Development of Voltammetry Analysis Method of Iron Metal Ions by Solid-State Membrane with Carbon Nanotube

Suyanta Suyanta; Sunarto Sunarto; Regina Tutik Padmaningrum; Karlinda Karlinda; Illyas Md Isa; Rahardian Rahardian; Qonitah Fardiyah; Fredy Kurniawan

doi:10.22146/ijc.81771

Development of Voltammetry Analysis Method of Iron Metal Ions by Solid-State Membrane with Carbon Nanotube

https://doi.org/10.22146/ijc.81771

Suyanta Suyanta⁽¹⁾, Sunarto Sunarto⁽²⁾, Regina Tutik Padmaningrum⁽³⁾, Karlinda Karlinda⁽⁴⁾, Illyas Md Isa⁽⁵⁾, Rahardian Rahardian^(6*), Qonitah Fardiyah⁽⁷⁾, Fredy Kurniawan⁽⁸⁾

(1) Universitas Negeri Yogyakarta
(2) Universitas Negeri Yogyakarta
(3) Universitas Negeri Yogyakarta
(4) Universitas Negeri Yogyakarta
(5) Universiti Pendidikan Sultan Idris
(6) Universitas Negeri Padang
(7) Universitas Brawijaya
(8) Institut Teknologi Surabaya
(*) Corresponding Author

Abstract

This study was aimed at developing a method of metal analysis in continuous integration using voltammetry techniques. The research subject was iron (II) ions. The objects of research were linearity, scan rate, repeatability of readings, and the presence of Fe (II) levels in well water samples. In this study, a selective electrode was developed with a solid membrane voltammetry system using differential pulse voltammetry measurement. The results showed the regression line of voltammetry method Y = 36.507ln (x) + 990.73 with a correlation value of 0.9627, the optimum scan rate is 20 mV/s, and the five repetitions of each measurement for one electrode shows good repeatability. The result of regression with UV-Vis spectrophotometric method Fe (II) Y = 0.20438x - 0.06987 with a correlation value of 0.99583. The voltammetry method was better than the UV-Vis method because it can be used for analysis up to a concentration of 1x10^-11M, while the UV-Vis method was only up to 1.5 ppm or 2.36x10^-5M.

Keywords

Fe(II) ion; nanotube carbon; solid-state membrane; spectrophotometry; voltammetry

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DOI: https://doi.org/10.22146/ijc.81771