SYNTHESIS OF 4-(3,4-DIMETOXY-PHENYL)-3-BUTENE-2-ON AND ACTIVITY IT’S TEST AS A FRUIT FLIES ATRACTANT
Deni Pranowo(1*), Suputa Suputa(2), Tutik Dwi Wahyuningsih(3)
(1) Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta 55281
(2) Faculty of Agriculture, Gadjah Mada University, Bulaksumur Yogyakarta 55281
(3) Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta 55281
(*) Corresponding Author
Abstract
4-(3,4-dimethoxyphenyl)-3-buten-2-on has been synthesized from veratraldehyde and acetone via aldol condensation. The reaction was performed at room temperature under basic condition for 24 hours to give brown solid of product (m.p 64-6 5oC) in 73.7% yield. Veratraldehyde itself was produced from alkylation of vanillin by the use of dimethylsulfate. The structure of the products was analyzed by FTIR, 1H NMR and GC-MS. Activity test of 4-(3,4-dimethoxyphenyl)-3-buten-2-on as an attractant was carried out in Sleman, Bantul and Kulon Progo with methyl eugenol as a reference. The result showed that 4-(3,4-dimethoxyphenyl)-3-buten-2-on was inactive compound as a fruit flies attractant and some of fruit flies, i.e. Bactrocera papayae, B. carambolae, B. umbrosa and B. abdolonginqua was found on the test area.
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[1] Asri, A., 2003, Membuat Perangkap Lalat Buah, Tabloid Sinar Tani, edisi 9 April 2003.
[2] Alfarini, P., 2003, Produk Hortikultura Indonesia Terancam Ditolak Taiwan, www.tempointeraktif.com, diakses pada 25 Maret 2005.
[3] Shelly, T.E., Pahio, Elaine, dan Edu James, 2004, J. Florida Entomologist, 87(4), 481-48
[4] Jacobson, M., Keiser, I., Harris, E.J., and Miyashita, H., 1976, J. Agric. Food Chem., 24(2), 782-783.
[5] Rosilawati, I., 2000, Pemanfaatan Vanilin Untuk Sintesis Veratral Sianida Sebagai Senyawa Antara Dalam Pembuatan Turunan Antibiotik C9154, Tesis S2, Program Pascasarjana FMIPA UGM.
[6] Wibowo, E., 1998, Sintesis Turunan Etil Ferulat Dari Vanilin Berdasarkan Reaksi Claisen, Skripsi, FMIPA UGM Yogyakarta.
[7] Rinasih, I., 1998, Sintesis Senyawa 3,4 Dimetoksi Benzaldehida dari Vanilin dalam Suasana Basa, Skripsi, FMIPA UGM, Yogyakarta
[8] Drew, R.A.I., 1989, The Tropical Fruit Flies (Diptera: Tephritidae: Dacinae) of the Australasian and Oceanian Regions. Memoirs of the Queensland Museum. Volume 26, the Board. Brisbane. Australia.
[9] Drew, R.A.I. and Hancock D.L., 1994, Bull. Entomol. Res. Supplement., 2, 1-68.
[10] White, I.M. and Elson-Harris, M.M., 1992, Fruit Flies of Economic Significance: Their Identification and Bionomics. CAB International in association with ACIAR. Printed and Bound in the UK by Redwood Press Ltd. Melksham.
DOI: https://doi.org/10.22146/ijc.21783
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