Comparison of the Adsorption Ability of MgAl-HC, CaAl-HC, and ZaAl-HC Composite Materials Based on Duku Peel Hydrochar in Adsorption of Direct Green Anionic Dyes

Novie Juleanti; Normah Normah; Patimah Mega Syah Bahar Nur Siregar; Alfan Wijaya; Neza Rahayu Palapa; Tamizi Taher; Nurlisa Hidayati; Risfidian Mohadi; Aldes Lesbani

doi:10.22146/ijc.68719

Comparison of the Adsorption Ability of MgAl-HC, CaAl-HC, and ZaAl-HC Composite Materials Based on Duku Peel Hydrochar in Adsorption of Direct Green Anionic Dyes

https://doi.org/10.22146/ijc.68719

Novie Juleanti⁽¹⁾, Normah Normah⁽²⁾, Patimah Mega Syah Bahar Nur Siregar⁽³⁾, Alfan Wijaya⁽⁴⁾, Neza Rahayu Palapa⁽⁵⁾, Tamizi Taher⁽⁶⁾, Nurlisa Hidayati⁽⁷⁾, Risfidian Mohadi⁽⁸⁾, Aldes Lesbani^(9*)

(1) Magister Program, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524, Ilir Barat 1, Palembang 30139, South Sumatra, Indonesia
(2) Magister Program, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524, Ilir Barat 1, Palembang 30139, South Sumatra, Indonesia
(3) Magister Program, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524, Ilir Barat 1, Palembang 30139, South Sumatra, Indonesia
(4) Magister Program, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524, Ilir Barat 1, Palembang 30139, South Sumatra, Indonesia
(5) Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang-Prabumulih Km. 90-32, Ogan Ilir 30862, South Sumatra, Indonesia
(6) Department of Environmental Engineering, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sumatera, Jl. Terusan Ryacudu, Way Hui, Jati Agung, Lampung 35365, Indonesia Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa, Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(7) Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa, Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(8) Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa, Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(9) Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang-Prabumulih Km. 90-32, Ogan Ilir 30862, South Sumatra, Indonesia Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa, Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(*) Corresponding Author

Abstract

Preparation of composite material from layered double hydroxide (LDH) with hydrochar (HC) from duku peel produces CaAl-HC, MgAl-HC, and ZnAl-HC have shown the success of the preparation process as evidenced by characterizations such as XRD and FT-IR. The XRD characterization data evidenced the typical diffraction of the hydrochar around 2θ = 20° in the composite material. FTIR analysis is a characterization that supports the success of composite materials, which showed the presence of typical vibrations of HC at 3245, 2931, and 1635 cm^–1 contained in the composite spectrum. The application of MgAl-HC, CaAl-HC, and ZnAl-HC composites as adsorbents showed Q_max (adsorption ability) values of 94.340 mg/g, 128.205 mg/g, and 89.286 mg/g. Overall the adsorption process is endothermic with a positive enthalpy value, and a negative Gibbs free energy value indicates a spontaneous adsorption process. The isotherm model of MgAl-HC, CaAl-HC, and ZnAl-HC show that the Langmuir isotherm model is more dominant, as indicated by the R² value closer to 1 which indicates that the adsorption process takes place in a monolayer.

Keywords

duku peel;hydrochar; adsorption; regeneration; dyes

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References

[1] Behbahani, E.S., Dashtian, K., and Ghaedi, M., 2020, Fe/Co-chalcogenide-stabilized Fe₃O₄ nanoparticles supported MgAl-layered double hydroxide as a new magnetically separable sorbent for the simultaneous spectrophotometric determination of anionic dyes, Microchem. J., 152, 104431.

[2] Starukh, H., and Levytska, S., 2019, The simultaneous anionic and cationic dyes removal with Zn e Al layered double hydroxides, Appl. Clay Sci., 180, 105183.

[3] Lim, S.J., and Kim, T.H., 2015, Combined treatment of swine wastewater by electron beam irradiation and ion-exchange biological reactor system, Sep. Purif. Technol., 146, 42–49.

[4] Zhuang, H., Han, H., Ma, W., Hou, B., Jia, S., and Zhao, Q., 2015, Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process, J. Environ. Sci., 33, 12–20.

[5] Mólgora, C.C., Domínguez, A.M., Avila, E.M., Drogui, P., and Buelna, G., 2013, Removal of arsenic from drinking water: A comparative study between electrocoagulation-microfiltration and chemical coagulation-microfiltration processes, Sep. Purif. Technol., 118, 645–651.

[6] Liu, H., Zhou, H., Li, H., Liu, X., Ren, C., Liu, Y., Li, W., and Zhang, M., 2019, Fabrication of Bi₂S₃@Bi₂WO₆/WO₃ ternary photocatalyst with enhanced photocatalytic performance: Synergistic effect of Z-scheme/traditional heterojunction and oxygen vacancy, J. Taiwan Inst. Chem. Eng., 95, 94–102.

[7] Liu, X., Zhou, Z., Yin, J., He, C., Zhao, W., and Zhao, C., 2020, Fast and environmental-friendly approach towards uniform hydrogel particles with ultrahigh and selective removal of anionic dyes, J. Environ. Chem. Eng., 8 (5), 104352.

[8] Milagres, J.L., Bellato, C.R., Ferreira, S.O., de M. Guimarães, L., de P. Tonon, G.J., and Bolandini, A., 2019, Simultaneous removal process of divalent metal and anionic and cationic dyes by layered reconstruction with hydrocalumite intercalated with dodecyl sulfate, Colloids Surf., A, 582, 123890.

[9] Meng, Z., Wu, M., Zhao, S., Jing, R., Li, S., Shao, Y., Liu, X., Lv, F., Liu, A., and Zhang, Q., 2019, Removing anionic dyes from wastewater based on in-situ formation of Fe₃O₄@Zn-Al layered double hydroxides by self-assembly, Appl. Clay Sci., 170, 41–45.

[10] Li, N., Chang, Z., Dang, H., Zhan, Y., Lou, J., Wang, S., Attique, S., Li, W., Zhou, H., and Sun, C., 2020, Deep eutectic solvents assisted synthesis of MgAl layered double hydroxide with enhanced adsorption toward anionic dyes, Colloids Surf., A, 591, 124507.

[11] Daud, M., Hai, A., Banat, F., Wazir, M.B., Habib, M., Bharath, G., and Al-Harthi, M.A., 2019, A review on the recent advances, challenges and future aspect of layered double hydroxides (LDH) – Containing hybrids as promising adsorbents for dyes removal, J. Mol. Liq., 288, 110989.

[12] Badri, A.F., Palapa, N.R., Mohadi, R., and Lesbani, A., 2020, Cationic dye removal by magnesium aluminum-biochar composite from aqueous solution, Int. J. Sci. Technol. Res., 9 (7), 186–190.

[13] He, H., Zhang, N., Chen, N., Lei, Z., Shimizu, K., and Zhang, Z., 2019, Efficient phosphate removal from wastewater by MgAl-LDHs modified hydrochar derived from tobacco stalk, Bioresour. Technol. Rep., 8, 100348.

[14] Balcomb, B., Singh, M., and Singh, S., 2015, Synthesis and characterization of layered double hydroxides and their potential as nonviral gene delivery vehicles, ChemistryOpen, 4 (2), 137–145.

[15] Palapa, N.R., Juleanti, N., Normah, N., Taher, T., and Lesbani, A., 2020, Unique Adsorption properties of malachite green on interlayer space of Cu-Al and Cu-Al-SiW₁₂O₄₀ layered double hydroxides, Bull. Chem. React. Eng. Catal., 15 (3), 653–661.

[16] Bamroongwongdee, C., Suwannee, S., and Kongsomsaksiri, M., 2019, Adsorption of Congo red from aqueous solution by surfactant-modified rice husk: Kinetic, isotherm and thermodynamic analysis, Songklanakarin J. Sci. Technol., 41 (5), 1076–1083.

[17] Alsamman, L., 2017, Development of Modified Layered Silicates with Superior Adsorption Properties for Uptake of Pollutants from Air and Water, Dissertation, RWTH Aachen University, Aachen, Germany.

[18] Siregar, P.M.S.B.N., Palapa, N.R., Wijaya, A., Fitri, E.S., and Lesbani, A., 2021, Structural stability of Ni/Al layered double hydroxide supported on graphite and biochar toward adorption of Congo red, Sci. Technol. Indones., 6 (2), 85–95.

[19] Wan Ngah, W.S., and Hanafiah, M.A.K.M., 2008, Adsorption of copper on rubber (Hevea brasiliensis) leaf powder: Kinetic, equilibrium and thermodynamic studies, Biochem. Eng. J., 39 (3), 521–530.

[20] Palapa, N.R., Taher, T., Wijaya, A., and Lesbani, A., 2021, Modification of Cu/Cr layered double hydroxide by Keggin type polyoxometalate as adsorbent of malachite green from aqueous solution, Sci. Technol. Indones., 6 (3), 209–217.

[21] Sahmoune, M.N., 2019, Evaluation of thermodynamic parameters for adsorption of heavy metals by green adsorbents, Environ. Chem. Lett., 17 (2), 697–704.

[22] Mahmoodi, N.M., Abdi, J., and Bastani, D., 2014, Direct dyes removal using modified magnetic ferrite nanoparticle, J. Environ. Health Sci. Eng., 12 (1), 96.

[23] Hashem, A., Ahmad, F., and Badawy, S.M., 2016, Adsorption of direct green 26 onto fix 3500 treated sawdust: Equilibrium, kinetic and isotherms, Desalin. Water Treat., 57 (28), 13334–13346.

[24] Yu, J., Zhang, X., Wang, D., and Li, P., 2018, Adsorption of methyl orange dye onto biochar adsorbent prepared from chicken manure, Water Sci. Technol., 77 (5), 1303–1312.

[25] Tran, T.V., Phan, T.Q.T., Nguyen, D.T.C., Nguyen, T.T., Nguyen, D.H., Vo, D.V.N., Bach, L.G., and Nguyen, T.D., 2020, Recyclable Fe₃O₄@C nanocomposite as potential adsorbent for a wide range of organic dyes and simulated hospital effluents, Environ. Technol. Innovation, 20, 101122.

[26] Nazir, M.A., Khan, N.A., Cheng, C., Shah, S.S.A., Najam, T., Arshad, M., Sharif, A., Akhtar, S., and Ur Rehman, A., 2020, Surface induced growth of ZIF-67 at Co-layered double hydroxide: Removal of methylene blue and methyl orange from water, Appl. Clay Sci., 190, 105564.

[27] Hua, P., Sellaoui, L., Franco, D., Netto, M.S., Luiz Dotto, G., Bajahzar, A., Belmabrouk, H., Bonilla-Petriciolet, A., and Li, Z., 2020, Adsorption of acid green and procion red on a magnetic geopolymer based adsorbent: Experiments, characterization and theoretical treatment, Chem. Eng. J., 383, 123113.

[28] Nazifa, T.H., Habba, N., Salmiati, S., Aris, A., and Hadibarata, T., 2018, Adsorption of procion red MX-5B and crystal violet dyes from aqueous solution onto corncob activated carbon, J. Chin. Chem. Soc., 65 (2), 259–270.

DOI: https://doi.org/10.22146/ijc.68719