Synthesis, Thermal Analysis, and Thermodynamic Properties Study of New Quinoline Derivative and Their V(IV), Co(II), and Cu(II) Complexes

Raghad Jawad Kadhim Aldoghachi; Faris Abdulridha Jassim Aldoghachi; Tahseen Abdul Qader Alsalim; Mohd Lokman Ibrahim

doi:10.22146/ijc.74423

Synthesis, Thermal Analysis, and Thermodynamic Properties Study of New Quinoline Derivative and Their V(IV), Co(II), and Cu(II) Complexes

https://doi.org/10.22146/ijc.74423

Raghad Jawad Kadhim Aldoghachi⁽¹⁾, Faris Abdulridha Jassim Aldoghachi^(2*), Tahseen Abdul Qader Alsalim⁽³⁾, Mohd Lokman Ibrahim⁽⁴⁾

(1) Department of Pharmaceutical Chemistry, University of Basrah, 61004, Basrah, Iraq
(2) Department of Chemistry, Faculty of Science, University of Basrah, 61004, Basrah, Iraq
(3) Department of Chemistry, Faculty of Education, University of Basrah, 61004, Basrah, Iraq
(4) School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor 40450, Malaysia
(*) Corresponding Author

Abstract

A new ligand (E)-2-((2-chloro-6-methylquinoline-3-yl)methylene)-N'-((E)-(2-chloro-6-methylquinoline-3-yl)methylene)hydrazine-1-carbothiohydrazide (QH) was prepared by reacting hydrazine hydrate with carbon disulfide to yield thiocarbohydrazide. The thiocarbohydrazide in the second step was treated with a quinoline derivative 2-chloro-6-methylquinoline-3-carbaldehyde to yield the ligand. The ligand was identified by spectroscopic techniques FTIR, ¹H-NMR, and ¹³C-NMR. Next, vanadium (V), cobalt (Co), and copper (Cu) complexes were prepared in the [M:L] ratio of 1:1 (QV, QCo, QCu). The complexes were characterized using FTIR, ESI, magnetic susceptibility, and molar conductivity. The thermal analysis (TGA) of V(IV), Co(II), and Cu(II) complexes were studied. The activation thermodynamic parameters, such as the energy of activation, enthalpy, entropy, and free energy change of the complexes, were evaluated, and the stabilities of the thermal decomposition of the complexes were discussed.

Keywords

quinoline derivative; thiocarbohydrazide; metal complexes; thermodynamic parameters

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DOI: https://doi.org/10.22146/ijc.74423