Wormhole-Like Mesoporous Carbons from Gelatine as Multistep Infiltration Effect

Maria Ulfa; Wega Trisunaryanti; Iip Izul Falah; Indriana Kartini

doi:10.22146/ijc.21137

Wormhole-Like Mesoporous Carbons from Gelatine as Multistep Infiltration Effect

https://doi.org/10.22146/ijc.21137

Maria Ulfa^(1*), Wega Trisunaryanti⁽²⁾, Iip Izul Falah⁽³⁾, Indriana Kartini⁽⁴⁾

(1) Chemical Education Study Program, Faculty of Teacher Training and Education, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta 57126, Central Java Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21, Yogyakarta 55281
(*) Corresponding Author

Abstract

Wormhole-like mesoporous carbon from gelatine (WMCG) with two different pore diameters have been synthesized by adopting a modified infiltration treatment. The infiltration effect on the morphology was investigated. The results show that the WMCG sample was obtained after dehydration, pyrolysis and silica removal process. The pore diameters WMCG are 15.2 and 4.8 nm with specific surface areas of 280 m²/g, total pore volumes of 0.5 cm³/g and the thermal stability up to 1400 °C. The bimodal pore of WMCG obtained as the high step of infiltration level effect.

Keywords

gelatine; infiltration; wormhole-like mesoporous carbon

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References

[1] Ulfa, M., Trisunaryanti, W., Falah, I.I., Kartini, I., and Sutarno, 2014, J. Appl. Chem., 7 (5), 1–7.

[2] Ulfa, M., Trisunaryanti, W., Falah, I.I., Kartini, I., and Sutarno, 2014, J. Chem. Eng., 4, 112–119.

[3] Ulfa, M., Trisunaryanti, W., Falah, I.I., Kartini, I., and Sutarno, 2014, Int. J. Innovation Appl. Stud., 7 (3), 849–856.

[4] Liu, J., Li, Z., He, C., Fu, R., Wu, D., and Song, S., 2010, Int. J. Hydrogen Energy, 36 (3), 2250–2257.

[5] Ting, C.C., Wu, H.Y., Vetrivel, S., Saikia, D., Pan, Y.C., Fey, G.T.K., and Kao, H.M., 2010, Microporous Mesoporous Mater., 128 (1-3), 1–11.

[6] Kosuge, K., and Singh, P.S., 2001, Microporous Mesoporous Mater., 44-45, 139–145.

[7] Wang, X., Li, W., Zhu, G., Qiu, S., Zhao, D., and Zhong, B., 2004, Microporous Mesoporous Mater., 71 (1-3), 87-97.

[8] Coradin, T., Bah, S., and Livage, J., 2004, Colloids Surf., B, 35 (1), 53–58.

[9] Yang, J., Zhai, Y., Deng, Y., Gu, D., Li, Q., Wu, Q., and Bo. Y.H., 2010, J. Colloid Interface Sci., 342 (2), 579–585.

[10] Bele, M., Gaberscek, M., Dominko, R., Drofenik, J., Zupan, K., Komac, P., Kucevar, K., Musevic, I., and Pejovnik, S., 2002, Carbon, 40 (7), 1117–1122.

[11] Ge, J., Shi, J., and Chen, L., 2009, Carbon, 47 (4), 1192–1195.

[12] Kang, S., Jian-chun, J., and Dan-dan, C., 2011, Biomass Bioenergy, 35 (8), 3643–3647

[13] Liou, T.H., 2010, Chem. Eng. J., 158 (2), 129–142.

[14] Böhme, K., Einicke, W.D., and Klepel, O., 2005, Carbon, 43 (9), 1918–1925.

[15] Sobiesiak, M., 2012, New Carbon Mater., 27 (5), 337–343.

[16] Guo, R., Guo, J., Yu, F., and Gang, D.D., 2013, Microporous Mesoporous Mater., 175, 141–146.

[17] Hayakawa, S., Kanaya, T., Tsuru, K., Shirosaki, Y., Osaka, A., Fujii, E., Kawabata, K., Gasqueres, G., Bonhomme, C., Babonneau, F., Jäger, C., and Kleebe, H.J., 2013, Acta Biotheor., 9 (1), 4856–4867.

[18] Diefallah, E.M., 1992, Thermochim. Acta, 202, 1–16.

[19] Frunza, L., 2003, Microporous Mesoporous Mater., 11 (1), 856–860.

[20] Zhu, S., Zhou, H., Hibino, M., Honma, I., and Ichihara, M., 2004, Mater. Chem. Phys., 88 (1), 202–206.

DOI: https://doi.org/10.22146/ijc.21137