Synthesis, Properties, and Function of Self-Healing Polymer-Based on Eugenol

Erwin Abdul Rahim(1*)

(1) Department of Chemistry, Tadulako University, Jl. Sukarno-Hatta Km 9, Palu 94148, Central Sulawesi, Indonesia
(*) Corresponding Author


Eugenol-based self-healing polymers were synthesized in a very short time of 94–159 s. Polymerization of eugenol catalyzed by H2SO4-CH3COOH yielded the corresponding self-healing polymers in quantitative yields in the range of molecular weight (5.18–15.10) × 105 g/mol. The polymer exhibited self-healing behavior at room temperature due to hydrogen bonds between the hydroxyl groups of polyeugenol and the hydroxyl groups of sulfuric acid. This material can function as a polyelectrolyte and a novel self-healing catalyst for biodiesel production.


self-healing polymer; eugenol; catalyst; biodiesel production

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[1] Cheng, C., Li, J., Yang, F., Li, Y., Hu, Z., and Wang, J., 2018, Renewable eugenol-based functional polymers with self-healing and high temperature resistance properties, J. Polym. Res., 25 (2), 67.

[2] Wang, H., Wang, P., Feng, Y., Liu, J., Wang, J., Hu, M., Wei, J., and Huang, Y., 2019, Recent advances on self-healing materials and batteries, Chem. Electro Chem, 6, 1605–1622.

[3] Liang, J.Y., Shin, S.R., Lee, S.H., and Lee, D.S., 2020, Self-healing and mechanical properties of thermoplastic polyurethane/eugenol-based phenoxy resin blends via exchange reactions, Polymers, 12 (5), 1011.

[4] Sumerlin, B.S., 2018, Next-generation self-healing materials, Science, 362 (6411), 150–151.

[5] Kumpfer, J.R., and Rowan, S.J., 2011, Thermo-, photo-, and chemo-responsive shape-memory properties from photo-cross linked metallo-supramolecular polymers, J. Am. Chem. Soc., 133 (32), 12866–12874.

[6] Terryn, S., Roels, E., Brancart, J., Van Assche, G., and Vanderborght, B., 2020, Self-healing and high interfacial strength in multi-material soft pneumatic robots via reversible Diels–Alder bonds, Actuators, 9 (2), 34.

[7] Jing, B.B., and Evans, C.M., 2019, Catalyst-free dynamic networks for recyclable, self-healing solid polymer electrolytes, J. Am. Chem. Soc., 141 (48), 18932−18937.

[8] Yao, P., Yu, H., Ding, Z., Liu, Y., Lu, J., Lavorgna, M., Wu, J., and Liu, X., 2019, Review on polymer-based composite electrolytes for lithium batteries, Front. Chem., 7, 522.

[9] Jo, Y.H., Li, S., Zuo, C., Zhang, Y., Gan, H., Li, S., Yu, L., He, D., Xie, X., and Xue, Z., 2020, Self-healing solid polymer electrolyte facilitated by a dynamic cross-linked polymer matrix for lithium-ion batteries, Macromolecules, 53 (3), 1024–1032.

[10] Ngai, K.S., Ramesh, S., Ramesh, K., and Juan, J.C., 2016, A review of polymer electrolyte: fundamental, approaches and application, Ionics, 22 (8), 1259−1279.

[11] Choudhury, S., Stalin, S., Vu, D., Warren, A., Deng, Y., Biswal, P., and Archer, L.A., 2019, Solid state polymer electrolytes for high-performance lithium metal batteries, Nat. Commun., 10 (1), 4398.

[12] Komintarachet, C., and Chuepeng, S., 2009, Solid acid catalyst for biodiesel production from waste used cooking oils, Ind. Eng. Chem. Res., 48 (20), 9350−9353.

[13] Zhang, J., Zhang, M., Tang, K., Verpoort, F., and Sun, T., 2013, Polymer-based stimuli-responsive recyclable catalytic systems for organic synthesis, Small,10 (1), 32−46.

[14] Bergbreiter, D.E., 2014, Soluble polymers as tools in catalysis, ACS Macro Lett., 3 (3), 260−265.

[15] Rahim, E.A, 2020, Synthesis of soluble novel polyecetylenes containing carbamate and eugenol moieties, Indones. J. Chem., 20 (4), 818–824.

[16] Rahim, E.A., Sanda, F., and Masuda, T., 2004, Synthesis and properties of novel eugenol-based polymers, Polym. Bull., 52 (2), 93–100.

[17] Rahim, E.A., Istiqomah, N., Almilda, G., Ridhay, A., Sumarni, N.K., and Indriani, 2020, Antibacterial and antioxidant activities of polyeugenol with high molecular weight, Indones. J. Chem., 20 (3), 722–728.

[18] Rahim, E.A., Sanda, F., and Masuda, T., 2006, Synthesis and properties of optically active amino acid based polyacetylenes bearing eugenol and fluorene moieties, J. Polym. Sci., Part A: Polym. Chem., 44 (2), 810–819.

[19] Rahim, E.A., 2018, Unique polymerization and new smart material of eugenol-based helical polymers, Int. J. Sci. Res., 7 (11), 990–996.

[20] Kajita, T., Tanaka, H., Noro, A., Matsuhita, Y., and Nakamura, N., 2019, Acidic liquid-swollen polymer membranes exhibiting anhydrous proton conductivity higher than 100 mS cm–1 at around 100 °C, J. Mater. Chem. A, 7 (26), 15585–15592.


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