Magnetically Active GO-Fe3O4 Nanocomposite for Enhanced Rhodamine B Removal Efficiency
Alexander Souhuat(1), Henry Fonda Aritonang(2*), Harry Steven Julius Koleangan(3)
(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sam Ratulangi University, Jl. Kampus Unsrat Kleak, Manado 95115, Indonesia
(*) Corresponding Author
Abstract
According to the World Bank study, approximately 17–20% of water contamination is attributed to the textile industry. The quantity of waste produced increases as a result of increased productivity. Textile wastewater contains dyes such as rhodamine B (RhB), which are hazardous and challenging to remove using standard methods. Adsorption utilizing nano-adsorbents has been widely researched and developed to remove dyes from the environment because of its numerous advantages. Graphene oxide-magnetite (GO-Fe3O4) has been extensively explored as an adsorbent due to its large surface area, strong bonding, and ease of separation from water. In this study, GO-Fe3O4 was synthesized by combining GO from coconut shell with Fe3O4 from iron sand as an absorbent to lower the amount of RhB. Various analytical techniques, including XRD, SEM-EDS, TEM, FTIR, and UV-vis, were employed to examine the properties of the composites. The GO-Fe3O4 exhibited a maximum adsorption capacity of 34.590 mg/g under specific conditions, i.e., 0.5 g adsorbent dosage, pH 4, and a 2 h contact time. The adsorption followed the pseudo-second-order kinetics model with 0.00016 mg/g min adsorption rate while the adsorption isotherm followed the Langmuir model where adsorbent surfaces are spread homogeneously by forming a monolayer.
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DOI: https://doi.org/10.22146/ijc.96383
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