed that the adsorption was optimum at pH 5 and contact time of 250 min. Adsorption of Pb(II) ion with all of adsorbents followed pseudo-second order kinetic equation. Adsorption of Pb(II) ion on CTS followed Freundlich isotherm while that on NIP and Pb-IIP followed the Langmuir adsorption isotherm. The adsorbent of Pb-IIP give higher capacity than the NIP and CTS. Adsorption capacity of Pb-IIP, NIP and CTS were 167.1, 128.9 and 76.1 mg/g, respectively. NIP gave higher adsorption selectivity for Pb(II)/Ni(II) and Pb(II)/Cu(II), whereas Pb-IIP showed higher adsorption selectivity for Pb(II)/Cd(II).The hydrogen bonding dominated interaction between Pb(II) ion on NIP and Pb-IIP.

Keywords


ion imprinted polymers; carboxymethyl chitosan; BADGE; adsorption; Pb(II) ion

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References

[1] Li, N., and Bai, R., 2005, Ind. Eng. Chem. Res., 44 (17), 6692–6700.

[2] Yan, H., Dai, J., Yang, Z., Yang, H. and Cheng, R., 2011, Chem. Eng. J., 174 (2-3), 586–594.

[3] Ghaee, A., Shariaty-Niassar, M., Barzin, J., and Zarghan, A., 2012, Appl. Surf. Sci., 258 (19), 7732–7743.

[4] Sölener, M., Tunali, S., Özcan A.S., Özcan, A., and Gedikbey, T., 2008, Desalination, 223 (1-3), 308–322.

[5] Farag, S., and Kareem, S.S.A., 2009, Carbohydr. Polym., 78 (2), 263–267.

[6] Suguna, M., Kumar, S.S., Reddy, A.S., Boddu, V.M., and Krishnaiah, A., 2011, Can. J. Chem. Eng., 89 (4), 833–843.

[7] Guibal, E., 2004, Sep. Purif. Technol., 38 (1), 43–74.

[8] Hasan, S., Krishnaiah, A., Ghosh T.K., Viswanath, D.S., Boddu, V.M., and Smith, E.D., 2006, Ind. Eng. Chem. Res., 45 (14), 5066–5077.

[9] de Mello, K.G.P.C, Bernusso, L.C., Pitombo, R.N.M., and Polakiewicz, B., 2006, Braz. Arch. Biol. Technol., 49 (4), 665–668.

[10] Miretzky, P., and Cirelli, A.F., 2009, J. Hazard. Mater., 167 (1-3), 10–23.

[11] Copello, G.J., Varela, F., Vivot, M., and Diaz, L.E., 2008, Bioresour. Technol., 99 (14), 6538–6544.

[12] Zhu, H.Y., Fu, Y.Q., Jiang, R., Yao, J., Xiao, L., and Zeng, G.M., 2012, Bioresour. Technol., 105, 24–30.

[13] Chen, A.H., Liu, S.C., Chen, C.Y., and Chen, C.Y., 2008, J. Hazard. Mater., 154 (1-3), 184–191.

[14] Zhang, Q., Deng, S., Yu, G., and Huang, J., 2011, Bioresour. Technol., 102 (3), 2265–2271.

[15] Santoso, U.T., Umaningrum, D., Irawati, U., and Nurmasari, R., 2008, Indo. J. Chem., 8 (2), 177–183.

[16] Oshita, K., Seo, K., Sabarudin, A., Oshima, M., Takayanagi, T., and Motomizu, S., 2008, Anal. Bioanal. Chem., 390, 1927–1932.

[17] Katarina, R.S., Takayanagi, T., Oshita, K., Oshima, M., and Motomizu, S., 2008, Anal. Sci., 24 (12), 1537–1544.

[18] Sabarudin, A., Noguchi, O., Oshima, M., Higuchi, K., and Motomizu, S., 2007, Microchim. Acta, 159 (3-4), 341–348.

[19] Ma, X., Chen, R., Zheng, X., Youn, H., and Chen, Z., 2011, Polym. Bull., 66 (6), 853–863.

[20] Liu, B., Wang, D., Xu, Y., and Huang, H., 2011, J. Mater. Sci., 46 (5), 1535–1541.

[21] Song, X., Li, C., and Wang, K., 2012, Ind. Eng. Chem. Res., 51 (34), 11261–11265.

[22] Nishad, P.A., Bhaskarapillai, A., Velmurugan, S., and Narasimhan, S.V., 2012, Carbohydr. Polym., 87 (4), 2690–2696.

[23] Wang, L., Xing, R., Liu, S., Qin, Y., Li, K., Yu, H., Li, R., and Li, P., 2010, Carbohydr. Polym., 81 (2), 305–310.

[24] Liu, B., Wang, D., Gao, X., Zhang, L., Xu, Y., and Li, Y., 2010, Eur. Food Res. Technol., 232 (5), 911–917.

[25] Buhani, Suharso, and Aprilia L., 2012, Indo. J. Chem., 12 (1), 94–99.

[26] Wang, L., Li, Q., and Wang, A., 2010, Polym. Bull., 65 (9), 961–975.

[27] Chen, X.G., and Park, H.J., 2003, Carbohydr. Polym., 53 (4), 355–359.

[28] Silverstein, R.M., Basler, G.C., dan Morril, T.C., 1991, Spectrometric Identification of Organic Compounds, 5th ed., John Wiley & Sons Inc., Toronto

[29] Qi, J., Li, X., Li, Y., Zhu, J., and Qiang, L., 2008, Front. Chem. Eng. Chin., 2 (1), 109–114.

[30] Zhang, Y., Xue, Y., Gao, R., and Zhang, X., 2005, Carbohydr. Res., 340 (11), 1914–1917.

[31] Jiao, T.F., Zhou, J., Zhou, J.X., Gao, L.H., Xing, Y.Y., and Li, X.H., 2011, Iran. Polym. J., 20 (2), 123–136.

[32] Santoso, U.T., Nurmasari, R., Umaningrum, D., Santosa, S.J., Rusdiarso, B., and Siswanta, D, 2012, Indo. J. Chem., 12 (1), 35–42.

[33] Mourya, V.K., Inamdar, N.N., and Tiwari, A., 2010, Adv. Mater. Lett., 1 (1), 11–13.

[34] Reddy, A.S., and Sastry, G.N., 2005, J. Phys. Chem. A, 109 (39), 8893–8903.

[35] Qiu, H., Lu, L.V., Pan, B.C., Zhang, Q.J., Zhang, W.M., and Zhang, Q.X., 2009, J. Zhejiang Univ. Sci. A., 10 (5), 716–724.

[36] Ho, Y.S., and McKay, G., 1999, Process Biochem., 34, 451–465.

[37] Huheey, J.E., 1993, Inorganic Chemistry: Principal of Structure and Reactivity, 4th ed., Harper Collins College Publisher, New York.

[38] Trivedi, P., Axe, L., and Dyer, J., 2001, Colloids Surf., A, 191 (1-2), 107–121.

[39] Bunting, J, and Thong, K., 1971, Can. J. Chem., 48, 1654–1661.

[40] Buhani, Narsito, Nuryono, Kunarti. E. S., 2010, Desalination, 251, 83–89.



DOI: https://doi.org/10.22146/ijc.21252

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