Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes

https://doi.org/10.22146/ijc.53131

Gunawan Gunawan(1*), Abdul Haris(2), Didik Setiyo Widodo(3), Linda Suyati(4), Wilman Septina(5)

(1) Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, S.H., Tembalang Semarang 50275, Indonesia
(2) Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, S.H., Tembalang Semarang 50275, Indonesia
(3) Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, S.H., Tembalang Semarang 50275, Indonesia
(4) Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, S.H., Tembalang Semarang 50275, Indonesia
(5) Hawaii Natural Energy Institute, University of Hawai'i at Mānoa (UHM), 1680 East West Road, POST 109 Honolulu, HI 96822, United States
(*) Corresponding Author

Abstract


Methylene blue degradation carried out using cadmium sulfide (CdS) photoanode in photofuel cell (PFC) had been done. CdS synthesized by chemical bath deposition (CBD) on the FTO substrate was used as anode and platinum as a cathode in photoelectrochemical studies. Characterization of CdS thin film was done using EDX, XRD, SEM, Raman, UV-Vis absorption spectrophotometer as well as photocurrent test of the CdS thin film under illumination using potentiostat with the three-electrode system. The EDX result indicated the presence of CdS with an elemental composition of Cd rich. XRD showed the appearance of CdS crystals in cubic and hexagonal formations. SEM image of CdS gave results in the form of crystals of less than 1 mm. Raman spectrum showed the appearance of CdS peaks. The bandgap of CdS was estimated to be 2.38 eV, and the photocurrent test confirmed that the film had a property of n-type semiconductor. Application of CdS thin film as a photoanode in the PFC system using 100 mg/L methylene blue solution showed degradation up to 48% for 2.5 h using a 4 cm2 photoanode, and the maximum potential of 0.8 V was obtained with a photoanode area of 1 cm2.

 


Keywords


cadmium sulphide; photoanode; photofuel cell; methylene blue

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References

[1] Antoniadou, M., Kondarides, D.I., Labou, D., Neophytides, S., and Lianos, P., 2010, An efficient photoelectrochemical cell functioning in the presence of organic wastes, Sol. Energy Mater. Sol. Cells, 94 (3), 592–597.

[2] Li, J., Li, J., Chen, Q., Bai, J., and Zhou, B., 2013, Converting hazardous organics into clean energy using a solar responsive dual photoelectrode photocatalytic fuel cell, J. Hazard. Mater., 262, 304–310.

[3] Li, K., Xu, Y., He, Y., Yang, C., Wang, Y., and Jia, J., 2013, Photocatalytic fuel cell (PFC) and dye self-photosensitization photocatalytic fuel cell (DSPFC) with BiOCl/Ti photoanode under UV and visible light irradiation, Environ. Sci. Technol., 47 (7), 3490–3497.

[4] Xia, L., Bai, J., Li, J., Zeng, Q., Li, X., and Zhou, B., 2016, A highly efficient BiVO4/WO3/W heterojunction photoanode for visible-light responsive dual photoelectrode photocatalytic fuel cell, Appl. Catal., B, 183, 224–230.

[5] Ogura, Y., Okamoto, S., Itoi, T., Fujishima, Y., Yoshida, Y., and Izumi, Y., 2014, A photofuel cell comprising titanium oxide and silver (I/0) photocatalysts for use of acidic water as a fuel, Chem. Commun., 50 (23), 3067–3070.

[6] Iyatani, K., Horiuchi, Y., Fukumoto, S., Takeuchi, M., Anpo, M., and Matsuoka, M., 2013, Separate-type Pt-free photofuel cell based on a visible light-responsive TiO2 photoanode: Effect of hydrofluoric acid treatment of the photoanode, Appl. Catal., A, 458, 162–168.

[7] Fujiwara, K., Akita, A., Kawano, S., Fujishima, M., and Tada, H., 2017, Hydrogen peroxide-photofuel cell using TiO2 photoanode, Electrochem. Commun., 84, 71–74.

[8] Seger, B., Lu, G.Q., and Wang, L., 2012, Electrical power and hydrogen production from a photo-fuel cell using formic acid and other single-carbon organics, J. Mater. Chem., 22 (21), 10709–10715.

[9] Fujishima, Y., Okamoto, S., Yoshiba, M., Itoi, T., Kawamura, S., Yoshida, Y., Ogura, Y., and Izumi, Y., 2015, Photofuel cell comprising titanium oxide and bismuth oxychloride (BiO1−xCl1−y) photocatalysts that uses acidic water as a fuel, J. Mater. Chem. A, 3 (16), 8389–8404.

[10] Konstantinou, I.K., and Albanis, T.A., 2004, TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review, Appl. Catal., B, 49 (1), 1–14.

[11] Liu, Y., Zhou, B., Li, J., Gan, X., Bai, J., and Cai, W., 2009, Preparation of short, robust and highly ordered TiO2 nanotube arrays and their applications as electrode, Appl. Catal., B, 92 (3-4), 326–332.

[12] Liu, Y., Li, J., Zhou, B., Chen, H., Wang, Z., and Cai, W., 2011, A TiO2-nanotube-array-based photocatalytic fuel cell using refractory organic compounds as substrates for electricity generation, Chem. Commun., 47 (37), 10314–10316.

[13] Liu, Y., Li, J., Zhou, B., Li, X., Chen, H., Chen, Q., Wang, Z., Li, L., Wang, J., and Cai, W., 2011, Efficient electricity production and simultaneously wastewater treatment via a high-performance photocatalytic fuel cell, Water Res., 45 (13), 3991–3998.

[14] Liu, Y., Zhou, B., Bai, J., Li, J., Zhang, J., Zheng, Q., Zhu, X., and Cai, W., 2009, Efficient photochemical water splitting and organic pollutant degradation by highly ordered TiO2 nanopore arrays, Appl. Catal., B, 89 (1-2), 142–148.

[15] Lee, S.L., Ho, I.N., Ong, S.A., Wong, Y.S., Voon, C.H., Khalik, W.F., Yusoff, N.A., and Nordin, N., 2017, A highly efficient immobilized ZnO/Zn photoanode for degradation of azo dye Reactive Green 19 in a photocatalytic fuel cell, Chemosphere, 166, 118–125.

[16] Wang, B., Zhang, H., Lu, X.Y., Xuan, J., and Leung, M.K.H., 2014, Solar photocatalytic fuel cell using CdS–TiO2 photoanode and air-breathing cathode for wastewater treatment and simultaneous electricity production, Chem. Eng. J., 253, 174–182.

[17] Yang, J., Liao, W., Liu, Y., Muruganathan, M., and Zhang, Y., 2014, Degradation of rhodamine B using a visible-light driven photocatalytic fuel cell, Electrochim. Acta, 144, 7–15.

[18] Li, L., Xue, S., Chen, R., Liao, Q., Zhu, X., Wang, Z., He, X., Feng, H., and Cheng, X., 2015, Performance characteristics of a membraneless solar responsive photocatalytic fuel cell with an air-breathing cathode under different fuels and electrolytes and air conditions, Electrochim. Acta, 182, 280–288.

[19] Antoniadou, M., Daskalaki, V.M., Balis, N., Kondarides, D.I., Kordulis, C., and Lianos, P., 2011, Photocatalysis and photoelectrocatalysis using (CdS-ZnS)/TiO2 combined photocatalysts, Appl. Catal., B, 107 (1-2), 188–196.

[20] Ikeda, S., Nonogaki, M., Septina, W., Gunawan, G., Harada, T., and Matsumura, M., 2013, Fabrication of CuInS2 and Cu(In,Ga)S2 thin films by a facile spray pyrolysis and their photovoltaic and photoelectrochemical properties, Catal. Sci. Technol., 3 (7), 1849–1854.

[21] Jiang, F., Ozaki, C., Gunawan, Harada, T., Tang, Z., Minemoto, T., Nose, Y., and Ikeda, S., 2016, Effect of indium doping on surface optoelectrical properties of Cu2ZnSnS4 photoabsorber and interfacial/photovoltaic performance of cadmium free In2S3/Cu2ZnSnS4 heterojunction thin film solar cell, Chem. Matter., 28 (10), 3283–3291.

[22] Gunawan, G., Septina, W., Ikeda, S., Harada, T., Minegishi, T., Domen, K., and Matsumura, M., 2014, Platinum and indium sulfide-modified CuInS2 as efficient photocathodes for photoelectrochemical water splitting, Chem. Commun., 50 (64), 8941–8943.

[23] Zhao, J., Menigishi, T., Zhang, L., Zhong, M., Gunawan, Nakabyashi, M., Ma, G., Hisatomi, T., Kayatama, M., Ikeda, S., Shibata, N., Yamada, T., and Domen, K., 2014, Enhancement of solar hydrogen evolution from water by surface modification with CdS and TiO2 on porous CuInS2 photocathodes prepared by an electrodeposition-sulfurization method, Angew. Chem. Int. Ed., 53 (44), 11808–11812.

[24] Gunawan, Septina, W., Harada, T., Nose, Y., and Ikeda, S., 2015, Investigation of the electric structures of heterointerfaces in Pt- and In2S3-modified CuInS2 photocathodes used for sunlight-induced hydrogen evolution, ACS Appl. Mater. Interfaces, 7 (29), 16086–16092.

[25] Septina, W., Gunawan, Ikeda, S., Harada, T., Higashi, M., Abe, R., and Matsumura, M., 2015, Photosplitting of water from wide-gap Cu(In,Ga)S2 thin films modified with a CdS layer and Pt nanoparticles for a high-onset-potential photocathode, J. Phys. Chem. C, 119 (16), 8576–8583.

[26] Jiang, F., Gunawan, Harada, T., Kuang, Y., Minegishi, T., Domen, K., and Ikeda, S., 2015, Pt/In2S3/CdS/Cu2ZnSnS4 thin film as an efficient and stable photocathode for water reduction under sunlight radiation, J. Am. Chem. Soc., 137 (42), 13691–13697.

[27] Zarębska, K., and Skompska, M., 2011, Electrodeposition of CdS from acidic aqueous thiosulfate solution—Investigation of the mechanism by electrochemical quartz micro-balance technique, Electrochim. Acta, 56 (16), 5731–5739.

[28] Patil, B.N., Naik, D.B., and Shrivastava, V.S., 2011, Synthesis and characterization of Al doped CdS thin films grown by chemical bath deposition method and its application to remove dye by photocatalytic treatment, Chalcogenide Lett., 8 (2), 117–121.

[29] Zyoud, A., Saa’deddin, I., Khudruj, S., Hawash, Z.M., Park, D., Campet, G., and Hilal, H.S., 2013, CdS/FTO thin film electrodes deposited by chemical bath deposition and by electrochemical deposition: a comparative assessment of photo-electrochemical characteristics, Solid State Sci., 18, 83–90.

[30] Mir, F.A., Chattarjee, I., Dar, A.A., Asokan, K., and Bhat, G.M., 2015, Preparation and characterizations of cadmium sulfide nanoparticles, Optik, 126 (11-12), 1240–1244.

[31] Dumbrava, A., Badea, C., Prodan, G., and Ciupina, V., 2010, Synthesis and characterization of cadmium sulphide obtained at room temperature, Chalcogenide Lett., 7 (2), 111–118.

[32] Rami, M., Benamar, E., Fahoume, M., Chraibi, F., and Ennaoui, A., 1999, Effect of the cadmium ion source on the structural and optical properties of chemical bath deposited CdS thin films, Solid State Sci., 1 (4), 179–188.

[33] Barote, M.A., Yadav, A.A., and Masumdar, E.U., 2011, Synthesis, characterization and photoelectrochemical properties of n-CdS thin films, Physica B, 406 (10), 1865–1871.

[34] Yang, F., Tian, X., Zhang, K., Zhang, X., and Liu, L., 2018, The morphology–property effect and synergetic catalytic effect of CdS as electrocatalysts for dye-sensitized solar cells, ECS J. Solid State Sci. Technol., 7 (6), P311–P316.

[35] Yeh, C.Y., Lu, Z.W., Froyen, S., and Zunger, A., 1992, Zinc-blende–wurtzite polytypism in semiconductors, Phys. Rev. B, 46 (16), 10086–10097.

[36] Ganesh, R.S., Sharma, S.K., Durgadevi, E., Navaneethan, M., Binitha, H.S., Ponnusamy, S., Muthamizhchelvan, C., Hayakawa, Y., and Kim, D.Y., 2017, Surfactant free synthesis of CdS nanospheres, microstructural analysis, chemical bonding, optical properties and photocatalytic activities, Superlattices Microstruct., 104, 247–257.

[37] Phuruangrat, A., Thongtem, T., and Thongtem, S., 2009, Characterization of cadmium sulfide nanorods prepared by the solvothermal process, Mater. Lett., 63 (17), 1562–1565.

[38] Alkire, R.C., Kolb, D.M., Lipkowski, J., and Ross, P.N., 2010, Photoelectrochemical Materials, and Energy, Conversion Processes, Wiley-VCH, Hoboken, New Jersey, USA.

[39] Jiang, J.B., Huo, P., Wang, P., Wu, Y.Y., Bian, G.Q., Zhu, Q.Y., and Dai, J., 2014, Synthesis and photocurrent responsive properties of CdS/Se clusters integrated with methylviologen, J. Mater. Chem. C, 2 (14), 2528–2533.

[40] Akpan, U.G., and Hameed, B.H., 2009, Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: A review, J. Hazard. Mater., 170 (2-3), 520–529.

[41] Houas, A., Lachheb, H., Ksibi, M., Elaloui, E., Guillard, C., and Herrmann, J.M., 2001, Photocatalytic degradation pathway of methylene blue in water, Appl. Catal., B, 31 (2), 145–157.

[42] Chen, Q., Bai, J., Li, J., Huang, K., Li, X., Zhou, B., and Cai, W., 2014, Aerated visible-light responsive photocatalytic fuel cell for wastewater treatment with producing sustainable electricity in neutral solution, Chem. Eng. J., 252, 89–94.

[43] Zhang, B., Fan, W., Yao, T., Liao, S., Li, A., Li, D., Liu, M., Shi, J., Liao, S., and Li, C., 2016, Design and fabrication of a dual-photoelectrode fuel cell towards cost-effective electricity production from biomass, ChemSusChem, 10 (1), 99–105.



DOI: https://doi.org/10.22146/ijc.53131

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