SYNTHESIS, CHARACTERIZATION AND APPLICATION OF DIATOMACEOUS EARTH – 4,4-DIAMINODIPHENYLETHER-O-HYDROXYBENZALDEHYDE AS AN ADSORBENT OF Ag(I) METAL ION

https://doi.org/10.22146/ijc.21436

Ahmad Fatoni(1*), Soerja Koesnarpadi(2), Nurlisa Hidayati(3)

(1) Department of Chemistry, Mulawarman University, Jln. Barong Tongkok No. 4 Kampus Gunung Kelua Samarinda, East Kalimantan 75123
(2) Department of Chemistry, Mulawarman University, Jln. Barong Tongkok No. 4 Kampus Gunung Kelua Samarinda, East Kalimantan 75123
(3) Department of Chemistry, Sriwijaya University, Jln. Palembang-Prabumulih Km. 32 Indralaya Ogan Ilir South Sumatera
(*) Corresponding Author

Abstract


Synthesis, characterization and application of Diatomaceous Earth-4,4-Diamino diphenylether-O-Hydroxybenzaldehyde (diatomaceous earth-DDE-O-Hb) as an adsorbent of Ag(I) metal ion has been done. The aim of the purification of natural diatomaceous earth with KMnO4, H2SO4 and HCl were to obtain pure diatomaceous earth, remove the other compounds and de-alumination, respectively. The adsorbent of diatomaceous earth-DDE-O-Hb was synthesized by reacting pure diatomaceous earth with 3-chloropropyltrimethoxysilane, 4,4-diaminodiphenylether (DDE) and O-hydroxybenzaldehyde (O-Hb). The FTIR spectroscopy was used to identify Schiff base group in diatomaceous earth-DDE-O-Hb adsorbent. The diatomaceous earth-DDE-O-Hb was applied as adsorbent in the adsorption of Ag(I) metal ion. Parameters influencing the interaction such as time, pH and concentration were optimized. The result showed that diatomaceous earth-DDE-O-Hb adsorbent have Schiff base group. The interaction time of 90 min showed that 70.79% of Ag(I) metal ions at the concentration of 100 ppm can be adsorbed by diatomaceous earth-DDE-O-Hb adsorbent. At the pH solution between 2 to 7, the concentration of 100 ppm of Ag(I) metal ion that can adsorbed by diatomaceous earth-DDE-O-Hb adsorbent was up to 98% and at the concentration of 25 ppm Ag(I) metal ion, the adsorption of Ag(I) by diatomaceous earth-DDE-O-Hb adsorbent was near 91%.

Keywords


Synthesis; characterization; diatomaceous earth-DDE-O-Hb adsorbent; Ag(I) metal ion

Full Text:

Full Text PDF


References

[1] Dey, R.K., Jha, U., Singh, A.C., Samal, A.S., and Ray, A.R., 2006, Anal. Sci., 22, 8, 1105–1110.

[2] Filho, N.L.D; Gushikem, Y and Polito, W.L, 1995, Anal. Chim. Acta, 306, 1, 167–172.

[3] Alcantara, I.L., Roldan, P.S., Castro, G.R., Moraes, F.V., Silva, F.A., Padilha, C.C.F., Oliveiera, J.D., and Padilha, P.M., 2004, Anal. Sci., 20, 7, 1029–1032.

[4] Liang, P., and Chen, X., 2005, Anal. Sci., 21, 10, 1185–1188.

[5] Mostafa, G.A.E., Hassanien, M.M., Abou El-Sherbini, K.S, and Gorlitz, V., 2003, Anal. Sci., 19, 8, 1151–1156.

[6] Osman, M.M., Kholeif, S.A., Abou-Almaaty, N.A., and Mahmoud, M.E., 2004, Anal. Sci., 20, 5, 847–852.

[7] Filho, N.L.D.; Do-Carmo, D.R.; Caetano, L., and Rosa, A.H., 2005, Anal. Sci., 21, 11, 1359–1363.

[8] Zhang, N., Huang, C., and Hu, B., 2007, Anal. Sci., 23, 8, 997-1002.

[9] Budiman, H., Sri, H.K.F., and Setiawan, A.H, 2009, Electron. J. Chem., 6, 1, 141–150.

[10] Nuryono, Nuzula, F., and Narsito, 2008, J. Alchemy, 7, 1, 1–8.

[11] Tai, X.; Yin, X.; Chen, Q., and Tan, M., 2003, Molecules, 8, 439–443.

[12] Nair, R., Shah, A., Baluja, S., and Chanda, S., 2006, J. Serb. Chem. Soc, 71, 7, 733–744.

[13] Yi, Y., Wei, X., Qiang, X., Ming, G., and Lu, Z.Y., 2004, Chin. Chem. Lett., 15, 5, 525–528.

[14] Liu, J.N.; Wu, B.W.; Zhang, B., and Liu, Y.C., 2006, Turk. J. Chem., 30, 41–48.

[15] Payhghadr, M., Babaei, A.A., Saghatforoush, L., and Ashrafi, F., 2009, Afr. J. Pure Appl. Chem., 3, 5, 92–97.

[16] Hidayati, N, 2007, Jurnal Kimia Mulawarman, 5, 1, 4–7.

[17] El-Aziz Akl, M.A., Kenawy, I.M., and Lasheen, R.R., 2005, Anal. Sci., 21, 923–931.

[18] Jal, P.K., Patel, S., and Mishra, B.K., 2004, Talanta 62, 5, 1005–1028.

[19] Sastrohamidjojo, H, 1992, Spektroskopi Inframerah, Liberty, Yogyakarta.

[20] Silverstein, R.M., Bassler, G.C., and Morril, C.T., 1991, Spectrometric Identification of Organic Compounds, 5th ed., John Wiley and Sons Inc., New York, 91–162.

[21] Li, J.; He, F. and Jiang, C., 2006, Anal. Sci., 22, 607–611.

[22] Andersen, O., 1984, Environ. Health Perspect., 54, 249–266.

[23] Huheey, J.E. Keiter, E.A., and Keiter, R.L, 1993, Inorganic Chemistry, 4th ed., HarperCollins College Publisher, New York.

[24] Santosa, S.J., Sudiono, S., and Sujandi, S., 2006, e-J. Surf. Sci. Nanotechnol., 4, 602–608.



DOI: https://doi.org/10.22146/ijc.21436

Article Metrics

Abstract views : 2276 | views : 1569


Copyright (c) 2010 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.