Optimization and Characterization of Wood Vinegar Produced by Shorea laevis Ridl Wood Pyrolysis


Hasan Ashari Oramahi(1*), Tsuyoshi Yoshimura(2), Elvi Rusmiyanto(3), Kustiati Kustiati(4)

(1) Faculty of Forestry, University of Tanjungpura, Jl. Daya Nasional, Pontianak 78124, Indonesa
(2) Research Institute for Sustainable Humanosphere (RISH), Kyoto University, Uji, 611-0011 Kyoto, Japan
(3) Faculty of Mathematics and Natural Sciences, University of Tanjungpura, Jl. Prof. Dr. H. Hadari Nawawi, Pontianak 78124, Indonesia
(4) Faculty of Mathematics and Natural Sciences, University of Tanjungpura, Jl. Prof. Dr. H. Hadari Nawawi, Pontianak 78124, Indonesia
(*) Corresponding Author


In this study, the Box-Behnken Design (BBD) was employed to investigate the effects of wood particle size, pyrolysis temperature, and pyrolysis time on the production of wood vinegar from Indonesia “bengkirai” wood (Shorea laevis Ridl). Characterization of wood vinegar was conducted by gas chromatography-mass spectrometry (GC-MS). Three variable designs consisting of wood particle size (2.00, 2.38, and 3.36 mm), pyrolysis temperature (350, 400, and 450 °C), and pyrolysis time (105, 120, and 135 min) were employed in a BBD response surface methodology (RSM-BBD). RSM-BBD results suggested that maximum wood vinegar yield would be obtained with a wood particle size of 3.85 mm, pyrolysis temperature of 400 °C, and pyrolysis time of 93 min. In addition, the mathematical model indicated the maximum wood vinegar yield would be 30.31%. The main compounds in wood vinegar were acetic acid, 1-hydroxy-2-propanone, furfural, 2,3-pentanedione, phenol, 2-methoxy phenol, 2-methoxy-4-methyl phenol, 2,6-dimethoxy phenol, and 1,2,4-trimethoxybenzene.


wood vinegar; Shorea laevis; response surface methodology; Box-Behnken design; pyrolysis temperature; wood particle size

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[1] Lee, S.H., H’ng, P.S., Lee, A.N., Sajap, A.S., Tey, B.T., and Salmiah, U., 2011, Production of wood vinegar from lignocellulosic biomass and their effectiveness against biological attacks, J. Appl. Sci., 10 (20), 2440–2446.

[2] Tiirikkala, K., Fagernäs, L., and Tiilikkala, J., 2010, History and use of wood pyrolysis liquids as biocide and plant protection product, Open Agric. J., 4, 111–118.

[3] Hagner, M., Tiilikkala, K., Lindqvist, I., Niemelä, K., Wikberg, H., Källi, A., and Rasa, K., 2018, Performance of liquids from slow pyrolysis and hydrothermal carbonization in plant protection, Waste Biomass Valorization, 1–12.

[4] Pinto, F., Paradela, F., Gulyurtlu, I., and Ramos, A.M., 2013, Prediction of liquid yields from the pyrolysis of waste mixtures using response surface methodology, Fuel Process. Technol., 116, 271–283.

[5] Oramahi, H.A., Wahdina, Diba, F., and Yoshimura, T., 2015, Optimization of production of lignocellulosic biomass bio-oil from oil palm trunk, Procedia Environ. Sci., 28, 769–777.

[6] Crespo, Y.A., Naranjo, R.A., Quitana, Y.G., Sanchez, C.G., and Sanchez, E.M.S., 2017, Optimisation and characterisation of bio-oil produced by Acacia mangium Willd wood pyrolysis, Wood Sci. Technol., 51 (5), 1155–1171.

[7] Akhtar, J., and Amin, N.S., 2012, A review on operating parameters for optimum liquid oil yield in biomass pyrolysis, Renewable Sustainable Energy Rev., 16 (7), 5101–5109.

[8] Islam, M.N., Beg, M.R.A., and Islam, R.I., 2005, Pyrolytic oil from fixed bed pyrolysis of municipal solid waste and its characterization, Renewable Energy, 30 (3), 413–420.

[9] Ma, C., Song, K., Yu, J., Yang, L., Zhao, C., Wang, W., Zu, G., and Zu, Y., 2013, Pyrolysis process and antioxidant activity of pyroligneous acid from Rosmarinus officinalis leaves, J. Anal. Appl. Pyrolysis, 104, 38–47.

[10] de Souza Araújo, E., Pimenta, A.S., Feijó, F.M.C., Castro, R.V.O., Fasciotti, M., Monteiro, T.V.C., and de Lima, K.M.G., 2018, Antibacterial and antifungal activities of wood vinegar from the wood of Eucalyptus urograndis and Mimosa tenuiflora, J. Appl. Microbiol., 124 (1), 85–96.

[11] Ratanapisit, J., Apiraksakul, S., Rerngnarong, A., Chungsiriporn, J., and Bunyakarn, C., 2009, Preliminary evaluation of production and characterization of wood vinegar from rubberwood, Songklanakarin J. Sci. Technol., 31 (3), 343–349.

[12] Montgomery, D.C., 2008, Design and analysis of experiments, John Wiley & Sons, New York.

[13] Kiliç, M., Pütün, E., and Pütün, A.E., 2014, Optimization of Euphorbia rigida fast pyrolysis conditions by using response surface methodology, J. Anal. Appl. Pyrolysis, 110, 163–171.

[14] Ngo, T.A., Kim, J., and Kim, S.S., 2013, Fast pyrolysis of palm kernel cake using a fluidized bed reactor: Design of experiment and characteristics of bio-oil, J. Ind. Eng. Chem., 19 (1), 137–143.

[15] Tranggono, Suhardi, Setiadji, B., Darmadji, P., Supranto, and Sudarmanto, 1996, Identifikasi asap cair dari berbagai jenis kayu dan tempurung kelapa, ITEPA, 1 (2), 15–24

[16] Oramahi, H.A., Yoshimura, T., Diba, F., Setyawati, D., and Nurhaida, 2018, Antifungal and antitermitic activities of wood vinegar from oil palm trunk, J. Wood Sci., 64 (3), 311–317.

[17] Liu, Y., Wei, S., and Liao, M., 2013, Optimization of ultrasonic extraction of phenolic compounds from Euryale ferox seed shells using response surface methodology, Ind. Crops Prod., 49, 837–843

[18] Yuan, Z., Xu, Z., Zhang, D., Chen, W., Zhang, T., Huang, Y., Gu, L., Deng, H., and Tian, D., 2018, Box-Behnken design approach towards optimization of activated carbon synthesized by co-pyrolysis of waste polyester textiles and MgCl2, Appl. Surf. Sci., 427, 340–348.

[19] Srinivasa, P.C., Ravi, R., and Tharanathan, R.N., 2007, Effect of storage conditions on the tensile properties of eco-friendly chitosan films by response surface methodology, J. Food Eng., 80 (1), 184–189.

[20] Safari, M., Abdi, R., Adl, M., and Kafashan, J., 2018, Optimization of biogas productivity in lab-scale by response surface methodology, Renewable Energy, 118, 368–375.

[21] Mun, S.P., and Ku, C.S., 2010, Pyrolysis GC-MS analysis of tars formed during the aging of wood and bamboo crude vinegar, J. Wood Sci., 56 (1), 47–52.

[22] Wu, Q., Zhang, S., Hou, B., Zheng, H., Deng, W., Liu, D., and Tang, W., 2015, Study on the preparation of wood vinegar from biomass residues by carbonization process, Bioresour. Technol., 179, 98–103.

[23] Zhai, M., Shi, G., Wang, Y., Mao, G., Wang, D., and Wang, Z., 2015, Chemical compositions and biological activities of wood vinegar from the walnut shell, BioResources, 10 (1), 1715–1729.

[24] Sofina-E-Arab and Islam, M.A., 2015, Production of mahogany sawdust reinforced LDPE wood–plastic composites using statistical response surface methodology, J. For. Res., 26 (2), 487–494.

[25] Wang, X., Yang, G., Li, F., Feng, Y., and Ren, G., 2013, Response surface optimization of methane potentials in anaerobic co-digestion of multiple substrates: Dairy, chicken manure, and wheat straw, Waste Manage. Res., 31 (1), 60–66.

[26] Karagöz, S., Bhaskar, T., Muto, A., and Sakata, Y., 2005, Comparative studies of oil compositions produced from sawdust, rice husk, lignin and cellulose by hydrothermal treatment, Fuel, 84 (7-8), 875–884.

[27] Fan, Y., Cai, Y., Li, X., Yin, H., Yu, N., Zhang, R., and Zhao, W., 2014, Rape straw as a source of bio-oil via vacuum pyrolysis: Optimization of bio-oil yield using orthogonal design method and characterization of bio-oil, J. Anal. Appl. Pyrolysis, 106, 63–70.

[28] Mantilla, S.V., Gauthier-Maradei, P., Gil, P.Á., and Cárdenas, S.T., 2014, Comparative study of bio-oil production from sugarcane bagasse and palm empty fruit bunch: Yield optimization and bio-oil characterization, J. Anal. Appl. Pyrolysis, 108, 284–294.

[29] Nam, H., and Capareda, S., 2015, Experimental investigation of torrefaction of two agricultural wastes of different composition using RSM (response surface methodology), Energy, 91, 507–516.

[30] Wei, Q., Ma, X., and Dong, J., 2010, Preparation, chemical constituents and antimicrobial activity of wood vinegar from walnut tree branches, J. Anal. Appl. Pyrolysis, 87 (1), 24–28.

[31] Zheng, H., Sun, C., Hou, X., Wu, M., Yao, Y., and Li, F., 2018, Pyrolysis of Arundo donax L. to produce pyrolytic vinegar and its effect on the growth of dinoflagellate Karenia brevis, Bioresour. Technol., 247, 273–281.

[32] Theapparat, Y., Khongthong, S., Rodjan, P., Lertwittayanon, K., and Faroongsarng, D., 2019, Physicochemical properties and in vitro antioxidant activities of wood vinegar prepared from brushwood biomass waste of Mangosteen, Durian, Rambutan, and Langsat, J. For. Res., 30 (3), 1139–1148.

[33] Pimenta, A.S., Fasciotti, M., Monteiro, T.V., and Lima, K.M., 2018, Chemical composition of wood vinegar obtained from Eucalyptus GG100 Clone, Molecules, 23 (2), 426.

[34] Nakai, T., Kartal, S.N., Hata, T., and Imamura, Y., 2007, Chemical characterization of pyrolysis liquids of wood-based composites and evaluation of their bio-efficiency, Build. Environ., 42 (3), 1236–1241.

[35] Li, Z., Zhang, Z., Wu, L., Wang, J., Liu, Z., Zhang, Z., and Wang, Z., 2017, Preparation and characterization of two wood vinegar obtained from the hull of spina date seed and shell of peanut, Chem. Res. Chin. Univ., 33 (3), 348–353.

DOI: https://doi.org/10.22146/ijc.45783

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