Effect of Residence Time of Graphitisation on Thermal Conductivity of Molded Graphite

https://doi.org/10.22146/ijc.21960

Pedy Artsanti(1), Yateman Arryanto(2*), Kusnanto Kusnanto(3)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(3) Department of Nuclear Engineering Universitas Gadjah Mada
(*) Corresponding Author

Abstract


The effect of residence time of graphitisation on thermal conductivity of molded graphite has been examined. The examination has been conducted by varying residence time of graphitisation of molded carbon with petroleum coke as raw material and coal tar pitch. Graphitisation has been conducted by heating molded graphite at 2500 °C in argon atmosphere with residention time of 10, 30 and 90 minutes. Graphitisation degree, density, shrinking mass and porosity of molded graphite were examined and so was its thermal conductivity. The result showed that the decrease of porosity and the increase of graphitisation degree due to the increasing of residention time of graphitisation will increase the thermal conductivity of graphite. Molded graphite graphitisized with residence time for 90 minutes residention time gave thermal conductivity of 2.134 Watt/mK and graphitization degree 0.718.

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References

[1] Gulo, S., 1997, Pembuatan Grafit Impremeabel dan Kokas Minyak Bumi, Tesis Magister Sains, Fakultas MIPA Universitas Gadjah Mada, Yogyakarta

[2] Heintz, E.A., 1996, Review The Characterization of Petroleum Coke, Carbon, 34: 699-709.

[3] Incropera, F.P., and DeWitt, D.P., 1985, Introduction to Heat Transfer, John Wiley & Sons, New, York.

[4] Kakuta, M., Tanaka, H., Sato, J., and Naguchi, H., 1981, A New Calcining Technology for Manufacturing to Coke with Lower Thermal Expansion Coefficient, Carbon, 19: 347-352.

[5] Kelly, B.T., 1981, Physics of Graphite, Applied Science Publishers, London.

[6] Mateos, J.M.J., Romeo, E., and Salazar, C.G.D., 1993, XRD Study of Petroleum Cokes by Line Profile Analysis: Relation Among Heat Treatment, Structure and Sulphur Content, Carbon, 31: 1159-1178.

[7] Marinkovic, S., 1984, Subtitutional Solid Solubility in Carbon and Graphite, in Chemistry and Physics of Carbon, Ed Thower, A.P., Marcel Dekker, Inc., New York, volume 19,1

[8] Meers, J.T., Bowman, J.C., and Krumhansl, J.A., 1957, Industrial Carbon and Graphite, X-Ray and Low Temperature Thermal Conductivity Study of Defects in Graphite, Papers read at the Conference, Society of Chemical Industri, London.

[9] Omar, M.A., 1975, Elementary Solid State Physics: Principles and Applications, Addison-Wesley Publishing Company Reading, Massachusetts.

[10] Pierson, H.O., 1993, Handbook of Carbon, Graphite, Diamond and Fullerens, Properties, Processing and Applications, Noyes Publications, New Jersey.

[11] Powell R.W., 1957, Industrial Carbon and Graphite, The Thermal Conductivities of Carbons and Graphites at High Temperatures, Papers reads at the Conference, Society of Chemical Industri. London.

[12] Reynolds, W.N., 1968, Physical Properties of Graphite, Elsevier Publishing Co., Ltd, Amsterdam.

[13] Saadaoui, H,. Roux, J.C., Flandrois, S., and Nysten, B., 1993, Graphitization of Pyrocarbons: An STM Study, Carbon, 34: 481-486.

[14] Seera, M.S., and Pavlovicx, A.S., 1993, X-ray Diffraction, Thermal Expansion, Electrical Conductivity, and optical Microscopy Studies on Coal-Based Graphites, carbon, 31: 557-564.

[15] Shreve, R.N., and Brink, J.A., 1977, Chemical Process Industries, McGraw Hill Inc., Tokyo.

[16] Sogabe, T., Inagaki, M., and Ibuki, T., 1992, Coating of Graphite by Polymide and Its Gas Permeability, carbon, 30: 513-516.

[17] Weishauptova, Z., Medek, J., and Vaverkova, Z., 1992, A Change in The Porous Structure of Coke between 1540°C and 2880°C, Carbon, 30: 1055-1062.



DOI: https://doi.org/10.22146/ijc.21960

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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