UTILIZATION OF ACTIVATED ZEOLITE AS MOLECULAR SIEVE IN CHROMATOGRAPHIC COLUMN FOR SEPARATION OF COAL TAR COMPOUNDS

https://doi.org/10.22146/ijc.21866

Dwi Retno Nurotul Wahidiyah(1*), Bambang Setiaji(2), Iqmal Tahir(3)

(1) Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta
(2) Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta
(3) Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta
(*) Corresponding Author

Abstract


Application of activated zeolite (ZAA) as molecular sieve to separate compounds of coal tar from vaccum fractional distillation, have been done. The size of zeolite was 10-20 mesh and used as solid phase in column chromatography with length of 30 cm. The first step of the research was coal pyrolisis and the product (tar) was distillated by fractional column and vaccum system at reduced pressure 44 cmHg and maximum temperature at 200 oC. The distillate from this procedure was flowed to the column chromatography of zeolite (ZAA). The compound absorbed by zeolite was eluted with varying solvents, i.e: CCl4, acetone and ethanol. Each fraction was then analyzed by gas chromatography. The results showed, zeolite have a capability to separate the compounds of tar and it tends to absorb medium hydrocarbon. The nonpolar eluent [CCl4] gives the better result in eluting tar compound than polar (ethanol) or medium polar eluents (acetone).


Keywords


zeolite; coal tar; column chromatography

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References

[1] Suyanti, L., 2000, Kinetika Reaksi Pirolisis Tar Batu Bara Dengan Menggunakan Katalis,Tesis Program Pasca Sarjana, Universitas Gadjah Mada

[2] Khopkar, S.M., 1990, Konsep Dasar Kimia Analitik, Penebit Universitas Indonesia, Jakarta

[3] Caruso F., Caruso R.A., and Mohwald, H., 1999, J. Chem. Mater, 11, 3309 – 3314.

[4] Dean, J.A., 1970, Chemical Separation Methods, Van Nostrand Reinhold, London

[5] Shamsi, A., 1996, Ind. Eng. Chem. Rev., 35, 1251-1256

[6] Hasanuddin, R., 2000, Peningkatan Kualitas Batu Bara Lignit dengan Metode Pirolisis danEkstraksi, Tesis Program Pasca sarjana, Universitas Gadjah Mada

[7] Hayashi, J., Amoro, S., Kasukabe,.K., and Mooraka, 1995, Energy and Fuel, 9, 290-294

[8] Hessley, A., 1986, Coal Science, An Introduction to Chemistry, Technology and Utilization, Mc Graw Hill Publishing Company Limited, London

[9] Smith, F.J, and Braithwaite A., 2001, Chromatographic Methods, 5th ed, Kluwer Academic Publishers, London

[10] Othmer, K., 1994, Encyclopedia of Chemical Technology, John Willey & Sons, New York

[11] Rubinson, K.H, 1999, Contemporary Instrumental Analysis, Prentice Hall Inc, New Jersey

[12] Rhodes, H.K, Sean., D.A., Caruso, F., Zhang B.J., and Mann, S., 2000, J. Chem. Mater, 12, 2832- 2837

[13] Anonim, 2002, Data base PT. Prima Zeolita, Yogyakarta



DOI: https://doi.org/10.22146/ijc.21866

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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