Drying of Merbau (Intsia bijuga) Sawdust Extract: Effect of Temperature on the Quality of Natural Dye Product
Aswati Mindaryani(1*), Vincent Sutresno Hadi Sujoto(2), Sandrina Christine Michelin Silalahi(3), Himawan Tri Bayu Murti Petrus(4), Edia Rahayuningsih(5)
(1) Sustainable Mineral Processing Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Yogyakarta 55281, Indonesia; Indonesia Natural Dye Institute (INDI), Integrated Research and Testing Laboratory (LPPT), Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(2) Sustainable Mineral Processing Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Yogyakarta 55281, Indonesia
(3) Sustainable Mineral Processing Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Yogyakarta 55281, Indonesia
(4) Sustainable Mineral Processing Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Yogyakarta 55281, Indonesia; Indonesia Natural Dye Institute (INDI), Integrated Research and Testing Laboratory (LPPT), Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(5) Sustainable Mineral Processing Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Yogyakarta 55281, Indonesia; Indonesia Natural Dye Institute (INDI), Integrated Research and Testing Laboratory (LPPT), Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(*) Corresponding Author
Abstract
The textile sector leaves 80% of effluent untreated. Carcinogenic, mutagenic, and poisonous synthetic colors in textile waste streams harm the ecosystem. Biodegradable natural dyes are safer than synthetic dyes. Merbau sawdust is abundant in Papua but underutilized. Merbau wood (Intsia bijuga) has considerable tannin and dye potential. Tannin diffuses to the surface, coloring it brown in humid air or water. Merbau extract can be dried to make powdered natural dye. This study examines Merbau sawdust extract drying and natural dye quality at different temperatures. The drying process was carried out in a convective oven at 60, 75, and 90 °C. The data showed that the solid product of natural dye was already dried at 60–90 °C within 100 min. The content of tannin in the dried natural dye powder was analyzed by titration method. The tannin content in the solid product was 0.5–0.9 g tannin/g solid. The drying rate during the constant drying rate period is around 0.00137 to 0.00256 g/cm2 min. The effect of drying temperature (60 to 90 °C) on the tannin degradation is insignificant, based on the titration method and FTIR analysis.
Keywords
Full Text:
Full Text PDFReferences
[1] Wang, L., Li, Y., and He, W., 2017, The energy footprint of China’s textile industry: Perspectives from decoupling and decomposition analysis, Energies, 10 (10), 1461.
[2] Bhatia, S.C., 2017, Pollution Control in Textile Industry, 1st Ed., Eds. Devraj, S., WPI Publishing, New York, US.
[3] Lellis, B., Fávaro-Polonio, C.Z., Pamphile, J.A., and Polonio, J.C., 2019, Effects of textile dyes on health and the environment and bioremediation potential of living organisms, Biotechnol. Res. Innovation, 3 (2), 275–290.
[4] Daberao, A.M., Kolte, P.P., and Turukmane, R.N., 2016, Cotton dying with natural dye, Int. J. Res. Sci. Innovovation, 3 (8), 157–161.
[5] Rahayuningsih, E., Fatimah, W.S., Pamungkas, M.S., and Marfitania, T., 2022, Effect of physicochemical process variables on natural indigo dye production from Strobilanthes cusia leaves by response surface methodology, Indones. J. Chem., 22 (2), 342–351.
[6] Reningtyas, R., Rahayuningsih, E., Kusumastuti, Y., and Kartini, I., 2022, Photofading of natural indigo dye in cotton coated with zinc oxide nanoparticles synthesized by precipitation method, Int. J. Technol., 13 (3), 553–564.
[7] Křížová, H., 2015, “Natural Dyes: Their Past, Present, Future, and Sutainibility” in Recent Developments in Fibrous Material Science, Eds. Křemenáková, D., and Militký, J., OPS, Kanina, Czechia, 59–71.
[8] Mindaryani, A., Rahayuningsih, E., Adriyanti, D.T., Parthasiwi, L.D., Widhiasih, M.S., and Larasati, F., 2020, Production of tannin-based natural dye from mangrove (Rhizophora mangle) tree bark waste from wood chips industry: A feasibility study, IOP Conf. Ser.: Mater. Sci. Eng., 778 (1), 012001.
[9] Tresnawati, N., Saleh, I., Sudarmin, S., and Wardani, S., 2020, The utilization of local plants as natural dye Ciwaringin batik, Cirebon, Indonesia, EurAsian J. BioSci., 14, 7357–7364.
[10] Evitasari, R.T., Rahayuningsih, E., and Mindaryani, A., 2019, Dyeing of cotton fabric with natural dye from Peristrophe bivalvis extract, AIP Conf. Proc., 2085, 020055.
[11] Neimsuwan, T., Hengniran, P., Siramon, P., and Punsuvon, V., 2017, Tannin extraction of rhizophora bark from residual charcoal production, J. Trop. For. Res., 1 (1), 36–50.
[12] Iqbal, S., and Ansari, T.N., 2021, “Extraction and Application of Natural Dyes” in Sustainable Practices in the Textile Industry, Eds. Rather, L.J., Shabbir, M., and Haji, A., Scrivener Publishing LLC, Beverly, Massachusetts, US, 1–40.
[13] Kurniasari, I.D., and Maharani, D.K., 2015, Pembuatan komposit kitosan alumina sebagai agen fiksasi zat warna rodamin B pada kain katun, UNESA J. Chem., 4 (1), 75–80.
[14] Fatubun, A., Susanti, C.M.E., Sinaga, N.I., Wanma, J.F., and Lea, M.M., 2023, Natural dyes used by the byak tribe and its prospects as raw materials for the natural dyes industry, IOP Conf. Ser.: Earth Environ. Sci., 1192 (1), 012023.
[15] Fauziyah, N., and Hakim, L., 2015, Plants as natural dyes for jonegoroan batik processing in Jono cultural tourism village, Bojonegoro, East Java, JITODE, 3 (2), 41–44.
[16] Lemmens, R.H.M.J., Soerianegara, I., and Wong, W.C., 1996, Plant resources of South-East Asia. No. 5(2). Timber trees: Minor commercial timbers, Taxon, 45 (3), 581.
[17] Pamoengkas, P., Siregar, I.Z., and Dwisutono, A.N., 2018, Stand structure and species composition of Merbau in logged-over forest in Papua, Indonesia, Biodiversitas, 19 (1), 163–171.
[18] Malik, J., Santoso, A., Mulyana, Y., and Ozarska, B., 2016, Characterization of Merbau extractives as a potential wood-impregnating material, BioResources, 11 (3), 7737–7753.
[19] Pizzi, A., 2008, “Tannins: Major Sources, Properties and Applications” in Monomers, Polymers and Composites from Renewable Resources, Eds. Belgacem, M.N., and Gandini, A., Elsevier, Amsterdam, 179–199.
[20] Kumari, M., and Jain, S., 2015, Screening of potential sources of tannin and its therapeutic application, Int. J. Nutr. Food Sci., 4 (2-1), 26-29.
[21] Ekechukwu, O.V., 1999, Review of solar-energy drying systems I: An overview of drying principles and theory, Energy Convers. Manage., 40 (6), 593–613.
[22] Putri, N.P., Niawanti, H., Rifaldiannur, M., and Desy, K., 2019, Modeling of tannin mass transfer on the Averrhoa bilimbi leaf extraction, Ekoloji, 28 (108), 2755–2760.
[23] Afolabi, T.J., Tunde-Akintunde, T.Y., and Adeyanju, J.A., 2015, Mathematical modeling of drying kinetics of untreated and pretreated cocoyam slices, J. Food Sci. Technol., 52 (5), 2731–2740.
[24] Geankoplis, C.J., 1993, Transport Processes and Unit Operations, 3rd Ed. Prentice-Hall, Hoboken, New Jersey, US.
[25] Nama Medoua, G., and Mbofung, C.M.F., 2007, Kinetics studies of some physico-chemical substances during roasting and preparation of beverage made by Cassia occidentalis seeds, LWT-Food Sci. Technol., 40 (4), 730–736.
[26] Ndukwu, M.C., Dirioha, C., Abam, F.I., and Ihediwa, V.E., 2017, Heat and mass transfer parameters in the drying of cocoyam slice, Case Stud. Therm. Eng., 9, 62–71.
[27] Kumar, A., Kandasamy, P., Chakraborty, I., and Hangshing, L., 2022, Analysis of energy consumption, heat and mass transfer, drying kinetics and effective moisture diffusivity during foam-mat drying of mango in a convective hot-air dryer, Biosyst. Eng., 219, 85–102.
[28] Chen, B.L., Jang, J.H., Amani, M., and Yan, W.M., 2023, Numerical and experimental study on the heat and mass transfer of kiwifruit during vacuum freeze-drying process, Alexandria Eng. J., 73, 427–442.
DOI: https://doi.org/10.22146/ijc.87624
Article Metrics
Abstract views : 1500 | views : 921Copyright (c) 2023 Indonesian Journal of Chemistry
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.
View The Statistics of Indones. J. Chem.