Kinetic Study of Fulvate Complex Dissolution of Fe, Mn, Zn, Cu, Ni, and Mo from Hydrolyzed Rice Hush Ash Composite (CSH) and Evaluation of Its Performance in Increasing Essential Micronutrient Content in Cempo Merah and Cempo Putih Rice

Agus Kuncaka; Andika Rifqi Rayendra; Dilla Karuniawati; Rifka Ayu Kurniawati; Dwi Siswanta; Mudasir Mudasir; Adhitasari Suratman

doi:10.22146/ijc.98791

Kinetic Study of Fulvate Complex Dissolution of Fe, Mn, Zn, Cu, Ni, and Mo from Hydrolyzed Rice Hush Ash Composite (CSH) and Evaluation of Its Performance in Increasing Essential Micronutrient Content in Cempo Merah and Cempo Putih Rice

https://doi.org/10.22146/ijc.98791

Agus Kuncaka^(1*), Andika Rifqi Rayendra⁽²⁾, Dilla Karuniawati⁽³⁾, Rifka Ayu Kurniawati⁽⁴⁾, Dwi Siswanta⁽⁵⁾, Mudasir Mudasir⁽⁶⁾, Adhitasari Suratman⁽⁷⁾

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(5) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(6) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(7) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(*) Corresponding Author

Abstract

This study aimed to make humic composite (CSH), a humus-like material that serves as synthetic humus, that can function as a source of micronutrients in the soil and carry micronutrients to plants through the formed fulvate complex. Qualitative analysis of the micronutrient content of Fe, Mn, Zn, Cu, Ni, and Mo had been carried out using EDX, XRF and ESR spectroscopies, while quantitative analysis was carried out through atomic absorption spectrometry and UV-vis spectrophotometry of fulvic acid and humic acid in CSH. Quantitative analysis was carried out to determine micronutrient content in composite and rice samples using AAS. The results showed that the micronutrient content of Fe, Mn, Zn, Cu, Ni, and Mo in Cempo Putih and Cempo Merah rice applied with CSH was significantly higher compared to commercial rice. The desorption test of Fe, Mn, Zn, Cu, Ni, and Mo from the composite at various pH showed that the optimum pH for desorption occurred at pH 5. The desorption kinetics of Fe, Mn, Zn, Cu, Ni, and Mo from the composite followed a pseudo-second-order kinetic model. Analysis ESR showed that the paramagnetic fulvate complexes detected were only Fe complexes and Mn complexes.

Keywords

synthetic humus; fulvate complexes; kinetics; desorption; essential micronutrients

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DOI: https://doi.org/10.22146/ijc.98791