Separation of Pb(II) Ion with Tetraacetic Acid Derivative of Calix[4]arene by Using Droplet-based Microreactor System

Yehezkiel Steven Kurniawan; Mizuki Ryu; Ramachandra Rao Sathuluri; Wataru Iwasaki; Shintaro Morisada; Hidetaka Kawakita; Keisuke Ohto; Masatoshi Maeki; Masaya Miyazaki; Jumina Jumina

doi:10.22146/ijc.34387

Separation of Pb(II) Ion with Tetraacetic Acid Derivative of Calix[4]arene by Using Droplet-based Microreactor System

https://doi.org/10.22146/ijc.34387

Yehezkiel Steven Kurniawan⁽¹⁾, Mizuki Ryu⁽²⁾, Ramachandra Rao Sathuluri⁽³⁾, Wataru Iwasaki⁽⁴⁾, Shintaro Morisada⁽⁵⁾, Hidetaka Kawakita⁽⁶⁾, Keisuke Ohto^(7*), Masatoshi Maeki⁽⁸⁾, Masaya Miyazaki⁽⁹⁾, Jumina Jumina⁽¹⁰⁾

(1) Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, Japan
(2) Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, Japan
(3) Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, Japan
(4) Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology, 807-1 Shuku, Tosu, Saga 841-0052, Japan
(5) Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, Japan
(6) Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, Japan
(7) Department of Chemistry and Applied Chemistry, Saga University
(8) Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Kita, Sapporo 060-0808, Japan
(9) Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology, 807-1 Shuku, Tosu, Saga 841-0052, Japan
(10) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(*) Corresponding Author

Abstract

In this study, the microreactor system was investigated and compared with the batch-wise system as rapid and effective extractive Pb(II) separation over Fe(III), Cu(II) and Zn(II) with tetraacetic acid calix[4]arene. By using a microreactor system, the Pb(II) extraction percentages reached the maximum of 73, 89 and 100% in 8 sec residence time at equilibrium pH of 2.00, 2.25 and 2.50, respectively. The stripping percentage was 92% at 8 sec residence time by using a microreactor system with 2.0 M HNO₃ as a stripping reagent. Complete separation of Pb(II) over Fe(III), Cu(II) and Zn(II) ions with the tetraacetic acid calix[4]arene in a competitive metal system was achieved at pH 2.00. However, the batch system required 24 h to reach the equilibrium for both extraction and stripping processes. The results suggested that the microreactor system enhanced the Pb(II) extraction and stripping rate up to 10⁴times faster than the batch-wise system.

Keywords

microreactor; Pb(II) extraction; separation; calix[4]arene

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DOI: https://doi.org/10.22146/ijc.34387