Preliminary Study on the Synthesis of Phosphorylated Mung Bean Starch: The Effect of pH on the Physicochemical and Functional Properties

https://doi.org/10.22146/ijc.25150

Illona Nathania(1*), Asaf Kleopas Sugih(2), Henky Muljana(3)

(1) Department of Chemical Engineering, Parahyangan Catholic University, Jl. Ciumbuleuit 94, Bandung 40141, Indonesia
(2) Department of Chemical Engineering, Parahyangan Catholic University, Jl. Ciumbuleuit 94, Bandung 40141, Indonesia
(3) Department of Chemical Engineering, Parahyangan Catholic University, Jl. Ciumbuleuit 94, Bandung 40141, Indonesia
(*) Corresponding Author

Abstract


Mung bean (Vigna radiate L.) is a grain legume widely cultivated in tropical and sub-tropical regions. Mung bean seeds contain a significant amount of carbohydrate (63%-w/w) and are easily digested compared to seeds from other legumes. Mung bean starch has the potential to be used as thickener or gelling agents in food industries. Certain functional properties of mung bean starch, however, still need to be improved. In this research, a preliminary study was performed to upgrade mung bean starch properties using phosphorylation reaction. In particular, the effect of starch suspension pH (6–10) on the functional properties of the modified products was investigated. Phosphorylation was carried out at 130 °C, for 2 h using sodium tripolyphosphate (STPP) with an intake of 5%-w based on dry starch. The phosphorylated products were subsequently washed with water and dried. The experimental results show that the P-content of the phosphorylated mung bean starch is accessible in the range of 0.04–0.08%. The solubility (6.09–11.37%-w/w) and swelling power (9.88–11.17 g/g) of the modified starch products have been improved compared to native starch (solubility = 6.06 %-w/w, swelling power = 8.05 g/g). Phosphorylation also proved to increase peak viscosity, paste clarity, and water absorption/oil absorption capacity of the products.

Keywords


modified starch; mung bean; phosphorylation; starch

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References

[1] Shannon, J.C., Garwood, D.L., and Boyer, C.D., 2009, “Genetics and Physiology of Starch Development” in Starch: Chemistry and Technology, BeMiller, J., and Whistler, R., eds., Academic Press, Burlington, 24–26.

[2] Minh, N.P., 2014, Different factors affecting to mung bean (Phaseoulus aureus) tofu production, Int. J. Multi. Res. Dev., 1 (4), 105–110.

[3] Han, C.R., Yang, M.D., Xu, X., and Ma, Y.Q., 2011, Comparison of the physicochemical properties of red bean and mung bean starch, Adv. Mater. Res., 183-185, 630–634.

[4] Seisun, D., 2010, “Introduction” in Food Stabilisers, Thickeners and Gelling Agents, Imeson, A. ed., Wiley-Blackwell, Chichester, 1–10.

[5] Mason, W.R., 2009, “Starch Use in Foods” in Starch: Chemistry and Technology, BeMiller, J., and Whistler, R., eds., Academic Press, New York, 756–759.

[6] Sugih, A.K., Muljana, H., Surya, W., and Anggraini, M., 2013, Synthesis and characterisation of phosphorylated sago (Metroxylon sagu) starch, Starch Update 2013: The 7th International Conference on Starch Technology, Bangkok, National Center for Genetic Engineering and Biotechnology (BIOTEC), Thailand, 91–96.

[7] Sugih, A.K., Muljana, H., Alamsyah, A.N., Saputra, C., and Mandalas, F.G., 2012, Synthesis and characterization of phosphorylated and acetylated hanjeli (Coix lacryma-jobi L.) starch for food thickener applications, Proceeding: The 19th Regional Symposium of Chemical Engineering, Bali, Indonesia, 091–097.

[8] Lim, S., and Seib, P.A., 1993, Preparation and pasting properties of wheat and corn starch phosphates, Cereal Chem., 70 (2), 137–144.

[9] Stahl, J.A., Lobato, L.P., Bochi, V.C., Kubota, E.H., Gutkoski, L.C., and Emanuelli, T., 2007, Physicochemical properties of Pinhão (Araucaria angustifolia, Bert, O. Ktze) starch phosphates, LWT Food Sci. Technol., 40 (7), 1206–1214.

[10] Lin, Q., Xiao, H., Zhao, J., Li, L., and Yu, F., 2009, Characterization of the pasting, flow and rheological properties of native and phosphorylated rice starches, Starch, 61 (12), 709–715.

[11] Passauer, L., Bender, H., and Fischer, S., 2010, Synthesis and characterisation of starch phosphates, Carbohydr. Polym., 82 (3), 809–814.

[12] Sugih, A.K., Nathania, I., Muljana, H., 2015, Synthesis and characterisation of phosphorylated arrowroot (Maranta arundinacea L.) Starch, Proceedings of Starch Update 2015: The 8th International Conference on Starch Technology, Bangkok, Thailand, 3–4 December 2015.

[13] Cho S.A., and Kim S.K., 2000, Particle size distribution, pasting pattern, and texture of gel of acorn, mung bean, and buckwheat starches, Korean J. Food Sci. Technol., 32 (6), 1291–1297.

[14] Mishra, S., and Rai, T., 2006, Morphology and functional properties of corn, potato and tapioca starches, Food Hydrocolloids, 20 (5), 557–566.

[15] Muhammad, K., Hussin, F., Man, Y.C., Ghazali, H.M., and Kennedy, J.F., 2000, Effect of pH on phosphorylation of sago starch, Carbohydr. Polym., 42 (1), 85–90.

[16] Deetae, P., Shobsngob, S., Varanyanond, W., Chinachoti, P., Naivikul, O., and Varavinit, S., 2008, Preparation, pasting properties and freeze-thaw stability of dual modified crosslink-phosphorylated rice starch, Carbohydr. Polym., 73 (2), 351–358.



DOI: https://doi.org/10.22146/ijc.25150

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