Technique of Batch Adsorption for the Elimination of (Malachite Green) Dye from Industrial Waste Water by Exploitation Walnut Shells as Sorbent

https://doi.org/10.22146/ijc.23063

Luma Ahmed Mohammed Ali(1*), Ahmed Saleh Farhood(2), Firas Fadhel Ali(3)

(1) Department of Chemistry, College of Science, University of Babylon, Babylon, Iraq
(2) Department of Chemistry, College of Science, University of Babylon, Babylon, Iraq
(3) Department of Chemistry, College of Education for Women, University of Anbar, Anbar, Iraq
(*) Corresponding Author

Abstract


This study proposes an easy and cheap technique to get rid of dangerous Malachite Green (MG) dye from waste material by victimization carbon from walnut shells. The simple treatment was carried out by heating at temperature in which was set to the best carbonization degree to arrange carbon from these shells; thus, the temperature was set to 200 °C. Optimum conditions for sorption like the quantity of adsorbent, contact time, particle size of adsorbent, pH scale and initial MG concentration were conjointly examined. The results showed that the simplest removal was obtained once victimization 1 g of carbon with particle size 150 μM and time contact 150 min. However, the sorption of the dye was not affected by the pH except the sorption was very low at pH = 2. The removal potency was high approximating 99.53%. The results conjointly showed that the sorption equilibrium of MG onto carbon that was ready from the walnut shell has been evaluated via Langmuir and Freundlich models.

Keywords


Malachite Green; walnut shells; batch adsorption

Full Text:

Full Text PDF


References

[1] Afkhami, A. and Moosavi, R., 2010, Adsorptive removal of Congo red, a carcinogenic textile dye, from aqueous solutions by magnetite nanoparticles, J. Hazard. Mater., 174 (1-3), 398–403.

[2] Lian, L., Guo, L., and Guo, C., 2009, Adsorption of Congo red from aqueous solutions onto Ca-bentonite, J. Hazard. Mater., 161 (1),126–131.

[3] Gupta, V.K., Jain, R., Mittal, A., Saleh, T.A., Nayak, A., Agarwal, S., and Sikarwar, S., 2012, Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions, Mater Sci. Eng., C, 32 (1), 12–17.

[4] Naser, N.A., Kadim, K.H., and Taha, D.N., 2012, Synthesis and characterization of an organic reagent 4-(6-bromo-2-benzothiazolylazo) pyrogallol and its analytical application, J. Oleo Sci., 61 (7), 387–392.

[5] Baskaralingam, P., Pulikesi, M., Elango, D., Ramamurthi, V., and Sivanesan, S., 2006, Adsorption of acid dye onto organo bentonite, J. Hazard. Mater., 128 (2-3),138–144.

[6] Feng, Y., Dionysiou, D.D., Wu, Y., Zhou, H., Xue, L., He, S., and Yang, L., 2013, Adsorption of dyestuff from aqueous solutions through oxalic acid-modified swede rape straw: Adsorption process and disposal methodology of depleted bio adsorbents, Bioresour. Technol., 138, 191–197.

[7] Abbas, G.J., Mashkour, M.S., and Taha, D.N., 2016, Flow injection spectrophotometric determination of penicillamine in pharmaceutical formulation using 1,2-naphthoquine-4-sulfonate , J. Purity Util. React. Environ., 5 (4), 92–105.

[8] Taha, D.N., Obaid, Z.S., 2016, Designing flow injection unit for chromates determining, Res. J. Pharm. Biol. Chem. Sci., 7 (6), 2241–2250.

[9] Koprivanac, N., and Kusic, H., 2008, Hazardous organic pollutants in colored wastewaters, Nova Science Publishers, New York.

[10] Crini, G., 2006, Non-conventional low-cost adsorbents for dye removal: A review, Bioresour. Technol., 97 (9), 1061–1085.

[11] Mahmoodi, N.M., 2013, Zinc ferrite nanoparticle as a magnetic catalyst: Synthesis and dye degradation, Mater. Res. Bull., 48 (10), 4255–4260.

[12] Hameed, B.H., and El-Khaiary, M.I., 2008, Equilibrium, kinetics and mechanism of malachite green adsorption on activated carbon prepared from bamboo by K2CO3 activation and subsequent gasification with CO2, J. Hazard. Mater., 157 (2-3), 344–351.

[13] Aksu, Z., 2005, Application of bio sorption for the removal of organic pollutants: A review, Process Biochem., 40 (3-4), 997–1026.

[14] El Nemr, A., Abdelwahab, O., EI-Sikaily, A., and Khaled, A., 2009, Removal of direct blue-86 from aqueous solution by new activated carbon developed from orange peel, J. Hazard. Mater., 161 (1),102–110.

[15] DiPanfilo, R., and Nosa O. Egiebor, N.O., 1996, Activated carbon production from synthetic crude coke, Fuel Process. Technol., 46 (3), 157–169.

[16] Khalili, N.R., Campbell, M., Sandi, G., and Golaś, J., 2000, Production of micro- and mesoporous activated carbon from paper mill sludge: I. Effect of zinc chloride activation, Carbon, 38 (14), 1905–1915.

[17] Taha D.N., and Samaka, I.S., 2012, Natural Iraqi palygorskite clay as low cost adsorbent for the treatment of dye containing industrial wastewater, J. Oleo Sci., 61 (12), 729–736.

[18] Gong, R., Zhang, X., Liu, H., Sun, Y., and Liu, B., 2007, Uptake of cationic dyes from aqueous solution by bio sorption onto granular kohlrabi peel, Bioresour. Technol., 98 (6), 1319–1323.

[19] Kumar, K.V., 2007, Optimum sorption isotherm by linear and non-linear methods for malachite green onto lemon peel, Dyes Pigm., 74 (3), 595–597.

[20] Kumar, O., and Bandyopadhyay, M., 2006, Sorption of cadmium from aqueous solution using pretreated rice husk, Bioresour. Technol., 97 (1), 104–109.

[21] Husseien, M., Amer, A.A., El-Maghraby, A., and Nahla, A., 2007, Utilization of barley straw as a source of a activated carbon for removal of methylene blue from aqueous solution, J. Appl. Sci. Res., 3 (11), 1352–1358.

[22] Singh, K.K., Talat, M., and Hasan, S.H., 2006, Removal of lead from aqueous solutions by agricultural waste maize bran, Bioresour. Technol., 97 (16), 2124–2130.

[23] Vijayaraghavan, K., Palanivelu, K., and Velan, M., 2006, Biosorption of copper(II) and cobalt(II) from aqueous solutions by crab shell particles, Bioresour. Technol., 97 (12), 1411–1419.

[24] Ding, D.H., Zhao, Y.X., Yang, S.J., Shi, W.S., Zhang, Z.Y., Lei, Z.F., and Yang, Y.N., 2013, Adsorption of cesium from aqueous solution using agricultural residue – Walnut shell: Equilibrium, kinetic and thermodynamic modeling studies, Water Res., 47 (7), 2563–2571.

[25] Pehlivan, E., and Altun, T., 2008 Biosorption of chromium(VI) ion from aqueous solutions using walnut, hazelnut and almond shell, J. Hazard. Mater., 155 (1-2), 378–384.

[26] Daneshvar, N., Ayazloo, M., Khataee, A.R., and Pourhassan, M., 2007, Biological decolorization of dye solution containing malachite green by microalgae Cosmarium sp., Bioresour. Technol., 98, 1176–1182.

[27] Al-Degs, Y., Khraisheh, M.A.M., and Ahmed M.N., 2000, Evaluation of activated carbon adsorbents for the removal of textile reactive dyes from wastewater, Jordan Int. Chem. Eng. Conf., 1, 159–167.

[28] Nethaji, S., Sivasamy, A., Kumar, R.V., and Mandal, A.B., 2013, Preparation of char from lotus seed biomass and the exploration of its dye removal capacity through batch and column adsorption studies, Environ Sci. Pollut. Res, 20 (6), 3670–3678.

[29] Ahmad, M.A., Ahmad, N., and Bello, O.S., 2014, Adsorptive removal of malachite green dye using durian seed-based activated carbon, Water Air Soil Pollut., 225, 2057.

[30] Wang, X.S., 2010, Invasive freshwater macrophyte alligator weed: Novel adsorbent for removal of malachite green from aqueous solution, Water Air Soil Pollut., 206 (1), 215–223.

[31] Song, Y., Ding, S., Chen, S., Xu, H., Mei, Y., and Ren, J., 2015, Removal of malachite green in aqueous solution by adsorption on sawdust, Korean J. Chem. Eng., 32 (12), 2443–2448.

[32] Bekçi, Z., Seki, Y., and Cavas, L., 2009, Removal of malachite green by using an invasive marine alga Caulerpa racemosa var. cylindracea, J. Hazard. Mater., 161 (2-3), 1454–1460.

[33] Khattri, S.D., and Singh, M.K., 1999, Colour removal from dye wastewater using sugar cane dust as an adsorbent, Adsorpt. Sci. Technol., 17 (4), 269–282.

[34] Hamdaoui, O., Saoudi, F., Chiha, M., and Naffrechoux, E., 2008, Sorption of malachite green by a novel sorbent, dead leaves of plane tree: Equilibrium and kinetic modeling, Chem. Eng. J., 143 (1-3), 73–84.

[35] Guo, Y., Yang, S., Fu, W., Qi, J., Li, R., Wang, Z., and Xu, H., 2003, Adsorption of malachite green on micro- and mesoporous rice husk-based active carbon, Dyes Pigm., 56 (3), 219–229.

[36] Xia, C., Jing, Y., Jia, Y., Yue, D., Ma, J., and Yin, X., 2011, Adsorption properties of congo red from aqueous solution on modified hectorite: Kinetic and thermodynamic studies, Desalination, 265 (1-3), 81–87.

[37] Langmuir, I., 1918, The adsorption of gases on plan surface of glass, mica and platinum, J. Am. Chem. Soc., 40 (9), 1361–1403.

[38] Weber, T.W., and Chakravorti, R.K., 1974, Pore and solid diffusion models for fixed-bed absorbers, AlChE J., 20 (2), 228–238.

[39] Freundlich, H.M.F., 1906, Over the adsorption in solution, J. Phys. Chem., 57, 385–470.

[40] Taha, D.N., Samaka, I.S., and Mohammed, L.A., 2013, Adsorptive removal of dye from industrial effluents using natural Iraqi palygorskite clay as low cost adsorbent, J. Asian Sci. Res., 3 (9), 945–955.

[41] Taha, D.N., Samaka, I.S., Mohammed, L.A., and Naige, A.S., 2014, Adsorption studies of direct red 28 dye onto activated carbon prepared from low-cost material, Civ. Environ. Res., 6 (7), 149–159.

[42] Sulistyaningsih, T., Santosa, S.J., Siswanta, D., Rusdiarso, B., 2016, Adsorption of [AuCl4]- on ultrasonically and mechanical-stirring assisted Mg/Al-NO3 hydrotalcite-magnetite, Indones. J. Chem., 16 (3) 268–276.

[43] Heraldy, E., Santosa, S.J., Triyono, and Wijaya, K., 2015, Anionic and cationic dyes removal from aqueous solutions by adsorption on to synthetic Mg/Al hydrotalcite-like compound, Indones. J. Chem., 15 (3), 234–241.



DOI: https://doi.org/10.22146/ijc.23063

Article Metrics

Abstract views : 3147 | views : 2495


Copyright (c) 2017 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.