Optimum and Green Fabrication of MIL-100(Fe) for Crystal Violet Dye Removal from Aqueous Solution

Christian Julius Wijaya; Felycia Edi Soetaredjo; Maria Yuliana; Shella Permatasari Santoso; Sandy Budi Hartono; Wenny Irawaty; Jenni Lie; Jindrayani Nyoo Putro; Chintya Gunarto; Nathania Puspitasari; Suryadi Ismadji; Setiyo Gunawan

doi:10.22146/ijc.93323

Optimum and Green Fabrication of MIL-100(Fe) for Crystal Violet Dye Removal from Aqueous Solution

https://doi.org/10.22146/ijc.93323

Christian Julius Wijaya^(1*), Felycia Edi Soetaredjo⁽²⁾, Maria Yuliana⁽³⁾, Shella Permatasari Santoso⁽⁴⁾, Sandy Budi Hartono⁽⁵⁾, Wenny Irawaty⁽⁶⁾, Jenni Lie⁽⁷⁾, Jindrayani Nyoo Putro⁽⁸⁾, Chintya Gunarto⁽⁹⁾, Nathania Puspitasari⁽¹⁰⁾, Suryadi Ismadji⁽¹¹⁾, Setiyo Gunawan⁽¹²⁾

(1) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(2) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(3) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(4) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(5) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(6) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(7) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(8) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(9) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(10) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(11) Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
(12) Department of Chemical Engineering, Faculty of Industrial Technology and Systems Engineering, Institut Teknologi Sepuluh Nopember, Keputih Sukolilo, Surabaya 60111, Indonesia
(*) Corresponding Author

Abstract

MIL-100(Fe) was prepared and subsequently used to remove crystal violet dye from aqueous solutions simulating dye-containing wastewater in the environment. In the future, it is aimed that MIL-100(Fe) can be used in managing dye-containing wastewater in the environment and reducing the negative impacts it can cause. Here, MIL-100(Fe) fabrication needs to be optimized to obtain optimum process conditions, which are environmentally friendly and can produce MIL-100(Fe) with the best characteristics. This study focused on optimizing the fabrication of MIL-100(Fe), which is a type of MOF with good chemical stability, thermal stability, and flexible structure. In this study, the room-temperature fabrication of MIL-100(Fe) was established using a ligand-to-metal molar ratio of 0.95 and an acetic acid concentration of 5.1 vol% for 6.2 h. The optimum MIL-100(Fe) was tested for crystal violet removal and provided an optimum removal capacity of 182.66 ± 3.81 mg/g. Statistical approaches are used to investigate the independent parameters and their interactions contributing to MIL-100(Fe) formation.

Keywords

crystal violet dye; metal-organic frameworks; MIL-100(Fe); optimization; statistical approach

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DOI: https://doi.org/10.22146/ijc.93323