KINETIC INVESTIGATION OF CARBON DIOXIDE, ACETIC ACID, ACRYLIC ACID FORMATION ON DILUTED AND LEACHED MoVTeNb CATALYST

https://doi.org/10.22146/ijc.21352

Restu Kartiko Widi(1*)

(1) Department of Chemical Engineering, Faculty of Engineering, University of Surabaya (UBAYA), TG Building 6th floor, Jln. Raya Kalirungkut Tenggilis, Surabaya, 60293
(*) Corresponding Author

Abstract


Reaction kinetics for the oxidation of propane over diluted-leached MoVTeNb is described. This paper is focused on the study of determination of the orders of carbon dioxide, acetic acid and acrylic acid formation. Deep oxidation of propane to carbon dioxide is first order with respect to hydrocarbon, and partial order (0.31) with respect to oxygen. The selective oxidation of propane to acrylic acid is partial order (0.49) with respect to hydrocarbon and partial order (0.09) with respect to oxygen.

Keywords


propane oxidation; catalyst; selective oxidation; kinetic; acrylic acid

Full Text:

Full Text PDF


References

[1] Boizumault-Moriceau, P., Pennequin, A., Grzybowska, B., and Barbaux, Y., 2003, Appl. Catal. A, 245, 55–67.

[2] Grzybowska Swierkosz, B., 2000, Top. Catal., 11-12, 23–42.

[3] Grzybowska-Swierkosz, B., 2002, Top. Catal., 21, 175

[4] Novakova, E.K., Vedrine, J.C., and Derouane, E.G., 2002, J. Catal., 211, 226–234.

[5] Vedrine, J.C., Novakokva, E.K., and Derouane, E.G., 2003, Catal. Today, 81, 2, 247–262.

[6] Widi, R.K., Hamid, S.B.A., and Schlogl, R., 2009, React. Kinet. Catal. Lett., 98, 2, 273–286.

[7] Widi, R.K, 2010, Indo. J. Chem., 10, 2, 172–176.

[8] Jacob, B.W., Olaf, T., Fazliana, A.H., Annette, T., Ute, W., Dang, S.S., Restu, K.W., Sharifah, B.A.H., and Robert, S., 2006, Top Catal., 39, 1-2, 51–61.

[9] Widi, R.K., Hamid, S.B.A., and Schlogl, R., 2008, J. Nat. Gas Chem., 17, 2, 130–134.

[10] Lin, M.M., 2001, Appl. Catal. A, 207, 1–7.

[11] Botela, P., Solsona, B., Martinez-Arias, A., and Lopez-Nieto, J.M., 2001, Catal. Lett., 74, 3-4, 149–155.

[12] Lin, M., Desai, T.B., Kaiser, F.W., and Klugherz, P.D., 2000, Catal. Today, 61, 223–229.

[13] Fogler, H.S., 1999, Elements of Chemical Reaction Engineering, 3rd ed., Prentice-Hall Inc., New Jersey, 126.



DOI: https://doi.org/10.22146/ijc.21352

Article Metrics

Abstract views : 2677 | views : 3324


Copyright (c) 2012 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.