The Properties of Thermosensitive Zwitterionic Sulfobetaine NIPAM-co-DMAAPS Polymer and the Hydrogels: The Effects of Monomer Concentration on the Transition Temperature and Its Correlation with the Adsorption Behavior

https://doi.org/10.22146/ijc.41499

Eva Oktavia Ningrum(1*), Agus Purwanto(2), Galuh Chynintya Rosita(3), Asep Bagus(4)

(1) Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya, 60111, Indonesia
(2) Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta, Central Java 57126, Indonesia
(3) Department of Chemical Engineering, Faculty of Industrial Technology, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia
(4) Department of Chemical Engineering, Faculty of Industrial Technology, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia
(*) Corresponding Author

Abstract


The properties of N-isopropylacrylamide copolymerized with N,N-dimethyl(acrylamidopropyl)ammonium propane sulfonate [poly(NIPAM-co-DMAAPS)] prepared with various monomer ratios such as transition temperature, molecular structure, viscosity were systematically investigated in water and Zn(NO3)2 solution. Poly(NIPAM-co-DMAAPS) in water and Zn(NO3)2 solution exhibited a phase transition with a lower critical solution temperature (LCST). The higher ratio of NIPAM monomer in poly(NIPAM-co-DMAAPS), the lower the LCST of the polymer. Furthermore, the transition temperature of poly(NIPAM-co-DMAAPS) with a lower NIPAM concentration were not confirmed both in water nor Zn(NO3)2 solution. The more increase the NIPAM concentration used in the preparation, the more increase the polymer viscosity. Moreover, the more increase the adsorption amount of ions onto the gel, the more increase the polymer transmittance as well.


Keywords


transition temperature; thermosensitive; adsorption

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DOI: https://doi.org/10.22146/ijc.41499

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