SYNTHESIS OF POLYEUGENYL OXYACETIC ACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(II) THAT USING SOLVENT EXTRACTION METHOD

https://doi.org/10.22146/ijc.21540

La Harimu(1*), Sabirin Matsjeh(2), Dwi Siswanta(3), Sri Juari Santosa(4)

(1) Study Program of Chemistry Education, Faculty of Teacher Training and Education, Haluoleo University, Kampus Baru Anduonohu, Kendari, Sulawesi Tenggara, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Sekip Utara, Yogyakarta 55281, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Sekip Utara, Yogyakarta 55281, Indonesia
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Sekip Utara, Yogyakarta 55281, Indonesia
(*) Corresponding Author

Abstract


Polyeugenyl oxyacetic acid has been synthesized from polyeugenol and chloroacetic acid and applied to separate metal Fe(III), Cr(III), Cu(II), Ni(II), Co(II), and Pb(II) using solvent extraction method. pH effect, polyeugenyl oxyacetic acid ion carrier concentration, extraction time, and metal concentration optimized to gain optimum condition. The result of experiment indicated that polyeugenyl oxyacetic acid resulted the yellowed brown synthesis with melting point 125 °C and yield 68.9%. The Characterization of spectroscopy IR attributed by absorption to the area 1735,8 cm -1 as carbonyl extend vibration (C=O) acid and 1H-NMR that was attributed by chemical shift at 4.6 ppm as carboxy proton (CH2-C=0). The metal separation optimum condition gained pH 3-6 for ion Fe(III), pH 5 for ion Cr(III), Ni(II), and Co(II) and pH 6 for ion Cu(II), and Pb(II). Optimum carrier concentraction 5 mL, 10 mL, and 15 mL for ion Fe(III), and ion Cr(III), Ni(II), Co(II), and ion Cu(II), Pb(II) respectively. Extraction time 2.5 h for ion Fe(III), 20 h for ion Cr(III), and 36 h for ion Cu(II), Pb(II), Ni(II), and Co(II). Metal concentration that would extracted correctly (0.75-5 x 10-4 M) for ion Fe(III), (0.75-2.5 x 10-4 M) for ion Cr(III), Ni(II), and Co(II) and (0.75-1 x 10-4 M) for ion Cu(II) and Pb(II). The best polyeugenil oxyacetic acid response to separate ion Fe(III) than other ions with selectivity order Fe(III)> Cr(III)> Cu(II)> Pb(II)> Ni(II)> Co(II).


Keywords


polyeugenil oxyacetic acid; pH; extraction time; metal concentraction; solvent extraction

Full Text:

Full Text PDF


References

[1]   Badmus M.A.O, Audu, and Anyata, B.U. 2007, African J. Biotechnol., 6 (3), 238-242.

[2]   Cosar T. and Ziyadanogullari, R. 1997, Turk. J. Chem., 22, 379-386.

[3]   Geckeler, K.E., 2001, Pure Appl. Chem., 73, 129-136.

[4]   Anupama, G. and Singh, A.K., 2004, React. Funct. Polym., 61, 255-263.

[5]   Leszek, G., 2005, Physicochemical Problems of Mineral Processing, 39, 117-128.

[6]   Takahiko, K., Toh, T., Kubota, F., Goto, M., Shinkai, S., and Nakashio, F., 1998, Anal. Sci., 14, 501-506.

[7]   Keshmirizadeh, E., Modarress, H., Eliassi, A., Mansoori, G.A. 2003, Eur. Polym. J., 39, 1141-1150.

[8]   Mulder, M, 1991, Basic Principles of Membrane Technology, Kluer Academic Publisher, Dordrecht.

[9]   Ouejhani, A., Dachraout, M., Lalleve, G., and Fauvarque, J.F., 2003, Anal. Sci., 19, 11, 1499.

[10] Beata, P., Walkowiak, W., and Wozniak, M.J., 2005, Physicochemical Problems of Mineral Processing,, 39, 89-98.

[11] Santarosa, V.E., Peretti., F., Caldart, V., Zoppas, J., and Zeni, M., 2002, Study Desalination, 149, 389-391.

[12] Sharma, R.K., 2001, Pure Appl. Chem., 73 (1), 181-186.

[13] Siswanta, D., 1993, Design and Synthesis of Selective Ammonium Ionophores for An Ion-Selective Electrode, Thesis, Keio University, Keio.

[14] Steven, M.P., 1975, Polymer Chemistry An Introduction. Addison-Wesley, Publishing Company Inc., London.



DOI: https://doi.org/10.22146/ijc.21540

Article Metrics

Abstract views : 423 | views : 729


Copyright (c) 2010 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 / 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.