PREPARATION AND CHARACTERIZATION THE NON-SULFIDED METAL CATALYST: Ni/USY and NiMo/USY

https://doi.org/10.22146/ijc.21526

Khoirina Dwi Nugrahaningtyas(1*), Wega Trisunaryanti(2), Triyono Triyono(3), Nuryono Nuryono(4), Dian Maruto Widjonarko(5), Ari Yusnani(6), Mulyani Mulyani(7)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Indonesia
(5) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret State University, Surakarta
(6) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret State University, Surakarta
(7) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret State University, Surakarta
(*) Corresponding Author

Abstract


The two-new catalysts had been prepared by using the impregnation method according to Nugrahaningtyas [6] and Li [4]. One catalyst is of Nickel (Ni), supported on Ultra Stable Zeolite Y (USY), whereas the other one is NiMo supported on same supporting agent. These new catalysts are expected to be more effective when applied on the hydrotreatment reaction in standpoint of its capabilities on removing the unwanted-heteroatom. Characterization those two types of catalysts then carried out by using the criteria of acidity, porosity and, metal content. The result shows that these non-sulfide catalysts have several good characters that supporting their usefulness in hydrotreatment-catalytic reaction. In addition, catalyst NiMo/USY - 1 performs many ideal criteria as the best functional catalyst.


Keywords


Non-sulfided Catalyst; hydro-treating; preparation; characterization

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References

[1] Absi-Halabi, M., Stanislaus. A, and Al-Dolama, K., 1998, Performance Comparison of Alumina-Supported NiMo, Ni-W and NiMo-W Catalyst in Hydrotreating Vacuum Residue, Fuel, 77, 7, 787-790.

[2] Hendayana, Sumar., dkk, 1994, Kimia Analitik Instrumen, IKIP Semarang

[3] Isoda, T., Nagao, S., Ma, X., Korai, Y., and Mochida, I., 1996, Energy Fuels, 10, 487-492.

[4] Li, D., Xu H., and Guthrie, G.D.Jr., 2000, J. Catal., 189, 281-296.

[5] Martinez, M.T., Benito, A.B., Callejas, M.A., and Trasobares, S., 1998, Energy Fuels, 12, 365-370.

[6] Nugrahaningtyas, K.,D., Widjonarko, D.,M., Muhammad F.J.P, and Wijaya, D., 2007, “Hydrocracking Tir Batubara dengan Katalis Monometal dan Bimetal berbasis Zeolit Alam Aktif”, Proseding Konggres dan Simposium ke II Masyarakat katalis Indonesia Indonesian Catalyst Society.

[7] Sugioka, M., Kanda, Y., Kobayashi, T., and Uemichi, Y., 2004, J. Mem. Muroran Inst. Tech., 54, 41-46



DOI: https://doi.org/10.22146/ijc.21526

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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