SEPARATION AND PRECONCENTRATION OF COPPER (II) ION BY FATTY HYDROXAMIC ACIDS IMMOBILIZED ONTO AMBERLITE XAD – 4 RESIN

https://doi.org/10.22146/ijc.21754

Dedy Suhendra(1*), W. M. Z. Wan Yunus(2), Md. Jelas Haron(3), Mahiran Basri(4), Sidik Silong(5)

(1) Department of Chemistry, FKIP Universitas Mataram, Jl. Majapahit no. 62 Mataram, NTB
(2) Department of Chemistry, Faculty of Science Universiti Putra Malaysia, 43400 UPM Serdang Selangor
(3) Department of Chemistry, Faculty of Science Universiti Putra Malaysia, 43400 UPM Serdang Selangor
(4) Department of Chemistry, Faculty of Science Universiti Putra Malaysia, 43400 UPM Serdang Selangor
(5) Department of Chemistry, Faculty of Science Universiti Putra Malaysia, 43400 UPM Serdang Selangor
(*) Corresponding Author

Abstract


A method of copper (II) ion preconcentration and separation from other ions by using a column containing fatty hydroxamic acids - loaded Amberlite XAD 4 resin (FHA-Amb) is described. Several factors, which affect the separation and preconcentration efficiency such as pH, sample volume, and concentration of eluent and flow rate, have been investigated.  A quantitative recovery of copper (II) ion from FHA-Amb resin column was obtained using 10% HNO3 solutions as eluent with a preconcentration factor of 60. A method for separation of Cu(II) from Zn(II) and Cd(II) is proposed.  A rapid sample throughput, a clean separation, a high preconcentration factor and simplicity are the main advantages in these analytical procedures.


Keywords


extraction; preconcentration; fatty hydroxamic acid; copper (ii) ion; amberlite XAD-4

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References

[1]   Jain, V.K., Sait, S.S., Shrivastav, P., and Agrawal, Y.K., 1997, Talanta, 45, 397-404.

[2]   Ferreira, S.L.C., de Brito, C.F., Dantas, A.F., de Araujo, N.M.L., and Costa, A.C.S., 1999, Talanta, 48, 1173-1177.

[3]   Kabay, N., Demircioglu,  M., Ekinci, H., Yuksel,  M., Saglam, M., and Streat, M., 1998, Reactive & Functional Polym., 38, 219-226.

[4]   Anthemidis, A.N., Zachariadis, G.A., and Stratis, J.A., 2002, Talanta, 58, 831-840.

[5]   Ferreira, S.L.C., Ferreira, J.R., Lemos, V.A., Dantas, A.F., de Araujo, N.M.L., and Costa, A.C.S., 2000, Talanta, 50, 253-1259.

[6]   Jain, V.K., Handa, A., Sait, S.S., Shrivastav, P., and Agrawal, Y.K., 2001, Anal. Chim. Acta, 429, 237-246.

[7]   Greenwood, N.N., and Earnshow, A., 1984 Chemistry of Elements, Pergamon, New York, 1364-1369.

[8]   Franson, M.A.H., 1995, Standard Methods for Examination of Water and Waste Water, 19th ed. American Publication Health Association, Washington, DC, 3-68.

[9]   San Andres, M.P., Marina, M.L., and Vera, S. 1995, Analyst, 120, 255.

[10] Tait, B.K., Mdlalose, K.E., and Taljaard, I., 1995, Hydrometalurgy, 38, 1-6.

[11] Kara D., and Alkan M., 2002,Microchemical Journal, 71, 29-39.

[12] Eidecker, R., and Jackwerth, E., 1988, Z. Anal. Chem. 328, 401-406.

[13] Say, R., Birlik, E., Ersoz, A., Yilmaz, F., Gedikbey, T.,  and Denizli, A., 2003, Anal. Chim. Acta, 480, 251-258.

[14] Wang, X., Chen, Q., Yin, Z., Zhang, P.,  Long, Z., and Su, Z., 2003, Hydrometallurgy, 69, 39-44.

[15] Singh, R., and Prasad, B.B., 2000, Process Biochem., 35, 897-905.

[16] Sarangi K., and Das, R.P., 2003, Hydrometallurgy, 2158, 1-8.

[17] Olesik, J.W., and Moore, Jr, A.W., 1990, Anal. Chem. 62, 840-845.

[18] Ramesh, A., Mohan, K.R., and Seshaiah, K., 2002, Talanta 57, 243-252.

[19] Dev, K., Pathak, R., and Rao, G.N., 1999, Talanta, 48, 579-584.

[20] Uzun, A., Soylak, M., and Elci, L., 2001, Talanta, 54, 197-202.

[21] Suhendra, D., Wan Yunus, W.M.Z., Haron, M.J., Basri M., and Silong S., 2005, J. Oleo Sci., 54: 1, 33-38.

[22] Haron, M.J., Wan Yunus, W.M.Z., Desa, M.Z. and Kassim, A., 1994, Talanta, 41, 5: 805-807.

[23] Tan, B.K., and Oh, C.H., 1981 Malaysian Palm Oil Chemical and Physical Characteristic, PORIM Technology 3, Kuala Lumpur, Malaysia.



DOI: https://doi.org/10.22146/ijc.21754

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