Preparation and Pb(II) Adsorption Properties of Crosslinked Pectin-Carboxymethyl Chitosan Film

https://doi.org/10.22146/ijc.21192

Budi Hastuti(1*), Mudasir Mudasir(2), Dwi Siswanta(3), Triyono Triyono(4)

(1) Department of Chemistry Education, Faculty of Faculty of Teacher Training and Education, Universitas Sebelas Maret, Jl. Ir. Sutami 36A Surakarta 57126
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(*) Corresponding Author

Abstract


A modified pectin has been synthesized by reacting/combining -OH group among pectin and chitosan with BADGE (Bisphenol A diglycidyl ether) crosslinker agent. The structure and morphology of the new material were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and X-ray Diffraction (XRD) analysis. Thermogravimetric studies showed an improvement in thermal characteristic. Adsorption experiments were performed in batch processes; sorption isotherms and kinetics were also studied. The Langmuir and Freundlich adsorption isotherm models were applied to describe the isotherms and isotherm constants for the adsorption of Pb(II) ion onto adsorbent pectin-carboxymethyl chitosan-BADGE (pec-CMC-BADGE). The dynamic study showed that the sorption process followed the second-order kinetic equation. Result indicated also that Pb(II) ion uptake could be well described by the Langmuir and Freundlich adsorption model of pec-CMC-BADGE and CMC with DG° of 25.3 and 23.1 kJ mol-1,respectively, while that of pectin followed Freundlich isotherm with DG° of 16.6 kJ mol-1.

Keywords


pectin; carboxymethyl chitosan; BADGE; adsorption; Pb(II)

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References

[1] Chen, C.Y., Yang, C.Y., and Chen, A.H., 2011, J. Environ. Manage., 92 (3), 796–802.

[2] Yan, H., Dai, J., Yang, Z., Yang, H., and Cheng, R., 2011, Chem. Eng. J., 174 (2-3), 586–594.

[3] Kandile, N.G., and Nasr, A.S., 2009, Carbohydr. Polym., 78 (4), 753–759.

[4] Stumm, W., and Morgan, J.J., 1966, Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters, John Wiley and Sons, Inc., New York, 727–759.

[5] Yoshimura, T., Sengoku, K., and Fujioka, R., 2005, Polym. Bull., 55 (1), 123–129.

[6] Chen, A.H., Yang, C.Y., Chen, C.Y., and Chen, C.W., 2009, J. Hazard. Mater., 163 (2-3), 1068–1075.

[7] Chen, A.H., Liu, S.C., Chen, C.Y., and Chen, C.Y., 2008, J. Hazard. Mater., 154 (1-3),184–191.

[8] Oshita, K., Oshima, M., Gao, Y., Lee, K.H., and Motomizu, S., 2002, Anal. Sci., 18 (10), 1121–1125.

[9] Cai, Z., Song, Z., Yang, C., Shang, S., and Yin, Y., 2009, Polym. Bull., 62 (4), 445–456.

[10] Zhu, A., Pan, Y., Liao, T., Zhao F., and Chen, T., 2007, J. Biomed. Mater. Res., Part B, 85 (2), 489–495.

[11] De Mello, K.G.P.C, Bernusso, L.C., Pitombo, R.N.M., and Polakiewicz, B., 2006, Braz. Arch. Biol. Technol., 49 (4), 665–668.

[12] Mourya, V.K., Inamdara, N.N., and Tiwari, A., 2010, Adv. Mater. Lett., 1 (1), 11–33.

[13] Ardelean, E., Nicu, R., Asandei, D., and Bobu, E., 2009, Eur. J. Sci. Theol., 5(4), 67–75.

[14] Lim, J., Yoo, J., Ko, S., and Lee, S., 2012, Food Hydrocolloids, 29 (1), 160–165.

[15] Wai, W.W., AlKarkhi, A.F.M., and Easa, A.M., 2010, Carbohydr. Polym., 79 (3), 584–589.

[16] Kumar, A., and Chauhan, G.S., 2010, Carbohydr. Polym., 82 (2), 454–459.

[17] Bigucci F., Luppi, B., Cerchiara, T., Sorrenti, M., Bettinetti, G., Rodriguez, L., and Zecchi, V., 2008, Eur. J. Pharm. Sci., 35 (5), 435–441.

[18] Ghaffari, A., Navaee, K., Oskoui, M., Bayati, A., and Rafiee-Tehrani, M., 2007, Eur. J. Pharm. Biopharm., 67 (1), 175–186.

[19] Bernabé, P., Peniche, C., and Argüelles-Monal, W., 2005, Polym. Bull., 55 (5), 367–375.

[20] Jiao, T.F, Zhou, J., Zhou, J.X., Gao, L.H., Xing, Y.Y., and Li, X.H., 2011, Iranian Polym. J., 20 (2), 123–136.

[21] Cestari, A.R., Viera, E.F.S., Matos, J.D.S., and dos Anjos, D.S.C., 2005, J. Colloid Interface Sci., 285 (1), 288–295.

[22] Ho, Y.S., and McKay, G., 1999, Process Biochem., 34 (5), 451–465.

[23] Masykur, A., Santosa, S.J., Siswanta, D., and Jumina, 2014, Indones. J. Chem., 14 (1), 63–70.



DOI: https://doi.org/10.22146/ijc.21192

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