KINETICS AND EQUILIBRIUM MODEL OF Pb(II) AND Cd(II) ADSORPTION ONTO TETRAKIS-THIOMETHYL-C-4-METHOXYPHENYLCALIX[4]RESORCINARENE

https://doi.org/10.22146/ijc.21371

Suryadi Budi Utomo(1*), Jumina Jumina(2), Dwi Siswanta(3), Mustofa Mustofa(4)

(1) Chemical Education Study Program, PMIPA FKIP, Sebelas Maret University, Surakarta
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(4) Department of Pharmacology and Toxicology, Faculty of Medicine, Universitas Gadjah Mada, Yogyakarta 55281
(*) Corresponding Author

Abstract


The ability of tetrakis-thiomethyl-C-4-methoxyphenylcalix[4]resorcinarene for trapping Pb(II) and Cd(II) from aqueous solution at different pH, contact times, and initial metal concentration was investigated. Concentration of metal ions before and after interaction was analyzed by Atomic Absorption Spectrophotometer (AAS). The result indicated that tetrakis-thiomethyl-C-4-methoxyphenylcalix[4]resorcinarene is a good host for metal ions, where Cd(II) sorption capacity was higher than that of Pb(II). Effect of pH on batch experiments for the mentioned ions indicated that the optimum pH for metal binding were 5 for both of lead(II) and cadmium(II). In order to investigate the mechanism of adsorption, the 1st-order, pseudo 1st-order, and pseudo 2nd-order kinetic models were used. The adsorption model of metal ions on the resorcinarene followed pseudo second order of Ho & McKay expression. The equilibrium adsorption isotherm has been analyzed by Langmuir and Freundlich equations. Langmuir model had the higher correlation coefficient than that of Freundlich model.

Keywords


Cd(II); Langmuir isotherm adsorption; Pb(II); pseudo second order; tetrakis-thiomethyl-C-4-methoxy phenylcalix[4]resorcinarene

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References

[1] Widianarko, B., and van Straalen, N.M., 2000, Ecotoxicol. Environ. Saf., 46, 1, 95–100.

[2] Widianarko, B., Sulistyawati, I., and van Straalen, N.M., 2003, Indo. J. Environ. Chem. Toxicol., 1, 2, 1–10.

[3] Hartono and Santosa, E.B., 2005, Enviro, 6, 2, 58–63.

[4] Broto and Syamsul, A.S., 2006, Jurnal Ilmu Tanah dan Lingkungan, 6, 2, 82–100.

[5] Abidin, Z., and Sunardi, 2009, Indo. J. Chem., 9, 3, 425–431.

[6] William, P.L., and James, R.C., 2000, Principles of Toxicology, 2nd ed., New York, John Wiley and Sons.

[7] Goswami, S., and Ghosh, U.C., 2005, Water SA, 31, 4, 597–602.

[8] Barros, M.A.S.D., Zola, A.S., Arroyo, P.A., Agular, E.F., and Tavares, C.R.G., 2003, Braz. J. Chem. Eng., 20, 4, 413–421.

[9] Widihati, I.A.G., 2009, Jurnal Kimia, 3, 1, 27–32.

[10] Nuryono and Suyanta, 2004, Indo. J. Chem., 4, 2, 125–131.

[11] Santosa, S.J., Siswanta, D., Kurniawan, A., and Rahmanto, W.H., 2007, Surf. Sci., 601, 5155–5161.

[12] Cahyaningrum, S.E., and Amaria, 2005, Indo. J. Chem, 5, 2, 130–134.

[13] Buhani and Suharso, 2006, Indo. J. Chem., 6, 1, 43–46.

[14] Supriyanto, G., Handajani, U.S., Istanti, and Abdillah, M.J., 2005, Jurnal Kimia Lingkungan, 7, 1, 19–23.

[15] Djunaidi, M.C., Retno, A.L., Pratama, J.W., Siswanta, D., and Jumina, 2007, Alchemy, 6, 1, 40–49.

[16] Utomo, S.B. and Susilowati, E., 2007, Enviro, 9, 1, 21–27.

[17] Jumina, Sarjono, R.E., Paramita, B.W., Siswanta, D., Santosa, S.J., Anwar, C., Sastrohamidjojo, H., Ohto, K., and Oshima, T., 2007, J. Chin. Chem. Soc., 54, 5, 1167–1178.

[18] Utomo, S.B., Jumina, and Wahyuningsih, T.D., 2009, Indo. J. Chem., 9, 3, 437–444.

[19] Arora, V., Chawla, H.M., and Singh, S.P., 2007, Arkivoc, 2, 172–200.

[20] Puddephatt, R.J., 2006, Can. J. Chem., 84, 11, 1505–1514.

[21] Fox, O.D., Cookson, J., Wilkinson, E.J.S., Drew, M.G.B.; MacLean, E.J., Teat, S.J., and Beer, P.D., 2006, J. Am. Chem. Soc., 128, 21, 6990–7002.

[22] Moore, S.S., Tarnowski, T.L., Newcomb, M., and Cram, D.J., 1977, J. Am. Chem. Soc., 99, 19, 6398–6405.

[23] Zhao, J., Bolte, M., Dordea, C., Gruner, B., and Bohmer, V., 2009, J. Synth. Org. Chem. Jpn., 23, 4063–4067.

[24] Kalenius, E., Kekalainen, T., Neitola, R., Beyeh, K., Rissanen, K., and Vainiotalo, P., 2008, Chem. Eur. J., 14, 17, 5220–5228.

[25] Boas, U., and Heegaard, P.M.H., 2004, Chem. Soc. Rev., 33, 1, 43–63.

[26] Ho, Y.S., 2004, Scientometrics, 59, 1, 171–177.

[27] Ho, Y.S., and Mckay, G., 2000, Water Res., 34, 3, 735–742.

[28] Utomo, S.B., Jumina, Siswanta, D., Mustofa, and Kumar, N., 2011, Indo. J. Chem., 11, 1, 1–8.

[29] Haiduc, I., and Edelmann, F.T., 1999, Supramolecular Organometalic Chemistry, Wiley-VCH, New York.

[30] Nandi, B.K., Goswami, A., and Purkait, M.K., 2009, Appl. Clay Sci., 42, 3-4, 583–590.

[31] Umaningrum, D., Santoso, U.T., Nurmasari, R., and Yunus, R., 2010, Indo. J. Chem., 10, 1, 80–87.

[32] Ayu, Y.P., 2006, Study of The Adsorption of Lead (II), Copper (II), and Chromium (III) Metals Ion on C-Methylcalix[4]resorcinarene, Undergraduate Thesis, Universitas Gadjah Mada, Yogyakarta

[33] Jumina, Sarjono, E.S., Matsyeh, S., and Kumar, N., 2001, BMIPA, 11, 3, 35–51.



DOI: https://doi.org/10.22146/ijc.21371

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