PREPARATION, CHARACTERIZATION, AND CATALYTIC ACTIVITY TEST OF Ni-Mo/NATURAL ZEOLITE ON PYRIDINE HYDRODENITROGENATION

https://doi.org/10.22146/ijc.21438

Sri Kadarwati(1*), Sri Wahyuni(2), Wega Trisunaryanti(3), Triyono Triyono(4)

(1) Department of Chemistry, Semarang State University, Kampus Sekaran Gunungpati Semarang 50229
(2) Department of Chemistry, Semarang State University, Kampus Sekaran Gunungpati Semarang 50229
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Kotak Pos 21 Bls Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences,Universitas Gadjah Mada, Jl. Sekip Utara, Pos Box: BLS 21, Yogyakarta 55281
(*) Corresponding Author

Abstract


Preparation, characterization, and catalytic activity test of Ni-Mo/natural zeolite on pyridine hydrodenitrogenation were carried out. Preparation of catalyst was conducted by impregnation method using nickel nitrate hexahydrate and ammonium heptamolibdate precursor as Ni and Mo source respectively. Characterization of catalyst was conducted by using gravimetry, atomic absorption spectrophotometry, and X-ray diffraction method. Catalytic activity test on pyridine hydrodenitrogenation was carried out by using flow system reactor with hydrogen flow rate variable. The research results showed that the catalyst's total acidity and crystallinity are increased with level of impregnation success of 96.71% and 90.08% respectively. Ni-Mo/natural zeolites able to increase the catalytic conversion up to 71.78% at 350 °C and hydrogen flow rate of 10 mL/min with more highly varied product distribution. Assuming that the pyridine hydrodenitrogenation follows the pseudo first order kinetics.

Keywords


hydrodenitrogenation; pyridine; Ni-Mo/natural zeolite

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References

[1] Sardhar Basha, S.J., Vijayan, P., Suresh, C., Santhanaraj, D., and Shanthi, K., 2009, Ind. Eng. Chem. Res., 48, 6, 2774–2780.

[2] Wangliang, L.Y.L., Cui Min, L.C., and Chenguang, L., 2004, Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem., 49, 1, 63–68.

[3] Moore, J.W., and Pearson, R.G., 1981, Kinetics and Mechanisms, 3th ed., John Wiley and Sons, Inc., Canada.

[4] Qiang, Z., Yi, L., Ling, H., Wei-zhong, Q., Guo-hua, L., and Fei, W., 2008, New Carbon Mater., 23, 4, 319–325.

[5] Montesinos-Castellanos, A., and Zepeda, T.A., 2008, Microporous Mesoporous Mater., 113, 146–162.

[6] Sarbak, Z., 2001, Appl. Catal. A, 216, 1-2, 9–12.

[7] Nagai, M., Goto, Y., Irisawa, A., and Omi, S., 2000, J. Catal., 191, 128–137.

[8] Nasution, J.G.P., 2007, Pembuatan Katalis Naphta Hydrotreating Berbasis Nikel-Molybdenum dan Berpenyangga Lempung Berpilar, Thesis, Institut Teknologi Bandung

[9] Oyekunle, L.O., and Edafe, O.A., 2009, Pet. Sci. Technol., 27, 6, 557–567.

[10] Qu, L., Flechsenhar, M., and Prins, R., 2003, J. Catal., 217, 2, 284–291.

[11] Rota, F., and Prins, R., 2001, J. Catal., 202, 1, 195–199.

[12] Szymańska, A., Lewandowski, M., Sayag, C., and Djéga-Mariadassou, G., 2003, J. Catal., 218, 1, 24–31.

[13] Thiollier, A., Afanasiev, P., Cattenot, M., and Vrinat, M., 1998, Catal. Lett., 55, 1, 39–45.

[14] Trisunaryanti, W., Triyono, and Fibirna, D.A., 2003, Indo. J. Chem., 3, 2, 80–90.

[15] Sun, M., and Prins, R., 2001, J. Catal., 203, 1, 192–200.

[16] Prins, R., 2002, Adv. Catal., 46, 399.



DOI: https://doi.org/10.22146/ijc.21438

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