THE INFLUENCE OF pH TOWARDS MULTIPLE METAL ION ADSORPTION OF Cu(II), Zn(II), Mn(II), AND Fe(II) ON HUMIC ACID
Buhani Buhani(1*), Suharso Suharso(2)
(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro, No. 1 Gedung Meneng-Bandar Lampung 35145
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro, No. 1 Gedung Meneng-Bandar Lampung 35145
(*) Corresponding Author
Abstract
Multiple metal ions adsorption of Cu(II), Zn(II), Mn(II) and Fe(II) on humic acid with a batch method has been carried out at pH interaction of 3, 5, and 6. Concentration of metal ions in solution before and after interaction was analyzed with Atomic Absorption Spectrophotometer (AAS). Result showed that adsorption multiple metal ions of Cu(II), Zn(II), Mn(II), and Fe(II) on humic acid is optimum at pH 5. Adsorption energies of the multiple metal ions Cu(II), Zn(II), Mn(II), and Fe(II) on humic acid at pH 3, 5, and 6 are around 35.0 - 37.6 kJ/mole. In general, capacity of competition adsorption of the multiple metal ions has an order as follows; Cu(II) < Fe(II) < Zn(II) < Mn(II).
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DOI: https://doi.org/10.22146/ijc.21771
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