Comparison of the Effectiveness of Calcined Chicken and Duck Eggshells as Zn Metal Adsorbent Using Atomic Absorption Spectrophotometric

https://doi.org/10.22146/ijc.74930

Hesty Nuur Hanifah(1*), Ginayanti Hadisoebroto(2), Cucun Cunayah(3), Diyanti Alma Kusuma Dani(4)

(1) Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Al Ghifari, Jl. Cisaranten Kulon No. 140, Bandung 40293, Indonesia
(2) Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Al Ghifari, Jl. Cisaranten Kulon No. 140, Bandung 40293, Indonesia
(3) Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Al Ghifari, Jl. Cisaranten Kulon No. 140, Bandung 40293, Indonesia
(4) Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Al Ghifari, Jl. Cisaranten Kulon No. 140, Bandung 40293, Indonesia
(*) Corresponding Author

Abstract


Zinc is a heavy metal that is often found in liquid waste and causes water pollution. Eggshells can be used as an adsorbent to reduce heavy metals in water because they have a lot of pores, CaCO3, and mucopolysaccharide acid protein. This study aimed to determine the effectiveness of a comparison between calcined chicken and duck eggshells to adsorb Zn, by determining the optimum pH, contact time, optimum mass, and the characterization of adsorbents. The results of this study showed that calcined chicken eggshells adsorb Zn at an optimum pH of 6, with the required optimum contact of 75 min and a mass of 400 mg with adsorption effectiveness of 99.64%. Meanwhile, calcined duck eggshells have an optimum pH of 6, an optimum contact time of 60 min, and an optimum mass of 400 mg with adsorption effectiveness of 99.73%. Activated carbon from the market has an adsorption effectiveness of 99.53%. So, it can be concluded that calcined chicken and duck eggshells can be used as zinc metal adsorbent.


Keywords


calcined chicken eggshells; calcined duck eggshells; adsorbent; zinc metal

Full Text:

Full Text PDF


References

[1] Hama Aziz, K.H., Mustafa, F.S., Omer, K.M., Hama, S., Hamarawf, R.F., and Rahman, K.O., 2023, Heavy metal pollution in the aquatic environment: Efficient and low-cost removal approaches to eliminate their toxicity: A review, RSC Adv., 13 (26), 17595–17610.

[2] Tran, H.N., Nguyen, H.C., Woo, S.H., Nguyen, T.V., Vigneswaran, S., Hosseini-Bandegharaei, A., Rinklebe, J., Kumar Sarmah, A., Ivanets, A., Dotto, G.L., Bui, T.T., Juang, R.S., and Chao, H.P., 2019, Removal of various contaminants from water by renewable lignocellulose-derived biosorbents: A comprehensive and critical review, Crit. Rev. Environ. Sci. Technol., 49 (23), 2155–2219.

[3] Qasem, N.A.A., Mohammed, R.H., and Lawal, D.U., 2021, Removal of heavy metal ions from wastewater: A comprehensive and critical review, npj Clean Water, 4 (1), 36.

[4] Hussain, S., Khan, M., Sheikh, T.M.M., Mumtaz, M.Z., Chohan, T.A., Shamim, S., and Liu, Y., 2022, Zinc essentiality, toxicity, and its bacterial bioremediation: A comprehensive insight, Front. Microbiol., 13, 900740.

[5] Bakka, A., Mamouni, R., Saffaj, N., Laknifli, A., Benlhachemi, A., Bakiz, B., El Haddad, M., Ait Taleb, M., Roudani, A., and Faouzi, A., 2016, The treated eggshells as a new biosorbent for elimination of carbaryl pesticide from aqueous solutions: Kinetics, thermodynamics and isotherms, Sci. Study Res.: Chem. Chem. Eng., Biotechnol., Food Ind., 17 (3), 271–284.

[6] Mohamed, Z., Abdelkarim, A., Ziat, K., and Mohamed, S., 2016, Adsorption of Cu(II) onto natural clay: Equilibrium and thermodynamic studies, J. Mater. Environ. Sci., 7 (2), 566–570.

[7] Yusuff, A.S., 2017, Preparation and characterization of composite anthill-chicken eggshell adsorbent: Optimization study on heavy metals adsorption using response surface methodology, J. Environ. Sci. Technol., 10 (3), 120–130.

[8] Murcia-Salvador, A., Pellicer, J.A., Rodríguez-López, M., Gómez-López, V., Núñez-Delicado, E., and Gabaldon, J., 2020, Egg by-products as a tool to remove direct blue desorption properties, Materials, 13 (6), 1262.

[9] Bhaumik, R., Mondal, N.K., Das, B., Roy, P., Pal, K.C., Das, C., Banerjee, A., and Datta, J.K., 2012, Eggshell powder as an adsorbent for removal of fluoride from aqueous solution: Equilibrium, kinetic and thermodynamic studies, E-J. Chem., 9 (3), 1457–1480.

[10] Tamang, M., and Paul, K.K., 2022, Adsorptive treatment of phenol from aqueous solution using chitosan/calcined eggshell adsorbent: Optimization of preparation process using Taguchi statistical analysis, J. Indian Chem. Soc., 99 (1), 100251.

[11] Rajoriya, S., Saharan, V.K., Pundir, A.S., Nigam, M., and Roy, K., 2021, Adsorption of methyl red dye from aqueous solution onto eggshell waste material: Kinetics, isotherms and thermodynamic studies, Curr. Res. Green Sustainable Chem., 4, 100180.

[12] Awogbemi, O., Von Kallon, D.V., and Aigbodion, V.S., 2022, Pathways for sustainable utilization of waste chicken eggshell, J. Renewable Mater., 10 (8), 2217–2246.

[13] Demiral, I., and Şamdan, C.A., 2016, Preparation and characterisation of activated carbon from pumpkin seed shell using H3PO4, Anadolu Univ. J. Sci. Technol., A, 17 (1), 125–138.

[14] Awogbemi, O., Inambao, F., and Onuh, E.I., 2020, Modification and characterization of chicken eggshell for possible catalytic applications, Heliyon, 6 (10), e05283.

[15] Ullah, A.K.M.A., Maksud, M.A., Khan, S.R., Lutfa, L.N., and Quraishi, S.B., 2017, Development and validation of a GF-AAS method and its application for the trace level determination of Pb, Cd, and Cr in fish feed samples commonly used in the hatcheries of Bangladesh, J. Anal. Sci. Technol., 8 (1), 15.

[16] Ravindran, G., Madhavi, M.R., and Abusahmin, B.S., 2018, Optimization of zinc(II) adsorption using agricultural waste, Int. J. Eng. Technol., 7 (3.34), 300–304.

[17] Zonato, R.O., Estevam, B.R., Perez, I.D., Aparecida dos Santos Ribeiro, V., and Boina, R.F., 2022, Eggshell as an adsorbent for removing dyes and metallic ions in aqueous solutions, Cleaner Chem. Eng., 2, 100023.

[18] Mrosso, R., Mecha, A.C., and Kiplagat, J., 2023, Carbon dioxide removal using a novel adsorbent derived from calcined eggshell waste for biogas upgrading, S. Afr. J. Chem. Eng., 47, 150–158.

[19] Razali, N., Jumadi, N., Jalani, A.Y., Kamarulzaman, N.Z., and Pa’ee, K.F., 2022, Thermal decomposition of calcium carbonate in chicken eggshells: Study on temperature and contact time, Malays. J. Anal. Sci., 26 (2), 347–359.

[20] Neme, I., Gonfa, G., and Masi, C., 2022, Activated carbon from biomass precursors using phosphoric acid: A review, Heliyon, 8 (12), e11940.

[21] Spencer, W., Senanayake, G., Altarawneh, M., Ibana, D., and. Nikoloski, A.N., 2024, Review of the effects of coal properties and activation parameters on activated carbon production and quality, Miner. Eng., 212, 108712.

[22] Alhasan, H.S., Alahmadi, N., Yasin, S.A., Khalaf, M.Y., and Ali, G.A.M., 2022, Low-cost and eco-friendly hydroxyapatite nanoparticles derived from eggshell waste for cephalexin removal, Separations, 9 (10), 10.

[23] Mohadi, R., Anggraini, K., Riyanti, F., and Lesbani, A., 2016, Preparation calcium oxide from chicken eggshells, Sriwijaya J. Environ., 1 (2), 32–35.

[24] Li, H., Budarin, V.L., Clark, J.H., North, M., and Wu, X., 2022, Rapid and efficient adsorption of methylene blue dye from aqueous solution by hierarchically porous, activated starbons®: Mechanism and porosity dependence, J. Hazard. Mater., 436, 129174.

[25] El-Bery, H.M., Saleh, M., El-Gendy, R.A., Saleh, M.R., and Thabet, S.M., 2022, High adsorption capacity of phenol and methylene blue using activated carbon derived from lignocellulosic agriculture wastes, Sci. Rep., 12 (1), 5499.

[26] Alqaheem, Y., and Alomair, A.A., 2020, Microscopy and spectroscopy techniques for characterization of polymeric membranes, Membranes, 10 (2), 33.

[27] Nasrazadani, S., and Hassani, S., 2016, “Chapter 2 - Modern analytical techniques in failure analysis of aerospace, chemical, and oil and gas industries” in Handbook of Materials Failure Analysis with Case Studies from the Oil and Gas Industry, Eds. Makhlouf, A.S.H., and Aliofkhazraei, M., Butterworth-Heinemann, UK, 39–54.

[28] Balasubramanian, V., Daniel, T., Henry, J., Sivakumar, G., and Mohanraj, K., 2020, Electrochemical performances of activated carbon prepared using eggshell waste, SN Appl. Sci., 2 (1), 127.

[29] Lutfi, N.N.H., and Rizal, F., 2022, Analysis of the heavy metal content of Zinc (Zn) in tofu using atomic absorption spectrophotometer (AAS), Asian J. Health Appl. Sci., 1 (3), 30–34.

[30] Aquisman, A.E., Bin Assim, Z., Binti Wahi, R., Kwabena, D.E., and Festus, W., 2019, Validation of the atomic absorption spectroscopy (AAS) for heavy metal analysis and geochemical exploration of sediment samples from the Sebangan river, Adv. Anal. Chem., 9 (2), 23–33.

[31] Epshtein, N.A., 2019, Validation of analytical procedures: Graphic and calculated criteria for assessment of methods linearity in practice, Drug Dev. Regist., 8 (2), 122–130.

[32] Abatan, O.G., Alaba, P.A., Oni, B.A., Akpojevwe, K., Efeovbokhan, V., and Abnisa, F., 2020, Performance of eggshells powder as an adsorbent for adsorption of hexavalent chromium and cadmium from wastewater, SN Appl. Sci., 2 (12), 1996.

[33] Badrealam, S., Roslan, F.S., Dollah, Z., Bakar, A.A.A., and Handan, R., 2018, Exploring the eggshell from household waste as alternative adsorbent for heavy metal removal from wastewater, AIP Conf. Proc., 2020 (1), 020077.



DOI: https://doi.org/10.22146/ijc.74930

Article Metrics

Abstract views : 2563 | views : 1412


Copyright (c) 2024 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.