Codoping of Nickel and Nitrogen in ZrO2-TiO2 Composite as Photocatalyst for Methylene Blue Degradation under Visible Light Irradiation

https://doi.org/10.22146/ijc.90151

Akhmad Syoufian(1*), Rian Kurniawan(2)

(1) Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(2) Institute of Chemical Technology, Universität Leipzig, Linnéster. 3, 04103 Leipzig, Germany
(*) Corresponding Author

Abstract


Nickel (Ni) and nitrogen (N) as codopants had been introduced into ZrO2-TiO2 composite photocatalyst. The objectives of this study are to investigate the codoping effect of Ni and N, as well as the calcination temperature towards the ability to photodegrade methylene blue (MB) under the irradiation of visible light. Different amounts of Ni dopant (wNi/wTi = 2–10%) along with a fixed amount of N dopant (wN/wTi = 10%) were applied to the ZrO2-TiO2 composite through the sol-gel method. Crystallization of the composite was done by calcination at 500, 700, and 900 °C. Characterization of the composite was done using Fourier-transform infrared spectrophotometer (FTIR), X-ray diffractometer (XRD), specular reflectance UV-visible spectrophotometer (SR-UV) and scanning electron microscopy equipped with energy dispersive X-ray spectrometer (SEM-EDX). The photocatalytic activity of the composite was evaluated by photodegradation of 4 mg L−1 MB solution under visible light irradiation at various reaction times. The lowest band gap was achieved until 2.79 eV by the composite with 6% Ni and 10% N calcined at 900 °C. The highest MB degradation percentage up to 61% was obtained by the composite with 6% Ni and 10% N calcined at 500 °C (kobs = 7.8 × 10−3 min−1).

Keywords


methylene blue; codoping; photodegradation; ZrO2-TiO2

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References

[1] Thabede, P.M., Shooto, N.D., and Naidoo, E.B., 2020, Removal of methylene blue dye and lead ions from aqueous solution using activated carbon from black cumin seeds, S. Afr. J. Chem. Eng., 33, 39–50.

[2] Abu-Nada, A., Abdala, A., and McKay, G., 2021, Removal of phenols and dyes from aqueous solutions using graphene and graphene composite adsorption: A review, J. Environ. Chem. Eng., 9 (5), 105858.

[3] Akpomie, K.G., and Conradie, J., 2020, Advances in application of cotton-based adsorbents for heavy metals trapping, surface modifications and future perspectives, Ecotoxicol. Environ. Saf., 201, 110825.

[4] Bayramoglu, G., Kunduzcu, G., and Arica, M.Y., 2020, Preparation and characterization of strong cation exchange terpolymer resin as effective adsorbent for removal of disperse dyes, Polym. Eng. Sci., 60 (1), 192–201.

[5] Badawi, A.K., and Zaher, K., 2021, Hybrid treatment system for real textile wastewater remediation based on coagulation/flocculation, adsorption and filtration processes: Performance and economic evaluation, J. Water Process Eng., 40, 101963.

[6] Wang, X., Xia, J., Ding, S., Zhang, S., Li, M., Shang, Z., Lu, J., and Ding, J., 2020, Removing organic matters from reverse osmosis concentrate using advanced oxidation-biological activated carbon process combined with Fe3+/humus-reducing bacteria, Ecotoxicol. Environ. Saf., 203, 110945.

[7] Al-Sakkaf, M.K., Basfer, I., Iddrisu, M., Bahadi, S.A., Nasser, M.S., Abussaud, B., Drmosh, Q.A., and Onaizi, S.A., 2023, An up-to-date review on the remediation of dyes and phenolic compounds from wastewaters using enzymes immobilized on emerging and nanostructured materials: Promises and challenges, Nanomaterials, 13 (15), 2152.

[8] Dória, A.R., Pupo, M., de Oliveira Santiago Santos, G., da Silva Vilar, D., Torres, N.H., Romanholo Ferreira, L.F., Cavalcanti, E.B., Eguiluz, K.I.B., and Salazar-Banda, G.R., 2020, Electrochemical oxidation of indanthrene blue dye in a filter-press flow reactor and toxicity analyses with Raphidocelis subcapitata and Lactuca sativa, Ecotoxicol. Environ. Saf., 198, 110659.

[9] Al-Tohamy, R., Ali, S.S., Li, F., Okasha, K.M., Mahmoud, Y.A.G., Elsamahy, T., Jiao, H., Fu, Y., and Sun, J., 2022, A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety, Ecotoxicol. Environ. Saf., 231, 113160.

[10] Ulfa, M., Al Afif, H., Saraswati, T.E., and Bahruji, H., 2022, Fast removal of methylene blue via adsorption-photodegradation on TiO2/SBA-15 synthesized by slow calcination, Materials, 15 (16), 5471.

[11] Vasiljevic, Z.Z., Dojcinovic, M.P., Vujancevic, J.D., Jankovic-Castvan, I., Ognjanovic, M., Tadic, N.B., Stojadinovic, S., Brankovic, G.O., and Nikolic, M.V., 2020, Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol–gel method, R. Soc. Open Sci., 7 (9), 200708.

[12] Sherly, E.D., Vijaya, J.J., Selvam, N.C.S., and Kennedy, L.J., 2014, Microwave assisted combustion synthesis of coupled ZnO-ZrO2 nanoparticles and their role in the photocatalytic degradation of 2,4-dichlorophenol, Ceram. Int., 40 (4), 5681–5691.

[13] Hamad, H., Bailón-García, E., Pérez-Cadenas, A.F., Maldonado-Hódar, F.J., and Carrasco-Marín, F., 2020, ZrO2-TiO2/Carbon core-shell composites as highly efficient solar-driven photo-catalysts: An approach for removal of hazardous water pollutants, J. Environ. Chem. Eng., 8 (5), 104350.

[14] Huang, W.C., and Ting, J.M., 2017, Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response, Ceram. Int., 43 (13), 9992–9997.

[15] Wang, H., Zhang, L., Chen, Z., Hu, J., Li, S., Wang, Z., Liu, J., and Wang, X., 2014, Semiconductor heterojunction photocatalysts: Design, construction, and photocatalytic performances, Chem. Soc. Rev., 43 (15), 5234–5244.

[16] Zhang, J., Zhou, P., Liu, J., and Yu, J., 2014, New understanding of the difference of photocatalytic activity among anatase, rutile and brookite TiO2, Phys. Chem. Chem. Phys., 16 (38), 20382–20386.

[17] Dutta, H., Nandy, A., and Pradhan, S.K., 2016, Microstructure and optical characterizations of mechanosynthesized nanocrystalline semiconducting ZrTiO4 compound, J. Phys. Chem. Solids, 95, 56–64.

[18] Guerrero-Araque, D., Ramírez-Ortega, D., Acevedo-Peña, P., Tzompantzi, F., Calderón, H.A., and Gómez, R., 2017, Interfacial charge-transfer process across ZrO2-TiO2 heterojunction and its impact on photocatalytic activity, J. Photochem. Photobiol., A, 335, 276–286.

[19] Zhang, J., Li, L., Xiao, Z., Liu, D., Wang, S., Zhang, J., Hao, Y., and Zhang, W., 2016, Hollow sphere TiO2-ZrO2 prepared by self-assembly with polystyrene colloidal template for both photocatalytic degradation and H2 evolution from water splitting, ACS Sustainable Chem. Eng., 4 (4), 2037–2046.

[20] Takahashi, H., Sunagawa, Y., Myagmarjav, S., Yamamoto, K., Sato, N., and Muramatsu, A., 2003, Reductive deposition of Ni-Zn nanoparticles selectively on TiO2 fine particles in the liquid phase, Mater. Trans., 44 (11), 2414–2416.

[21] Sun, X., Liu, H., Dong, J., Wei, J., and Zhang, Y., 2010, Preparation and characterization of Ce/N-codoped TiO2 particles for production of H2 by photocatalytic splitting water under visible light, Catal. Lett., 135 (3), 219–225.

[22] Kim, C.S., Shin, J.W., Cho, Y.H., Jang, H.D., Byun, H.S., and Kim, T.O., 2013, Synthesis and characterization of Cu/N-doped mesoporous TiO2 visible light photocatalysts, Appl. Catal., A, 455, 211–218.

[23] Samangsri, S., Areerob, T., and Chiarakorn, S., 2023, Development of visible light-responsive N-doped TiO2/SiO2 core–shell nanoparticles for photocatalytic degradation of methylene blue dye, Res. Chem. Intermed., 49 (4), 1649–1664.

[24] Asahi, R., Morikawa, T., Irie, H., and Ohwaki, T., 2014, Nitrogen-doped titanium dioxide as visible-light-sensitive photocatalyst: Designs, developments, and prospects, Chem. Rev., 114 (19), 9824–9852.

[25] Chaudhari, S.M., Gawal, P.M., Sane, P.K., Sontakke, S.M., and Nemade, P.R., 2018, Solar light-assisted photocatalytic degradation of methylene blue with Mo/TiO2: A comparison with Cr- and Ni-doped TiO2, Res. Chem. Intermed., 44 (5), 3115–3134.

[26] Hayati, R., Kurniawan, R., Prasetyo, N., Sudiono, S., and Syoufian, A., 2022, Codoping effect of nitrogen (N) to iron (Fe) doped zirconium titanate (ZrTiO4) composite toward its visible light responsiveness as photocatalysts, Indones. J. Chem., 22 (3), 692–702.

[27] Rahmawati, L., Kurniawan, R., Prasetyo, N., Sudiono, S., and Syoufian, A., 2023, Copper-and-nitrogen-codoped zirconium titanate (Cu-N-ZrTiO4) as a photocatalyst for photo-degradation of methylene blue under visible-light irradiation, Indones. J. Chem., 23 (2), 416–424.

[28] Zhang, X., and Liu, Q., 2008, Visible-light-induced degradation of formaldehyde over titania photocatalyst co-doped with nitrogen and nickel, Appl. Surf. Sci., 254 (15), 4780–4785.

[29] Adam, F., and Chua, J.H., 2004, The adsorption of palmytic acid on rice husk ash chemically modified with Al(III) ion using the sol-gel technique, J. Colloid Interface Sci., 280 (1), 55–61.

[30] Syoufian, A., and Nakashima, K., 2008, Degradation of methylene blue in aqueous dispersion of hollow titania photocatalyst: Study of reaction enhancement by various electron scavengers, J. Colloid Interface Sci., 317 (2), 507–512.

[31] Cong, Y., Zhang, J., Chen, F., and Anpo, M., 2007, Synthesis and characterization of nitrogen-doped TiO2 nanophotocatalyst with high visible light activity, J. Phys. Chem. C, 111 (19), 6976–6982.

[32] Wang, Q., Jin, R., Zhang, M., and Gao, S., 2017, Solvothermal preparation of Fe-doped TiO2 nanotube arrays for enhancement in visible light induced photoelectrochemical performance, J. Alloys Compd., 690, 139–144.

[33] Suwannaruang, T., Kidkhunthod, P., Chanlek, N., Soontaranon, S., and Wantala, K., 2019, High anatase purity of nitrogen-doped TiO2 nanorice particles for the photocatalytic treatment activity of pharmaceutical wastewater, Appl. Surf. Sci., 478, 1–14.

[34] El-Sherbiny, S., Morsy, F., Samir, M., and Fouad, O.A., 2014, Synthesis, characterization and application of TiO2 nanopowders as special paper coating pigment, Appl. Nanosci., 4 (3), 305–313.

[35] León, A., Reuquen, P., Garín, C., Segura, R., Vargas, P., Zapata, P., and Orihuela, P.A., 2017, FTIR and Raman characterization of TiO2 nanoparticles coated with polyethylene glycol as carrier for 2-methoxyestradiol, Appl. Sci., 7 (1), 49.

[36] Doufar, N., Benamira, M., Lahmar, H., Trari, M., Avramova, I., and Caldes, M.T., 2020, Structural and photochemical properties of Fe-doped ZrO2 and their application as photocatalysts with TiO2 for chromate reduction, J. Photochem. Photobiol., A, 386, 112105.

[37] Reddy, C.V., Reddy, I.N., Reddy, K.R., Jaesool, S., and Yoo, K., 2019, Template-free synthesis of tetragonal Co-doped ZrO2 nanoparticles for applications in electrochemical energy storage and water treatment, Electrochim. Acta, 317, 416–426.

[38] Alijani, M., Kaleji, B.K., and Rezaee, S., 2017, Improved visible light photocatalytic activity of TiO2 nano powders with metal ions doping for glazed ceramic tiles, Opt. Quantum Electron., 49 (6), 225.

[39] Agorku, E.S., Kuvarega, A.T., Mamba, B.B., Pandey, A.C., and Mishra, A.K., 2015, Enhanced visible-light photocatalytic activity of multi-elements-doped ZrO2 for degradation of indigo carmine, J. Rare Earths, 33 (5), 498–506.

[40] Nolan, N.T., Synnott, D.W., Seery, M.K., Hinder, S.J., Van Wassenhoven, A., and Pillai, S.C., 2012, Effect of N-doping on the photocatalytic activity of sol-gel TiO2, J. Hazard. Mater., 211-212, 88–94.

[41] Martínez-Castañón, G.A., Sánchez-Loredo, M.G., Martínez-Mendoza, J.R., and Ruiz, F., 2005, Synthesis of CdS nanoparticles: A simple method in aqueous media, Adv. Technol. Mater. Mater. Process., 7 (2), 171–174.

[42] Riaz, N., Mohamad Azmi, B.K., and Mohd Shariff, A., 2014, Iron doped TiO2 photocatalysts for environmental applications: Fundamentals and progress, Adv. Mater. Res., 925, 689–693.

[43] Jaiswal, R., Bharambe, J., Patel, N., Dashora, A., Kothari, D.C., and Miotello, A., 2015, Copper and Nitrogen co-doped TiO2 photocatalyst with enhanced optical absorption and catalytic activity, Appl. Catal., B, 168-169, 333–341.

[44] Singh, H., Sunaina, S., Yadav, K.K., Bajpai, V.K., and Jha, M., 2020, Tuning the bandgap of m-ZrO2 by incorporation of copper nanoparticles into visible region for the treatment of organic pollutants, Mater. Res. Bull., 123, 110698.

[45] Piątkowska, A., Janus, M., Szymański, K., and Mozia, S., 2021, C-, N- and S-doped TiO2 photocatalysts: A review, Catalysts, 11 (1), 144.

[46] Syoufian, A., and Kurniawan, R., 2023, Visible-light-induced photodegradation of methylene blue using Mn,N-codoped ZrTiO4 as photocatalyst, Indones. J. Chem., 23 (3), 661–670.

[47] Luttrell, T., Halpegamage, S., Tao, J., Kramer, A., Sutter, E., and Batzill, M., 2015, Why is anatase a better photocatalyst than rutile? - Model studies on epitaxial TiO2 films, Sci. Rep., 4 (1), 4043.



DOI: https://doi.org/10.22146/ijc.90151

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